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HomeMy WebLinkAboutProduct IdentificationM RALISTRY. Coverfree® Instructions Directions for use: 12 -0g2b ECEIVFD FEB 2 5 2020 sT. Lucie County, Permitting 1. Shake product vigorously. 2. Weekly with circulation system running, add 4 oz. per 675 sq. ft. (20,000 gallons) of surface area. Note: Skimmer application is preferred, however, Coverfree can be added directly to pool water. Important: Circulation system must be running for either application. Note: Reapply after heavy bather load due to splash out/drag out and heavy rain due to dilution and loss to overflow drains. For areas affected by drought or extreme conditions: Dose twice per week. iv A •r u a n t_ C: H Gl�ia S T RY 1. Product and Company Identification Product identifier Cover Free Other means of identification Not available Recommended use Suppression of water evaporation and heat loss Recommended restrictions None known. Manufacturer Natural Chemistry L.P. 40 Richards Ave. Norwalk, CT 06854 US Phone: (800) 753-1233 Emergency Phone: CHEMTREC (800) 424-9300 Physical hazards Health hazards Environmental hazards OSHA defined hazards Label elements Hazard symbol Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Supplemental information 2. Hazards Identification Not classified. Not classified. Not classified. Not classified. None. None. The mixture does not meet the criteria for classification. Observe good industrial hygiene practices. Wash hands after handling. Store away from incompatible materials. Dispose of waste and residues in accordance with local authority requirements. None known. Not applicable. 3. Composition/Information on Ingredients Mixture Chemical name Common name and synonyms CAS number % 1-Octadecanol 112-92-5 3-7 1,2-Propanediol Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information 57-55-6 1-5 4. First Aid Measures If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. Call a physician if symptoms develop or persist. Rinse skin with water/shower. Get medical attention if irritation develops and persists. Rinse with water. Get medical attention if irritation develops and persists. Rinse mouth. If ingestion of a large amount does occur, call a poison control center immediately. Irritant effects. Treat symptomatically. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire Fighting Measures Suitable extinguishing media Foam. Dry chemical. Carbon dioxide. 111cula Specific hazards arising from During fire, gases hazardous to health may be formed. the chemical Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire. and precautions for firefighters Fire -fighting Move containers from fire area if you can do so without risk. e qui pmentfr nstructions Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards No unusual fire or explosion hazards noted. Hazardous combustion Oxides of carbon. products Explosion data Sensitivity to mechanical Not available. impact Sensitivity to static Not available. discharge 6. Accidental Release Measures Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Do not touch protective equipment and damaged containers or spilled material unless wearing appropriate protective clothing. For emergency procedures personal protection, see section 8 of the SDS. Methods and materials for This product is miscible in water. Stop the flow of material, if this is without risk. containment and cleaning up Large Spills: Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re -use. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains, water courses or onto the ground. 7. Handling and Storage Precautions for safe handling Avoid contact with eyes and skin. Avoid prolonged exposure. Use care in handling/storage. Conditions for safe storage, Store in original tightly closed container. Store away from incompatible materials (see Section 10 including any incompatibilities of the SDS). 8. Exposure Controls/Personal Protection Occupational exposure limits US. AIHA Workplace Environmental Exposure Level (WEEL) Guides Components Type Value Form 1,2-Propanediol (CAS TWA 10 mg/m3 Aerosol. 57-55-6) Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields. Skin protection Hand protection Rubber gloves. Confirm with a reputable supplier first. Other Wear suitable protective clothing. Respiratory protection Not normally required if good ventilation is maintained. Thermal hazards Not applicable. General hygiene Always observe good personal hygiene measures, such as washing after handling the material considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Appearance Milky Physical state Liquid. Form Liquid. Color Orange Odor Not available. Odor threshold Not available. pH 8-10 Melting point/freezing point Not available. Initial boiling point and boiling Not available. range Pour point Not available. Specific gravity 0.97 - 1 Partition coefficient Not available. (n-octanol/water) Flash point Not available. Evaporation rate Not available. Flammability (solid, gas) Not applicable. Upper/lower Flammability or explosive limits Flammability limit - lower Not available. N Flammability limit - upper Not available. N Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure Not available. Vapor density Not available. Relative density 8.2 - 8.4 lb/gal Solubility(ies) Complete Auto -ignition temperature Not available. Decomposition temperature Not available Viscosity Not available. 10. Stability and Reactivity Reactivity None known. Possibility of hazardous No dangerous reaction known under conditions of normal use. reactions Chemical stability Material is stable under normal conditions. Conditions to avoid Contact with incompatible materials. Incompatible materials Strong oxidizing agents. Hazardous decomposition Oxides of carbon. products 11. Toxicological Information Routes of exposure Eye, Skin contact, Inhalation, Ingestion. Information on likely routes of exposure Ingestion Expected to be a low ingestion hazard. Inhalation No adverse effects due to inhalation are expected. Skin contact May be irritating to the skin. Eye contact May be irritating to eyes. Symptoms related to the Irritant effects. physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity 1,2-Propanediol (CAS 57-55-6) Acute Dermal • LD50 Rabbit 20800 mg/kg Inhalation LC50 Not available Oral LD50 Dog 19000 mg/kg Guinea pig 184000 mg/kg Mouse 23900 mg/kg Rabbit 14800 mg/kg Rat 20000 mg/kg 1-Octadecanol (CAS 112-92-5) Acute Dermal LD50 Rabbit > 3000 mg/kg > 3 g/kg Inhalation LC50 Not available Oral LD50 Rat > 5000 mg/kg Skin corrosion/irritation May cause irritation. Exposure minutes Not available. Erythema value Not available. Oedema value Not available. Serious eye damage/eye May be irritating to eyes. irritation Corneal opacity value Not available. Iris lesion value Not available. Conjunctival reddening Not available. value Conjunctival oedema value Not available. Recover days Not available. Respiratory or skin sensitization Respiratory sensitization Not classified. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1 % are mutagenic or genotoxic. Mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Teratogenicity Not classified. Specific target organ toxicity - Not classified. single exposure Specific target organ toxicity - Not classified. repeated exposure Aspiration hazard Not classified. Chronic effects Not classified. Further information Not available. Name of Toxicologically Not available. Synergistic Products Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. See below Components Species Test Results 1,2-Propanediol (CAS 57-55-6) Crustacea EC50 Daphnia 10000 mg/L, 48 Hours Aquatic Crustacea EC50 Water flea (Daphnia magna) > 10000 mg/I, 48 hours Fish LC50 Fathead minnow (Pimephales promelas) 710 mg/I, 96 hours 1-Octadecanol (CAS 112-92-5) Crustacea EC50 Daphnia 1666 mg/L, 48 Hours Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Mobility in soil No data available. Mobility in general Not available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal Considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some products product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport Information U.S. Department of Transportation (DOT) Not regulated as dangerous goods. Transportation of Dangerous Goods (TDG - Canada) Not regulated as dangerous goods. 15. Regulatory Information Canadian federal regulations This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the SDS contains all the information required by the Controlled Products Regulations. Canada WHMIS Ingredient Disclosure: Threshold limits 1,2-Propanediol (CAS 57-55-6) 1 % WHMIS status Controlled WHMIS classification Class D - Division 2B WHMIS labeling T US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. US CAA Section 111 Volatile Organic Compounds: Listed substance 1,2-Propanediol (CAS 57-55-6) Listed. Not regulated. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely No hazardous substance SARA 3111312 Hazardous No chemical SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Water Act (CWA) Hazardous substance Section 112(r) (40 CFR 68.130) Safe Drinking Water Act Not regulated. (SDWA) Food and Drug Not regulated. Administration (FDA) US state regulations California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance Not listed. US - Minnesota Haz Subs: Listed substance 1,2-Propanediol (CAS 57-55-6) Listed. US - New Jersey RTK - Substances: Listed substance 1,2-Propanediol (CAS 57-55-6) Listed. US - Texas Effects Screening Levels: Listed substance 1,2-Propanediol (CAS 57-55-6) Listed. 1-Octadecanol (CAS 112-92-5) Listed. US. Massachusetts RTK - Substance List Not regulated. US. Pennsylvania RTK - Hazardous Substances 1,2-Propanediol (CAS 57-55-6) Listed. US. Rhode Island RTK Not regulated. Inventory status Country(s) or region Inventory name On inventory (yes/no)• Canada Domestic Substances List (DSL) Yes Canada Non -Domestic Substances List (NDSL) No United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes 'A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) 16. Other Information LEGEND Severe 4 Serious 3 Moderate 2 Slight 1 Minimal 0 and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. Issue date 11-August-2014 Effective date 01-August-2014 Expiry date 01-August-2017 Further information For an updated SIDS, please contact the supplier/manufacturer listed on the first page of the document. Prepared by Dell Tech Laboratories, Ltd. Phone: (519) 858-5021 Other information This Safety Data Sheet was prepared to comply with the current OSHA Hazard Communication Standard (HCS) adoption of the Globally Harmonized System of Classification and Labeling of Chemicals (GHS). This SIDS conforms to the ANSI Z400.12129.1-2010 Standard.