HomeMy WebLinkAboutMATERIAL DATA SHEETI
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PERKADOX 16 I
1 IDFNTIFICATION OF THE RI1Pt9 )ARATION AND OF THE COMPANY/IJNDFRTAKING
Product identifier
Di(4-test butyicyclohexyl) peroxydicarbonste, powder
Supplier
Akzo Nobel Polymer Chemicals LLC
525 West Van Buren Street
Chicago, IL 60607-3823
www.akzonobel.com/polymer
Emergency telephone
transportation emergency
0-914-693-6946
CHEMTREC - USA: 1-800-424-9300
Chicago, iL USA
CANUTEC - CANADA: 1-613-996-6666
Relevant Identified uses of the substance or mixture
polymerization Initiator
Date'of last Issue Revision number
2014/05/04 / 9.05 I
Chemical family I
peroxides
2 HA7ARDR IDENTIFICATION I
Emergency overview I
DANGERI
REFRIGERATED ORGANIC PEROXIDE - MAINTAIN COOLING
HEAT OR CONTAMINATION MAY CAUSE HAZARDOUS DECOMPOSITION
MAY CAU85 EYE IRRITATION
Peroxides. and peroxide decomposition�products are flarpmable and can. ignite with explosive force if confined. Dust
explosion possible in the presence of air.
white,Appearance;, I
powd' er with faint odor.
Health effects
Skin contact, eye contact and inhalatil n are the priinary routes of exposure to this product
Dust may be irritating to the respiratory tract and cause. symptoms of bronchitis.
May cause sensitization by skin contact.
Eye contact may cause mild irritation.
If swallowed, this product may cause irritation of the mouth, throat, esophagus.and stomach.
I.Caeciriogem I
:Description
Applicable
IARC J
no
NTP
no
,OSHA
no
ACGIH
no
3. COMPOSITIOWIN FORMATION ON INGREDIENTS
Information on hazardous ingredients
Chemical description I
DI(4-tert-butyicyclohexyi) peroxydicarbonate, powder
Composition / information onjingredients
Number
I %w/w j
CAS -number
Chemical name
1
1 > 94
015520-11-3
Di(4-tert-butylcyclohexyl) peroxydicarbonate
4. FIRST AID MEASURES
Product code 661451
Date of last Issue 2014105104 Pagel - 8
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Material safety data sheet
AluoNobel
Most important symptoms and effects
Dust may be irritating to the respiratory tract and cause symptoms of bronchitis.
Description of first aid measures I
General
in all cases of doubt, or when symptoms persist, seek medical attention.
Inhalation
Remove to fresh air. If not breathing,lgive artificial respiration. Oxygen may additionally be given, by trained
personnel, if it is available. Get medical attention if symptoms occur.
Skin
Flush skin with plenty of water. Remove contaminated clothing and -shoes. Get medical attention if irritation
develops and persists. Wash clothing before reuse. Thoroughly clean or.destroy contaminated shoes.
Eye
Immediately flush eyes with plentylof water. If easy to do, contact lenses should be removed during the
flushing, by trained personnel..Occasionally hold the eyelids apart.during the flushing to ensure rinsing the
entire surface of the eye.and lids with water. Get medical attention if irritation develops and persists.
Ingestion .
Call a physician or a poison control center iminediately. Induce vomiting only if directed by medical personnel.
The patient should lie on their leftiside while vornitingto reduce the risk.of aspiration. Never give anything by
mouth to an unconscious or convulsing person.
Indication of any immediate medical attention and special treatment.needed
Persons with pre-existing skin, eye, or respiratory disease may be at increased risk from the irritant or allergic
properties of this material.
Attending physician should treat exposed patients symptomatically.
5- FIRE -FIGHTING MFASIIRFS
Extinguishing media
waterspray, foam, sand, dry cherriica4owder, CO2.
Unsuitable extinguishing media I
helons.
Hazardous decomposition / combustion products
CO2, Carbon monoxide. I
4-tert-Butylcyclohexanol.
Protective equipment
ntenyntotS must irvcat tits eyuipiii611L. yv.Cdt dlipiitv6ti re3pir8iyi diiii pryiecuve gloves.
Other information
Evacuate all non -essential personnl I. Extinguish a small fire with.powder or carbon dioxide then apply water to prevent
re -ignition. Cool closed containers with water. Waterused to extinguish a fire should not. be allowed to enter the
drainage system or water courses) After a fire, ventilate thoroughly the area and soak with water, clean the walls and
metallic surfaces.
Fire and explosion hazard j
CAUTION: reignition may occur. Decomposition under effect of heating (See also Section Hazardous decomposition
products). If involved in a fire, it fill support combustion. dust explosion hazard. In case of fire and/or explosion do not
breathe fumes.
NFPA ratings
Hazard classes
Rating
Health i
1
Flammability i
3
Reactivity j
2
Other information j
6. ACCIDENTAL RELEASE MEASURES
Product code 661451
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Material safety data iheet
c=QVenr»r 79Z I
Personal precautions
Do not breathe dust. Avoid contact with skin. For personal protection see Section 8.
Environmental precautions
Do not allow to enter drains or watercourses. I
Methods and material for containment and lcleaning up
Stop leakage if possible. Eliminate all sources of ignition, and do not generate flames or sparks. Sweep up and put it
into a container for disposal. Avoid dust generation. Keep contents moist. The waste should NOT be confined. Flush
surroundings with large amounts of water and soap.
Other information
CAUTION: reignition may occur. Evacuate personnel to safe area.
7 HANnI IN(` ANn RT0PAr F= I
Precautions for safe handling
Never weigh out in the storage room. When using do not eat; drink or smoke. Do not breathe dust. Handle in well
ventilated areas. Eliminate all sources of ignition, and do not generate flames orsparks. Keep away from reducing
agents. (e.g. amines), acids, alkalies and heavy metal compounds (e.g. accelerators, driers, metal soaps). Keep
product and emptied container away from heat and sources of ignition. Confinement must be avoided. Avoid
Incompatible materials (See Section 10).
Fire and explosion prevention
Use explosion protected equipment. Keeplaway from sources of ignition - No smoking, Avoid dust generation. Dust
explosion possible in. the presence of air. Use non -sparking tools in area's where explosive dust. air mixtures may
occur. Do not cut or weld on or near this container even when empty.
Conditions for safe storage
Store in accordance with1ocal/national regulations. Keep away from food, drink and animal feedingstuffs. Store in a
dry well ventilated place away from sources of heat and direct sunlight. Store separate from other chemicals. Keep
only In -the original container.
Storage
For'maximurn quality store below,': 20'C.
For safety, store below 3U °C.
Other information
It is recommended to use electrical equipment of temperature group T3. However, autoignition can never be excluded.
Wash hands thoroughly after handling or contact. Keep work clothes separate and do not take them home.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ctit'iiiiri WeTSiiinint5
Ensure good ventilation and local exhaustion of the working area. Explosion proof ventilation recommended.
Personal.protection
Respiratory
In case of dust formation use dust mask.
Hand
Wear suitable protective gloves of neoprene or synthetic rubber.
Eye
Wear eyelface protection.
Skin and body
Wear suitable protective clothing.
Other Information j
Emergency -shower and facilities for rinsing eyes must be accessible. Launder clothes before reuse.
In this country no exposure limit has been established
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9. PHYSICAL AND CHEMICAL PROPERTIES
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Material safety data sheet
DGRK®nnx iA
Appearance 1
powder
Color I
white
Odor I
faint
Boiling pointirange I
not applicable (Decomposes)
Melting pointlfreezing point I
Decomposes prior to melting.
Flash point
not applicable
Flammability
Decomposition products may be flammable.
Explosive properties I
-no-
Oxidizing properties I
not applicable
Vapor pressure I
<0.08 kPa (60'C / 140°F)
Density
1130 kg/m3(20°C /68°F)
Specific gravity = 1.13 (20°C / 68°F)
Bulk density I
450-480 kg/m' (20°C / 68°F)
Specific gravity = OA5-0.48 (20°C /
Solubility In water I
Insoluble (20°0/.687)
Solubility in other solvents I
Soluble with .aliphatic solvents.
pH value I
slightiq acidic
Partition coefficient n-octanol/watir
not determined
Relative vapor density (air-1) I
not applicable
Viscosity I
not applicable
Active oxygen.content
3.8 %
Peroxide content
95 %
Autoignition temperature
Test method not applicable (See Section 7)
SADT I
40 °C. See also Section 10.
Upper/lower flammability or ex i losive limits
not determined
Volatile %
not determined
10. STABILITY AND REACTIVITY
Product code 661451 I
I
AkzoNobel
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Material safety d l
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PERKADOX 16
Chemical stability i
SADT - (Self accelerating decomposition temperature) is the lowest temperature at which self accelerating
decomposition may occur with a substance in the packaging. as used in transport.
A dangerous self -accelerating decomposition reaction and, under certain circumstances, explosion or fire can
be caused by thermal decompositionlat and above the following temperature: 40 *C. Contact with incompatible
substances car. cause decomposition at or below the SADT 40 *C.
To insure against possible exothermic self -accelerating decomposition, storagetemperatures must riot exceed
emergency temperature of 35 'C.
Conditions
to avoid l
Under no circumstances should this product be exposed to temperatures above the emergency temperature of
35 *C. If the product temperature exceeds 35 °G all available means shall be used to bring the temperature
under control and the emergency procedures shall be started. Emergency procedures will vary depending on
conditions. Contact Akzo Nobel foriassistance with developing an emergency response plan.
To maintain quality store in original closed container below: 20 *C.
Confinement must be avoided.
Incompatible materials
Avoid contact with rust, iron and Copper.IContact with incompatiblematerials such as acids, alkalles, heavy metals
and reducing agents will result in hazardous decomposition. Do not mix with peroxide accelerators. Use only Stainless
steel 316, PP, polyethylene or glass-lihe8 equipment. Contact Akzo Nobeifor more information.
Possibility of hazardous reactions I
Polymerization does not, occur.
Hazardous decomposition products l
Hazardous decomposition products; 4-tert-Butylcyclohexanol.
Other information
Emergency procedures will vary depenl ing on conditions. The customer must have an emergency response plan in
place. Contact Akzo Nobel for assisfarice with developing an emergency response plan.
11. TOXICOLOGICAL INFORMATION I
Di(4-tert-butylcyclohexyl) peroxydicarbonate
Acute toxicity
Oral LD50
LD50 (rat):> 5000 mg/kg (OECD 401)
Germ cell mutagenicity
G�e15..�. n �ilT..t'.:�. d?,.t8 Fh� I lwsslficaticn nri4cAa aw.^t
met.
STOT - repeated exposure l v v „ v
28 days (oral) : No Observed' Adverse Effect Level (NOAEL): 500 mglkg/day (Target organs: liver, thyroid).
(OECD 407)
Irritation l
Skin i
Non -irritating (24 hours exposure time ) (OECD 404)
Eye
Mildly irritating (similar to OECD 405).
GHS classification : Mildly irritating to eyes (category 2B).
Sensitization
Sensitizing (skin) (OECD 429)
Genotoxicity
in vitro:
similar to OECD 471: Negative.
OECD 476; Negative.
OECD 478:Negative.
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12. ECOLOGICAL INFORMATION
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Product code 661451
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Material safety data sheet
IF
AkzoNobel
.,
Di(4-tort-butyicyclohexyl) peroxydicarbonate
Ecotoxicity
fish
96h-LC50 (Oncorhynchus mykiss): 704 mg/I. (OECD 203)
No Observed Effect Concentration.(NOEC) (96h):320 mgA.
daphnia I
48h-EC50 (Daphnia magna): 42 mg/il
(OECD 202)
algae
72h-IC50. (Desmodesmus subspicatus ): approx. 39 mgA.,(OECD 201)
No Observed Effect Concentration (NOEC) (72h ):, 17 mgA.
LOEC (72h ): 39mgA. I
bacteria j
No Observed Effect Concentration (NOEL) (5 days): 20 mgA. (similar to OECD 301 D)
Fate I
Degradation Abiotic
Hydrolysis: Stable in water.
Degradation. Biotic j
Not readily biodegradable (Closed bottle test ). (OECD301 B)
Bioaccurnulation
Bio Concentration Factor (BCF): 2926 'L/kg.
Fate 1
Log Pow: 5.08 I
13. DISPOSAL CONSIDERATIONS
Product
Due to the high risk of contamination rdcycling/recovery is not recommended. Waste disposal in accordance with
regulations (moat probably controlled incineration).
Contaminated packaging 1
According to local regulations. Emptied container might retain product residues. Follow all wamings even after the
container Is emptied. Do not wash residues into drains or other waterways.
h.-ar:dat'o^
For furtherdvice contact manufacturer.
14_ TRANSPORT 1MFORMATrON I
Land transport I
Transport hazard class
5.2 1
TREM-Card or ERG number I
NA ERG No: 148
UN number
3114
Proper Shipping Name
Organic peroxide type C, solid, temperature controlled ( DI(4-tert-butylcyclohexyl) peroxydicarbonate, 95% )
Other information
This product does not contain an environmentally hazardous substance per 49 CFR 172.101, Appendix A.
Required labels
5.2
EMERGENCY TEMPERATURE: 3'5 *C.
Product code 661451 i Date of last issue2014105104 Page 6 - 8
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Material safety data I sheet
AkzoNobel
EPA Reactive
yes
EHS Material
no
Hazard Rating Source
HMIS
HMIS Health
1
HMIS Flammability
3
HMIS Reactivity
2
WHMIS Hazard classes
C,D-2BIF
:(D•
I
Other regulatory information
This product has been classified in accordance with the hazard criteria, of the Controlled Products Regulations and the
MSDS contains all of the information req'ttired by the Controlled Products Regulations.
1R' OTHFR INFr1R1 ATIONI I
History
Other information
PERKADOX: This is a registered tradejnark of Akzo Nobel Chemicals BV or any of its affiliated companies in one or
more territories in the world.
Date of printing! I
pdf file generated
2014/06/03
Revision I
3',05
'Composed by
Regulatory Affairs - North America, I +1-312-544-7000.
Regulatory Affairs - Europe,
Changes were made insection
GHSIEU Classification; not relevantlto NAFTA
The informatlpn In this material safety data sheet should be provided to all who will use, handle, store, transport or otherwise be exposed to this product All information
concerning this product andfor suggestions for handling and use contained herein are offered In good faith and are believed to be reliable as of the date of publication. However,
no warranty Is made as to the accuracy of andfor sufficiency of such information andfor suggestions as to the.merchantabifiry or fitness of the product for any particular purpose,
or that any suggested use will not infringe any patent! Nothing in here shelf be construed as granting or extending any license under any patent. Buyer must determinefor
himself, by preliminary tests or otherwise, the suitability of this product for his purposes, including mixing with other products. The Information contained herein supersedes all
previously issued bulletins on the subject matter covered. If the date on this document is more than three years old, call to make certain that ibis sheet is current
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Product code 661451
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4
C N
urBy
WoMLeader in it Technology
WHMIS (Canada) NFPA (USA)
0
Fire
Yyt2
Health 4 r
B-2 D-2A D-2B
Specific hazard
materiai suety beta sheet
MSDS #: 16662V2
HMIS (USA)
Protective clothing
° 2
�ysic�I hatarclsl Y
ersonal protection X
Section 1. Chemical product and company identification
Trade name L704-NET-14
Product type Polyester Resin Solution
Chemical family Aromatic. 1
Material uses Used in the manufacture of thermoset plastic parts.
Manufacturer AOC, LLC l
In case of emergency
950 Highway 57 East
Collierville, TN U.S.A. 38017
CHEMTREC (US): 24 hours/7 days (800) 424-9300
Website: www.aoc-resins.com
CANUTEC (Canada): 24 hours/7 days (613) 996-6666
Phone Number. (901) 854-2800
8am-5pm (Central Time) Mon -Fri
Section 2. Hazards identification I
OSHA status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Routes of entry Eye contact, Skin contact, Inhalation, Ingestion
i
Potential acute health Eyes: Severe eye irritant which may result in redness, burning, tearing and blurred vision.
effects Skin: Skin irritant may result in burning sensation. Repeated or prolonged skin contact may cause
�Ihich
dermatitis.
Ingestion: Ingestion may result in mouth, throat and gastrointestinal imiation, nausea, vomiting and diarrhea.
Inhalation: Inhalation of spray mist or liquid vapors may cause upper respiratory irritation and possible central
nervous system effects including headaches, nausea, vomiting, dizziness, drowsiness, loss of coordination,
impaired judgement and general weakness.
Potential chronic health CARCINOGENIC EFFECTS:
effects S rene:
Classified A4 (not classifiable for human or animal) by ACGIH.
Classified 2B (possible for human) by IARC.
Classified as "reasonably anticipated to be a human carcinogen" by NTP.
An increased incidence of lung tumors was observed in mice from a recent inhalation study. The relevance of this
finding is uncertain since data from other long-term animal studies and from epidemiology studies of workers
exposed to styrene do not provide a basis to conclude that styrene is carcinogenic to humans.
Silica. Amorphous:
Classified 31(not classifiable for human) by IARC.
MUTAGENIC or TERATOGENIC EFFECTS: No known effect according to our database.
Effective Date: 02/0812013 1. Supersedes Date: 10/29/2012 Page:115
Section 3, Compositionlinformation on ingredients
Name
1) Styrene
2) Silica, Amorphous
Section 4. First aid measures
Eye contact Flush with a continuous
Use of buffered baby 0
Skin contact Gently and thoroughly H
persists, seek medical a
Inhalation Move the victim to a sale
breathing is difficult, givE
immediate medical atten
Ingestion Do not induce vomitinnl
1
L704-NET-14
CAS # % by weight
100.42-5 40.7
7631-86-9 1 1-5
of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.
oo will aid in removal. Seek medical attention.
the contaminated skin with running water and non-abrasive soap. If irritation
area as soon as possible. Allow the victim to rest in a well -ventilated area. If
oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek
Seek immediate medical attention.
Section 5. Fire -fighting measures /
The product is:
Flammable liquid, Class IC.
- Auto -ignition temperature
914°F(490-C) Sty ene
Flash point
87.6°F (31 °C) Styrene
-. Flammable limits
Lower: 0.9% Upper: 6.8% (Styrene)
Products of combustion
May produce carbon monoxide, carbon dioxide, and irritating
'
or toxic vapors, gases or particulate.
Fire hazard
Flammable in the presence of open flames, sparks, or heat
Explosion hazard
Can react with r'oxidizing materials. Explosive in the form of vapor when exposed to heat or flame. Material may
Polymerize when container is exposed to heat (fire) and polymerization will increase
pressure in a closed
container which may cause the container to rupture violently.
Fire -fighting media and
SMALL FIRE: Use carbon dioxide, foam, dry
instructions
chemical or water fog to extinguish.
LARGE FIRE: Evariiata s-.rc;,.;;ding
areas Usa
Wear carbon dioxide, foam, dry chemical or water fog to extinguish.
self-contained breathing apparatus (SCBA) and full fire -fighting
protective clothing. Cool containing
vessels with water spray in order to prevent pressure build-up, autoignition or explosion. Prevent run off to
sewers or other water ways.
Section 6. Accidental release measures
Small spill
Absorb with an inert material and place in an appropriate waste disposal container.
Large spill
Stop leak if without risk. Eliminate all ignition sources. Contain with an inert material, recover as much as
possible and place the remainder in
an appropriate waste disposal container. Warn unauthorized personnel to
move away. Prevent entry into sewers or confined areas.
Section 7. Handling and
-------------
Handling
Effective Date: 02/08/2013
WARNING! Use only in well -ventilated areas. Store away from direct sunlight. Avoid inhalation and contact
with eyes, skin, and clothing. Wear appropriate personal protective equipment for your task. Ground and bond
all containers when transferring the material. Empty containers may retain product and product vapor. Do not
expose to heat, flame, sparks or other ignition sources such as cutting, welding, drilling, grinding or static
electricity. Do not pressurize. Provide adequate safety showers and eyewashes in the area of use,
1
Supersedes Date: 10/29/2012
Page: 215
" J=MSDS#16662V2
I U04•NET•14
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Section 7. Handling and storage
Storage
Keep away from heat. Keep away from sources of ignition. Keep container tightly closed. Keep in a cool, well -
ventilated place. Containers should be grounded.
Section 8. Exposure controls/personal protection
Exposure limits
Styrene I ACGIH TLV (United States, 312012). Absorbed through skin.
TWA: 20 ppm 8 hour(s).
TWA: 85 mg/m' 8 hour(s).
STEL: 40 ppm 15 minute(s).
STEL:170 mg/m' 15 minute(s).
OSHA PEL Z2 (United States,11/2006).
TWA: 100 ppm 8 hour(s).
AMP: 600 ppm 5 minute(s).
CEIL: 200 ppm
NIOSH REL (United States, 6/2009).
TWA: 50 ppm 10 hour(s).
TWA: 215 mglm' 10 hour(s).
STEL:100 ppm 15 minute(s).
STEL: 425 mglm' 15 minute(s).
Silica, Amorphous NIOSH REL (United States, 6/2009).
i TWA: 6 mg/m' 10 hour(s).
Engineering controls
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below
their respective occupational exposure limits. Provide adequate safety showers and eyewashes in the area of
use. I
Personal protection
Personal protective equipment may vary depending on the job being performed.
Eye/face: Wear eye protection such as safety glasses with side shields, splash goggles or face shield with
safety glasses.
Skin: Avoid skin contact. Impervious gloves should be wom. Other items may include long sleeves, lab coats,
or impervious jackets. 11
Respiratory: Determine if airbome concentrations are below the recommended exposure limits in accordance
your company's PPE program and regulatory requirements. If they are not, select a NIOSH-approved
respirator that provides adequate protection from the concentration levels encountered. Air -purifying respirators
are generally adequate for organic vapors. Use positive pressure, supplied -air respirators if there is potential
for an uncontrolled release, if exposure levels are unknown, or under circumstances where air -purifying
respirators may not provide adequate protection.
Reference OSHA. 29 CFR 1910.134.
Personal protection in case
Chemical resistant gloves, full protective suit, and boots. Respiratory in accordance OSHA
of a large spill
protection with
regulation 29 CFR 1910A34. A self-contained breathing apparatus should be used to avoid inhalation of the
r, o .
prvduc1, .�...��r.`�i I 9
Section 9. Physical and chemical properties)
Physical state
Liquid. I
Color
Clear to Amber.
Odor
Aromatic.
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Molecular weight (glmol)
1000 to 15000 I
Boiling point
293°F(1450C) Styrene
Melting point
Not available.
pH (1% soln/water)
Not applicable.
Vapor pressure
4.5 mm Hg@ 68°F (20°C) Styrene
Vapor density
3.59 Styrene (Air=i1)
Specific gravity
1.1 (Water =1)
Partition coefficient: n•
Not available.
octanol/water
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Effective Date: 02/08/2013
i Supersedes Date: 10/29/2012 Page: 3/5
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• - L -
• fDispersibility
on 9. Physical and chemical P rte t-
ration rate Not available.
• hreshold 0.14 ppm Styrene
lity in water Slight.
properties Not dispersed in water.
Section 10. Stability and reactivity
Stability This product is normally stable,
polymerization, which could prc
container.
Instability temperature >170°F (77°C
L704•NET 14
can become unstable at elevated temperatures and undergo
s heat and fumes resulting in over -pressurization and rupture in a closed
Conditions of instability Heat. I
i
Incompatibility with various Polymerizes in the presence of (organic peroxides, oxidizing materials, or heat.
substances
Corrosivity
Our database contains no additional remark on the corrosivity of this product
Section 11. Toxicological information I
Toxicity to animals Name
• I Result Species Dose
Styrene . _ _ I Exposure
LD501ntraperitoneal Rat 898 mglkg
i LD50 Oral Rat 5000 mg/kg
LD50 Oral Rat 2650 mg/kg _
TDLo Dermal Rat 26.4 mg/kg
LC50 Inhalation Rat 11800 mg/m3 4 hours
Vapor
LC50 Inhalation Gas. Rat 2770 ppm 4 hours
Special remarks on toxicity Lung effects that have been observed in mouse studies have been shown in some studies to be the result of
to animals mouse specific enzymes (not in humans) that enable the mechanism cancer in mice.
Special remarks on chronic A study of tong term effects of workers exposed to styrene levels in the range of 25-35 ppm, 8 hour TWA,
effects on humans indicated a possible mild hearing loss.
Special remarks on other No additional remark,
nwmm�s I
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Section 12. Ecological information
Ecotoxicity
Toxic to aquatic organisms. Should not be released to sewage system or other bodies of wafer at
concentrations above limits established in regulations or permits.
Section 13. Disposal considerations
' [Waste disposal
Recycle to process, if possible. Consult your local or regional authorities. Ignitable characteristic.
Section 14. Transport information
DOT UN1866; Resin Solution; 3; Ill. Labels
TOG
UN1866; Resin Solution; 3; III<*>
I
IATA/lMDG UN1866; Resin Solution; I!3; 111
Effective Date: 02/08/2013
I Supersedes Date: 10/29/2012
_ Page: 4!5
MSDS #: 16662V2 L704-MET•14
Section 14. Transport information i
Additional information US regulations require the reporting of spills when the amount exceeds the Reportable Quantity (RQ) for
specific components of this material. See CERCLA in Section 15, Regulatory Information, for the Reportable
Quantities.
Section 15. Regulatory information
Other regulations This section does not reference all applicable regulatory compliance lists.
TSCA: All ingredients are listedlor compliant with TSCA.
DSL: All ingredients are listed or compliant with the NSNR.
Proposition 65 Warning: This product contains a chemical(s) known to the State of California to cause
cancer, birth defects and/or reproductive harm.
SARA 302 component(s): None.
SARA 313 component(s): Styrene.
CERCLA(RQ): Styrene - I000 lbs. (453.6 kg)
Section 16.Other information I
Prepared by AOC, LLC - Corporate Regulatory Affairs. Ca
LEGAL DISCLAIMER
The information contained in this data sheet is furnished ini good faith and without warranty, representation, or inducement or license of any
kind, except that it is accurate to the best of AOC, LLC's knowledge, or was obtained from sources believed byAOC, LLC to be reliable. The
accuracy, adequacy or completeness of health and safe precautions set forth herein cannot be guaranteed, and the buyer is solely
responsible for ensuring that the product is used, handled, stored, and disposed of safely and in compliance with applicable federal, state or
provincial, and local laws. AOC, LLC disclaims liability f i any loss, damage orpersonal injury that arises from, or is in any way related to, use
of the information contained in this data sheet.
Effective Date: 02/08/2013
Supersedes Date: 10/29/2012
Page: 515
BY
SAFETY DATA SHEET
CATALYST TRIGONOX C 22307
Page: 1
Revision Date: 01/24/2008
Print Date: 5/16/2008
MSDS Number: R0004997
Version: 1.4
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
OM]PANY/UNI)ERTAKING
Ashland
P.O. Box 2219
Columbus, OH 43216
Product name
Product code
Product Use Description
2. HAZARDS
Information Number
telephone
CATALYST TRIGONOX C
22307
No data
- Emergency Overview I
Appearance: liquid„ Colorless 0 slight yellow
Potential Health Effects
Routes of exposure
Inhalation, Skin al
Eye contact
Can cause permanc
and swelling of eyes. Can
Skin contact
Can cause severe
skin, and other skin damp
1-800-325-3751
614-790-3333
1-800-ASHLAND
(1-800-274-5263)
ion, Skin. contact, Eye Contact, Ingestion
eye injury. Symptoms include stinging, tearing, redness,
ure the cornea and cause blindness.
irritation. Symptoms may include redness and burning of
Ingestion
Swallowing small amounts of this material during normal handling is not likely to
cause harmful effects. Swallowing large amounts may be harmful. Exposure causes
severe irritation of the gastrointestinal tract.
i
Inhalation
i
It is possible to breathe this material under certain conditions of handling and use
(for example, during hearing, spraying, or stirring). Breathing small amounts of this
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SAFETY DATA SHEET i Revision Date: 01/24/2008
Print Date: 5/16/2008
" - CATALYST TRIGONOX C 2230MSDS Number: R0004997I7 Version: 1.4
material during normal handling is of likely to cause harmful effects. Breathing large
amounts may be harmful.
Aggravated Medical Condition
Preexisting disorders of th following organs (or organ systems) may be
aggravated by exposure to this material:, Skin, lung (for example, asthma -like conditions)
Symptoms
Signs and symptoms of exposure to this material through breathing, swallowing,
and/or passage of the material through the skin may include:, stomach or intestinal upset
(nausea, vomiting, diarrhea), irritation (nose, throat, airways), headache, dizziness
Target Organs
No data
Carcinogenicity
• - This material is not listed as a carcinogen by the International Agency for
Research on Cancer (IARC), the National Toxicology Program (NTP), or the
Occupational Safety and Health Administration (OSHA).
Reproductive hazard
Based on the available information, risk to the fetus from maternal exposure to
this material cannot be assessed.
3. COMPOSITIONANFORMATION ON INGREDIENTS_
Components I rA C-Na �•__ _ _ __ ..
�.uucCulra[lUn
T-BUTYL PERBENZOATE 614-45-9 <=100%
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4. FIRST AID MEASURES
Eyes
If material gets into the eyes, immediately flush eyes gently with water for at least
15 minutes while holding eyelids apart. If symptoms develop as a result of vapor
exposure, immediately move individual away from exposure and into fresh air before
flushing as recommended! above. Seek immediate medical attention.
Skin
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SAFETY .DATA- SKEET �' Revision Date: 01/24/2008
Print Date: 5/16/2008
CATALYST TRIGONOX C 22307 MSDS Number: R0004997Version: 1.4
Remove contaminated clothing. Flush exposed area with large amounts of water.
If skin is damaged, seek immediate medical attention. If skin is not damaged and
symptoms persist, seek medical attention. Launder clothing before reuse.
Ingestion
Seek medical attention. If individual is drowsy or unconscious, do not give
anything by mouth; place individual on the left side with the head down. Contact a
physician, medical facility, or poison control center for advice about whether to induce
vomiting. Ifpossible, do not leave individual unattended.
Inhalation
If symptoms develop, immediately move individual away from exposure and into
fresh air. Seek immediate medical attention; .keep person warm and quiet. If person is
not breathing, begin artificial respiration. If breathing is difficult, administer oxygen.
Notes to physician
• . Hazards: No informati I n available.
Treatment: No information available.
5. FIRE -FIGHTING MEASURES
.. I
Suitable extinguishing media
Foam, Dry chemical, Water spray, Carbon dioxide (CO2)
Hazardous combustion products
May form:, carbon dioxide and carbon monoxide, hydrocarbons
Precautions for fire -fighting
If product is heatedI1 Bove its flash point it will produce vapors sufficient to
support combustion. Vapors are heavier than air and may travel along the ground and be
iaanited by heat, pilot lights, flames and ignition sources at locations near the point
of release. Substance is an oxidizer that will cause moderate increase in the burning rate
of combustible materials with which it comes into contact. Never use welding or cutting
torch on or near drum (even empty) because product (even just residue) can. ignite
explosively. Wear full firefighting turn -out gear (full Bunker gear), and respiratory
protection (SCBA). Use water spray to cool fire exposed containers and structures until
fire is out if it can be done with minimal risk. Avoid spreading burning liquid with water
used for cooling purposes.
Flammability Class for Flammable Liquids
Combustible Liquid Class IIIA
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'ASHLANO.
SAFETY DATA SHEET
• i
CATALYST TRIGONOX C 22307
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16. ACCIDENTAL RELEASE MEASURES
Personal precautions
For personal protection
should be excluded from area c
Environmental precautions
No data
Methods for cleaning up
Immediately soak up
sparking equipment after we
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Revision Date: 01/24/2008
Print Date: 5/16/2008
MSDS Number: R0004997
Version: 1.4
section 8. Persons not wearing protective equipment
ill until clean-up has been completed.
with perlite or vermiculite. Sweep up°with non -
down with 10% NaOH.
Handling
Containers of this interial may be hazardous when emptied. Since emptied
containers retain product residues (vapor, liquid, and/or solid), all hazard precautions
given in the data sheet mustlb.e observed. Static: ignition:hazard.can result,from,handling
and use. Electrically bond and ground all containers, personnel and equipment before
transfer or use of material. ISpecial precautions may be necessary to dissipate static
electricity for non-conductive containers, Use proper bonding and grounding during
product transfer as described in National Fire Protection Association document NFPA 77,
Storage j
Store below 27 degrees C (80 degrees F) in original container. Store out of direct
sunlight away from incompatible and en,mh„s�hiA yat_^^'� r _r _ — 1T
�..u=,. L�viol w National sire
Protection Association (NFPA) Code 432, Code for the Storage of Organic Peroxide
Formulations. I
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8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
General advice
These recommendations provide general guidance for handling this product,
Personal protective equipment should be selected for individual applications and should
consider factors which affect exposure potential, such as handling practices, chemical
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• SAFETY DATA SHEET _ Revision Date: 01/24/2008
Print Date: 5/16/2008
MSDS Number: R0004997
CATALYST TRIGONOX C 22307 Version: 1.4
concentrations and ventilation. It is lultimately the responsibility of the employer to
follow regulatory guidelines established by local authorities.
Exposure controls I
Provide sufficient mechanical (general and/or local exhaust) ventilation to
maintain exposure below level of overexposure (from known, suspected or apparent
adverse effects).
Eye protection
I
Chemical splash goggles inl compliance with OSHA regulations are advised;
however, OSHA regulations also permit other type safety glasses.. Consult your safety
representative.
Skin and body protection
Wear resistant gloves (consult your safety equipment supplier).
To prevent repeated or prolonged skin contact, wear impervious clothing and boots.
IRespiratory protection
If overexposure has been determined or documented, a.NIOSH-approved air
supplied respirator is advised in absence of proper environmental control. OSHA
regulations also permit other NIOISH respirators under specified conditions. (See your
safety equipment supplier.) Engineering or administrative controls should be
implemented to reduce exposure,j
1 9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state
Form
Colour
Odour
Boiling point/boilingrange
Melting point/range
PH
Flash point
Evaporation rate
Explosion limits
Vapour pressure
Vapour density
Density I
Solubility
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liquid
K
Colorless to slight yellow
Mild aromatic odor
75.00 - 76.00 °C / 167 - 169 OF@ 0.02 kPa
46°.F/8°C
No data
144.99 OF / 62.77 °C
No data
No data
0.04 kPa @ 122 OF / 50 °C
6.700 (AIR=1)
1.021 g/cm3 @ 77 OF / 25 °C
8.651b/gal @ 77 OF / 25 °C
No data