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HomeMy WebLinkAboutREVISION INFO, Vapor-Barrier-GHS-SDS Page 1 of 10 VAPOR BARRIER™ Product Name (as used on Label and List) Dual Rubber Coating Revision Date: 9-2-16 GHS Safety Data Sheets (SDS) SECTION 1 – IDENTIFICATION PRODUCT NAME VAPOR BARRIER™ OTHER MEANS OF IDENTIFICATION VB END USE Latex Paints & Coatings, Water Borne Dispersion MANUFACTURER Ames Research Laboratories, Inc. Salem, Oregon 97302 Corporate Office: 1891 16th Street SE Salem, Oregon 97302-1436 (503) 588-3330 EMERGENCY PHONE NUMBER 1-888-345-0809 or Chemtrec 1-800-424-9300 SECTION 2 – HAZARD IDENTIFICATION CLASSIFICATION Acute Toxicity, Dermal – 5: Serious Eye Damage/Eye Irritation – 2B: Acute Toxicity, Inhalation – 5 SIGNAL WORD WARNING HAZARD STATEMENT May be harmful in contact with skin (H313) Causes eye irritation (H320) : May be harmful if inhaled (H333) HAZARD PICTOGRAMS N.A. – No Symbol PRECAUTIONARY STATEMENT(S) Wear protective gloves/protective clothing/eye protection/face protection. Avoid breathing dust/fume/gas/mist/vapor/spray. Use only outdoors or in well-ventilated area. If hands or other body parts come in contact, wash thoroughly after handling. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do so. Continue rinsing. (P305+P351+P338) If eye irritation persists: Get medical attention from a physician. (P337+P313) IF ON SKIN OR INHALED: Call a POISION CENTER or doctor/physician if you feel unwell. (P304+P312) HAZARDS NOT OTHERWISE CLASSIFIED N.A. Page 2 of 10 VAPOR BARRIER™ Product Name (as used on Label and List) Dual Rubber Coating Revision Date: 9-2-16 GHS Safety Data Sheets (SDS) SECTION 3 – COMPOSITION/INFORMATION ON INGREDIENTS SUBSTANCE / MIXTURE Mixture OTHER MEANS OF IDENTIFICATION N. A. CAS # / IDENTIFIERS INGREDIENT NAME % BY WEIGHT CAS NUMBER Acrylic 2-Hex-Carboxylated- Styrene-Cloral-butadiene-rubber (Proprietary trade secret claims) Not Regulated N/A Mixture Water 20 – 25% 7732-18-5 Acrylic Styrene Polymer (Proprietary trade secret claims) Not Regulated N/A Mixture Limestone (Calcium Carbonate) 5 – 10 % 1317-65-3 Titanium Dioxide 1 – 5 % 13463-67-7 Any concentrations shown in a range are to protect trade secret confidentiality or is due to batch variation. There are no additional ingredients present, which within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section. SECTION 4 – FIRST AID MEASURES DESCRIPTION OF NECESSARY FIRST AID MEASURES EYE CONTACT Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do so. Continue rinsing. If eye irritation persists: Get medical attention from a physician. INHALATION Slight ammonia odor. Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. SKIN CONTACT Remove contaminated clothing and shoes. Wash affected area(s) thoroughly with soap and water. Flush skin after contact. May cause mild skin irritation. Protect with gloves. INGESTION N/A. No data on latex. Ingestion not a probable route of entry. MOST IMPORTANT SYMPTOMS / EFFECTS, ACUTE AND DELAYED EYE CONTACT May cause eye irritation INHALATION May cause respiratory tract irritation SKIN CONTACT May cause skin irritation INGESTION N/A. No data on latex. Ingestion not a probable route of entry. Page 3 of 10 VAPOR BARRIER™ Product Name (as used on Label and List) Dual Rubber Coating Revision Date: 9-2-16 GHS Safety Data Sheets (SDS) INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDS, IF NECESSARY EYE CONTACT N/A INHALATION N/A SKIN CONTACT N/A INGESTION N/A. No data on latex. Ingestion not a probable route of entry. SECTION 5 – FIRE FIGHTING MEASURES EXTINGUISHING MEDIA: SUITABLE MEDIA Foam CO2, Dry chemical, Water, Fog Foam EXTINGUISHING MEDIA: UNSUITABLE MEDIA N/A SPECIFIC HAZARDS ARISING FROM THE CHEMICAL None known. Some potential gases including hydrogen chloride, carbon monoxide, aldehydes. SPECIAL PROTECTIVE ACTIONS FOR FIRE- FIGHTERS Containers exposed to fire should be kept cool with water spray. Containers can build up pressure if exposed to heat (fire). SPECIAL EQUIPMENT FOR FIRE-FIGHTERS As in any fire, wear pressure-demand self- contained breathing apparatus (SCBA) (MSHA/NIOSH approved or equivalent) and full protective gear. SECTION 6 – ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES FOR NON-EMGERGENCY PERSONNEL Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. FOR EMERGENCY PERSONNEL If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel." ENVIRONMENTAL PRECAUTIONS Avoid runoff into storm sewers and ditches that lead to waterways. This product does not meet the definition of hazardous waste under the U.S. EPA Hazardous Waste Regulations 40 CFR 261. Consult your state or local authorities for proper disposal in the event that more restrictive requirements apply. Page 4 of 10 VAPOR BARRIER™ Product Name (as used on Label and List) Dual Rubber Coating Revision Date: 9-2-16 GHS Safety Data Sheets (SDS) METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP LARGE SPILLS Soak spills with sand or earth and remove. Repeat sorbent/sweep cycle until the spill is dried up. Large spills of the material may best be cleaned up by absorbing the liquid on solid materials such as vermiculite, clay, kitty litter, or by adding aqueous electrolyte to coagulate the polymer for disposal in an approved landfill. Collect and dispose according to local regulations. SMALL SPILLS Flush with water. SECTION 7 – HANDLING AND STORAGE PRECAUTIONS FOR SAFE HANDLING PROTECTIVE MEASURES Use in a well ventilated area. Keep out of reach of children. If user operations generate dust, fume, or mist, use ventilation to keep exposure to airborne contaminants below the respective exposure limits. Use goggles and gloves. Similar to most latex paints. GENERAL HYGIENE Do not take internally. Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid breathing vapors from heated material. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATABILITIES Keep container closed when not in use. Dries rapidly. PROTECT FROM FREEZING. SECTION 8 – EXPOSURE CONTROL/PERSONAL PROTECTION OCCUPATIONAL EXPOSURE LIMITS OSHA PEL 8-HR TWA OSHA PEL STEL/Ceiling ACGIH TLV-TWA ACGIH TLV-STEL Limestone 15 mg/m3 N.E. 10 mg/m3 N.E. Titanium Dioxide 15 mg/m3 N.E. 10 mg/m3 N.E. CONTROLS ENGINEERING CONTROLS Local exhaust ventilation may be necessary to control any air contaminants to within their respective exposure limits during the use of this product. Contains low levels of ammonia for pH control. PERSONAL PROTECTIVE EQUIPMENT Wear a NIOSH/MSHA approved respirator when the product is mixed or applied in poorly ventilated areas or if the workplace levels of ingredients exceed exposure limits. When contact is likely, wear chemical resistive gloves, chemical safety goggles with a face shield, and clean protective clothing to cover arms and legs at a minimum. Page 5 of 10 VAPOR BARRIER™ Product Name (as used on Label and List) Dual Rubber Coating Revision Date: 9-2-16 GHS Safety Data Sheets (SDS) SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE PHYSICAL STATE Thick latex liquid COLOR Colonial White ODOR Slight ammonia odor ODOR THRESHOLD N.D. pH 9.0 – 10.0 MELTING POINT N/A BOILING POINT 212° F FLASH POINT These formulations tested in accordance with ASTM E 108- 80a Class A with Zero ignitions with a flame-spread test. With Weyerhaeuser Company, Fire Technology Unit. Product was tested in accordance with ASTM E-84-81a. “Smoke attained was Zero.” Product contains dispersed latex and water solvent. The flames spread index determined meets the criteria for Class A material over A/C/Substrate. EVAPORATION RATE Similar to latex paint, water-based latex polymers. FLAMMABILITY (SOLID, GAS) N/A UPPER / LOWER FLAMMABILITY OR EXPLOSIVE LIMITS N/A VAPOR PRESSURE 1.75 mm Hg VAPOR DENSITY Heavier than air RELATIVE DENSITY 1.04-1.11 SOLUBILITY(IES) Dilatable, miscible. PARTITION COEFFICIENT: N- OCTANOL / WATER N/A AUTO-IGNITION TEMPERATURE N/A DECOMPOSITION TEMPERATURE N/A VISOCITY 1500-3500 cps Page 6 of 10 VAPOR BARRIER™ Product Name (as used on Label and List) Dual Rubber Coating Revision Date: 9-2-16 GHS Safety Data Sheets (SDS) SECTION 10 – STABILITY AND REACTIVITY REACTIVITY This product is not reactive under normal conditions CHEMICAL STABILITY This product is stable under normal storage conditions. POSSIBILITY OF HAZARDOUS REACTION Will not occur under normal conditions. CONDITIONS TO AVOID Long-term exposure to elevated temperatures. INCOMPATIBLE MATERIALS Avoid contact with oxidizing materials. HAZARDOUS DECOMPOSITION PRODUCTS Acrid fumes. Oxides of carbon. SECTION 11 – TOXICOLOGICAL INFORMATION INFORMATION ON TOXICOLOGICAL EFFECTS ACUTE TOXICITY May cause slight irritation to skin, eyes, throat and respiratory tract. IRRITATION / CORROSION May cause slight irritation to skin, eyes, throat and respiratory tract. SENSITIZATION N.A. MUTAGENICITY N.A. CARCINOGENICITY N.A. REPRODUCTIVE TOXICITY N.A. TETRAOGENICITY N.A. SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) N/A SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) N/A ASPIRATION HAZARD N/A INFORMATION ON LIKELY ROUTES OF EXPOSURE Inhalation, dermal and eye contact are likely routes of exposure. POTENTIAL ACUTE HEALTH EFFECTS EYE CONTACT May cause slight irritation INHALATION May cause respiratory tract irritation SKIN CONTACT May cause irritation INGESTION Irritating to mouth, throat and stomach. SYMPTOMS RELATED TO THE PHYSICAL, CHEMCIAL AND TOXICOLOGICAL CHARACTERISTICS EYE CONTACT N/A INHALATION N/A Page 7 of 10 VAPOR BARRIER™ Product Name (as used on Label and List) Dual Rubber Coating Revision Date: 9-2-16 GHS Safety Data Sheets (SDS) SKIN CONTACT N/A INGESTION N/A DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG TERM EXPOSURE SHORT TERM EXPOSURE – POTENTIAL IMMEDIATE EFFECTS N/A SHORT TERM EXPOSURE – POTENTIAL DELAYED EFFECTS N/A LONG TERM EXPOSURE – POTENTIAL IMMEDIATE EFFECTS No anticipated effects. LONG TERM EXPOSURE – POTENTIAL DELAYED EFFECTS No anticipated effects. POTENTIAL CHRONIC HEALTH EFFECTS GENERAL N.A. CARCINOGENICITY N.A. MUTAGENICITY N.A. TERATOGENCITY N.A. DEVELOPMENTAL EFFECTS N.A. FERTILITY EFFECTS N.A. NUMERICAL MEASURES OF TOXICITY (ACUTE TOXICITY ESTIMATE) N.A. TOXICOLOGICAL DATA: INGREDIENT ORAL RAT (LD50) SKIN RABBIT (LD50) INHALATION RAT (LC50) Limestone >5000 mg/kg N/A N/A Titanium Dioxide 10000 mg/kg N/A N/A SECTION 12 – ECOLOGICAL INFORMATION TOXICITY Contains water-based acrylic. Relatively non-toxic to environment. PERSISTENCE AND DEGARDABILITY N/A BIOACCUMULATIVE POTENTIAL N/A MOBILITY IN SOIL N/A OTHER ADVERSE EFFECTS N/A SECTION 13 – DISPOSAL CONSIDERATIONS DISPOSAL CONSIDERATIONS Review all local, state, and federal regulations concerning health and pollution for appropriate disposal procedures. Page 8 of 10 VAPOR BARRIER™ Product Name (as used on Label and List) Dual Rubber Coating Revision Date: 9-2-16 GHS Safety Data Sheets (SDS) SECTION 14 – TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME Not regulated DOT Classification TDG Classification Mexico Classification IMDG IATA UN NUMBER Not regulated. Not regulated. Not regulated. Not regulated. Not regulated. UN PROPER NAME - - - - - PACKING GROUP - - - - - TRANSPORT HAZARD CLASS(ES) - - - - - ENVIRONMENTAL HAZARDS No. No. No. No. No. ADDITIONAL INFORMATION Special Provisions Not Applicable Special Provisions Not Applicable Special Provisions Not Applicable Emergency Schedules (Ems) Not Applicable Special Provisions Not Applicable SPECIAL PRECATIONS FOR USERS: Multi-model shipping descriptions are provided for information purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for the mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL II 73/78 AND THE IBC CODE N.A PROPER SHIPPING NAME N.A SHIP TYPE N.A POLLUTION CATEGORY N.A SECTION 15 – REGULATORY INFORMATION U.S. FEDERAL REGULATION OSHA Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200) CERLA – SARA HAZARD CATEGORY This product has been reviewed according to the EPA “Hazard Categories” promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Page 9 of 10 VAPOR BARRIER™ Product Name (as used on Label and List) Dual Rubber Coating Revision Date: 9-2-16 GHS Safety Data Sheets (SDS) Title III) and is considered, under applicable definitions, to meet the following category: None. SARA SECTION 313 This product does not contain toxic chemical(s) at or above the de minimus concentrations subject to the reporting requirements of section 313 of Title III Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372. TOXIC SUBSTANCES CONTROL ACT This product meets the compositional requirements of the Toxic Substances Control Act and contains only chemical ingredients that are listed on the TSCA inventory. CALIFORNIA PROP. 65 This product may contain no chemical(s) known to California to cause cancer and/or birth defects or other reproductive harm. INTERNATIONAL REGULATIONS CANADIAN EPA This product complies with Domestic Substance List of the Canadian Environmental Agency. CANADIAN WHMIS CLASS N/A SECTION 16 – OTHER INFORMATION HMIS RATINGS HEALTH 1 FLAMMABILITY 0 REACTIVITY 0 PERSONAL PROTECTION B EUROPEAN PRECAUTIONARY PICTOGRAMS General: If spraying or in poorly ventilated area: PREVIOUS SDS REVISION DATE 9/15 REASON FOR REVISION N.A. VOLATILE ORGANIC COMPOUNDS (VOC’S) ˂ 50 grams/liter LEGEND N.A. – Not Applicable, N.E. – Not Established, N.D. – Not Determined ABBREVIATIONS USED N/A – Information or data not available, NTP – National Toxicological Program, IARC – International Agency for Page 10 of 10 VAPOR BARRIER™ Product Name (as used on Label and List) Dual Rubber Coating Revision Date: 9-2-16 GHS Safety Data Sheets (SDS) Research on Cancer, NIOSH – National Institute of Occupational Safety and Health, PEL – Permissible Exposure Limit (8-hour TWA OSHA), TLV – Threshold Limit Value (8-Hour TWA ACGIH), STEL – Short Term Exposure Limit (15 min. TWA OSHA), C – Ceiling Value NOTICE TO READER It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given, The information presented here applies only to the product as shipped. The addition of a material can change the composition, hazards and risks of the product. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that their activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for the SDS's obtained from any other source. Note: This information must be included in all SDS that are copied and distributed for this material. END OF SAFETY DATA SHEET