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Home My WebLink AboutMATERIAL SAFETY DATA SHEETI •.0 ,asp { FIL 40App^NpNED �COPY ° A e' V�&®?COy Page 1 of 6 �LHO MATERIAL SAFETY DATA SHEET SECTION I - IDENTIFICATION --------------------------------------------------------------------------- TRADE NAME: STYPOL 040-0004 DESCRIPTION: STYRENE MONOMER, 20-40 PPM TBC PRODUCT CODE IDENTITY: 0400004R1 NPCA HMIS RATING: H 2* F 3 R 12 COMPANY NAME: CCP COMPOSITES US. ADDRESS: 820 E. 14TH AVE. N. KANSAS CITY IMO 64116 CUSTOMER: LAST REVISED: 10/03/2011 PRINT DATE: 03/12/2012 CCP COMPOSITES US. PRODUCT STEWARDSHIP INFORMATION TELEPHONE: COMPOSITES: 1-800-821-3590 POLYMERS: 1-800-488-5541 ATTENTION: 24 HOUR RESPONSE NUMBER (CHEMTREI): 1-800-424-9300 (NORTH AMERICA) 001-703-527-3887 (INTERNATIONAL) FOR MEDICAL EMERGENCIES (PROSAR): 1-800-269-9906 -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- I CCP certifies that its productslcomply with all the provisions of the Toxic Substances Control Act (TSCA), unless otherwise stated by ingredient in Section II. ------------------------------- ** The percent by weight composition data given in Sections II *** *** and X are NOT SPECIFICATIOiS, but are based on 'target' *** *** formula values for each in�giedient in the product. The .data *** *** are presented as ranges for low hazard ingredients and single *** *** point values for ingredients of regulatory concern. Actual *** *** batch concentrations willlvary within limits consistent with *** *** separately established.pr duct specifications. *** ---------------------------------I------- I ------------------------------------ SECTION I INGREDIENTS -------------------------------- ------------------------------------------ 1 CAS# 000100-42-5 STYRENE MONOMER PCT BY WT: 100.0000 VAPOR PRESSURE: 4.500 MMHG @ 68F EXPOSURE LIMIT: ACGIH TLV/TWA: 20 PPM (85 MG/CU.M.) ACGIH TLV/STEL: 40 PPM (170 MG/CU.M..) OSHA PEL%TWA: . 100 PPMI(8 HR TWA) OSHA PEL/CEILING: ACCEPTABLE MAX. PEAK: 600 PPM (5 MIN IN ANY 3 HRS) OSHA PEL/STEL: ACCEPTABLE CONCENTRATION: 200 PPM (15 MIN TWA) LD50, Oral: 4.37 GAG (RAT) LD50, Dermal: >5 G/KGI(RABBIT) OTHER: LCLo: 5000 PPM/8H (RAT), OTHER (cont.): NIOSH TWA: 50 PPM (215 MG/M3) OTHER LIMITS: IARC - Group 2B See Section V I NTP - Reasonably Anticipated to be a Human Carcinogen **!e*ir**ir***Yr:Fk*k:Y*t*yc**it**•k*•k**Yc�**********t****:Mir****ir*F*ic********ir*F*F**** This product contains one o!r more reported carcinogens or suspected carcinogens which are noted by NITP, IARC, or OSHA-Z in the appropriate subsection above under OTHER LIMITS. **Yr ix h*;F****ir***•k!r*t*:k*****:Frr****�****;F***:F*F*iC********ir*ic*:t ;t �e ;h****ic********* This substance is classified. as a hazardous air pollutant. ******ir•kir***•kk***�r****a'r***Vr*:c***i**********ir*yr is**•k******,***:F Yc :M**Y; k t is is***ic*** ------------------------- ----------------------------------------- SECTION III PHYSICAL DATA ---=--------------------------- ------------------------------------------- I I I M Page 2 of 6 * STYPOL 040-0004 * MATERIAL SAFETY DATA SHEET * G400004R1 Boiling Range: High- -N/A F Low- 293.0 F Vapor Pressure: See Section II Theoretical Weight per Gallon, Calculated: 7.5300 LB/GL Theoretical Specific Gravity, CalcLated: .905 Theoretical VOC, Calculated: 7.530 LB/GL --If applicable , see Section X for further VOC information -- Physical State: LIQUID Appearance: CLEAR, COLORLESS Odor: CHARACTERISTIC STYRENE Odor Threshold: -N/A pH: -N/A Freezing Point: -N/A Water Solubility: INSOLUBLE Coefficient of Water/Oil Distribut'on: -N/A Mechanical Impact Explosion: NO KNOWN HAZARD Static Electricity Explosion: AVO D STATIC CHARGE % HAP BY WEIGHT 100.000 MONOMER BY WEIGHT 100.000 --------- ---------- ---------- ------------------------------- --------------- --SECTION-IV--FIRE PiND EXPLOSION HAZARD DATA --------------- -------------------------------------------- FLAMMABILITY CHARACTERISTICS: Lowest Closed Cup Flashpoint: 88.0 degrees F • For Flash Points 73 to 100 deg. F. OSHA Flammability Classificatio : Class IC DOT Flammability Classification: Flammable Liquid Lower Flammable Limit in Air: Lower- 1.1 o by volume .% DOT Shipping Name: UN2055, STYRENE MONOMER, STABILIZED, 3,PG III EXTINGUISHING MEDIA: I Foam, carbon dioxide, dry chemical, water fog. UNUSUAL FIRE AND EXPLOSION HAZARDS: If polymerization takes place in a. container, there is possibility of violent rupture of the container. Vapors are uninhibited and may form polymers in vents or flame arres ors .of storage tanks resulting in stoppage of vents.. Vapors may cause flash fire. Keep containers tightly closed and isolate from eat, electrical equipment, sparks and flame. Never use welding or cutting torch on or near drum (even empty) because product (even just residie) can ignite explosively. SPECIAL FIRE FIGHTING PROCEDURES: Full protective equipment including self-contained br.eathinq apparatus should be used. Water spray may The ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible auto -ignition or explosion when exposed to extreme heat. ADDITIONAL TRANSPORTATION INFORMATION: Freight Classification: Page 3 of 6 * STYPOL 040-0004 * MATERIAL 'SAFETY DATA SHEET * 0400004R1 ****************************************** NMFC: 46750 STYRENE LTL CLASS 70 --------------------------------- j V HEALTH HAZARD DATA ----------------------------=----------------------------------------- EFFECTS OF EXCESSIVE OVEREXPOSURE.I PRIMARY ROUTES OF ENTRY ARE: EYE CONTACT: Irritation. Symptoms are tearing, redness and discomfort. SKIN CONTACT: irritation. Can cause defatting of skin which may lead to dermatitis. INHALATION: Irritation to nose and throat. Extended or repeated exposure to con- centrations above the recommended exposure limits may cause brain or nervous system depression, with, symptoms such as dizziness, headache or nausea and if continued indefinitely, loss of consciousness, liver and kidney damage. Reports have associated repeated and prolonged occupational over- exposure to solvents with permanent brain and nervous system damage. INGESTION: May cause mouth, throat, esophagus and stomach irritation, nausea, vomiting and diarrhea. Aspiration into lungs can cause pneumonitis which can be fatal. MEDICAL CONDITIONS THAT MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. Preexisting eye, skin, liver, kidney and respiratory disorders. EMERGENCY AND FIRST AID PROCEDURES: In case of eve contact, flush immediately with plenty of water for at least 15 minutes and get medical attention; for skin, wash thoroughly with soap and water. If affected by inhalation of vapors or spray mist, remove to fresh air. If swallowed, get medical attention immediately. Aspiration into lungs can cause pneumonitis which can be fatal. Based on the presence of components (01) CALIFORNIA PROPOSITION 65 INFORMATION: WARNING - This product contains chemical(s) known to the State of California to cause cancer. OTHER HEALTH HAZARDS: STYRENE MONOMER The 12th Report on Carcinogens Lsued by the National Toxicology Program lists styrene as a "reasonably anticipated" carcinogen, but the Report cautions that the NTP listing does not mean that. styrene presents a risk to persons in their daily lives. The Styrene Information and Research Center_ does not agree with the classification as it did not include a review of all available data. SIRC states: "HHS included styrene in the l2t RoIC �._ ..., despite C11-l1.-' idC';: that European Union regulators have determined styrene does not represent a human cancer concern. E.U. scientists reviewed the full styrene database, weighing all of the available data in reaching their conclusion." The International Agency for Research on Cancer (IARC) has reclassified styrene as Group 2B "possibly carcinogenic to humans". This new classification is not based on new health data relating to either humans or animals, but on a change in the IARC classification system. The Styrene Information and Research Center does not agree with the reclassification and has published the following statement. "Recently published studies tracing 50,000 workers exposed to high occupational levels of styrene over a period;of 45 years showed no association between styrene and cancer, no increase in cancer among styrene workers: (as opposed to the average among all workers), and no increase in mortality related to stvrene!" i An increased incidence of lung tumors was observed in mice from a recent inhalation study. The relevance of this finding is uncertain. Data from other long-term animal studies and from epidemiology studies of workers exposed to styrene do not provide a basis to conclude that r ' ' Page 4 of 6 * STYPOL 040-0004 MATERIAL' SAFETY DATA SHEET * 0400004R1 styrene is carcinogenic. Lung effects have been observed' in the mouse following repeated exposure to styrene. ---------------------------- SECTION VI REACTIVITY DATA ---------------------------------=-------------=--------------------------- STABILITY: Stable HAZARDOUS POLYMERIZATION: May occur. CONDITIONS TO AVOID: Elevated temperatures. INCOMPATABILITY (MATERIALS TO AVOIiD): Oxidizers, reducing agents, peroxides, strong acids, bases, UV light, or any source of free radicals and mild steel. HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition or combusjj��ion can produce fumes containing organic acids, carbon dioxide and car= monoxide. ---------------- ----- ------SECTION-VII--SILL OR LEAK PROCEDURES -------------- -------------------------------------- STEPS TO BE TAKEN IN CASE MATERIAL[(Avoid IS RELEASED OR SPILLED: Remove all sources of ignition flames, hot surfaces, and electrical, static, or frictional sparks). breathing vapors. Ventilate area. Contain and remove with inert absorbent and non -sparking tools. WASTE DISPOSAL METHOD: Dispose of in accordance with local, state and federal regulations. Do ---not incinerate closed containers. Incinerate in approved facility. ----------------------------T ---------------------------------------- ----------------SECTION VIII SPECIAL PROTECTION INFORMATION --------------------------- ----- ---------------- RESPIRATORY PROTECTION: Do not breathe vapors or spray mist. Wear an appropriate, properly fitted respirator (NIOSH/MSHA approved) during application and other use of this product until vapors ands mists are exhausted, unless air moni- toring demonstrates vapor and mist levels are below applicable limits. Follow respirator manufacturer's directions for respirator use. Observe OSHA Standard 29CFR 1910.134. VENTILATION: Provide general clean air dilution or local exhaust ventilation in volume and pattern to keep the air contaminant concentration below the lower explosion limit and below current applicable exposure limits. Refer to OSHA SLd[Iddrd 1910.94. NOTE: Heavy solvent vapors should be removed from lower levels of the work area and all ignition sources (nonexplosion-proof motors, etc.) should be eliminated. PROTECTIVE GLOVES: Use solvent impermeable gloves tip avoid contact with product. EYE PROTECTION: Do not get in eyes. Use safety eyeo-:ear with splash guards or side shields, chemical goggles, face shields. OTHER PROTECTIVE EQUIPMENT: i Avoid contact with skin. Use protective clothing. Prevent contact with contaminated clothing. Wash contaminated clothing, including shoes, before reuse. ----------------------------------- --------------------------------------- SECTION IX SPECIAL PRECAUTIONS -----------------------------------7--------------------------------------- * STYPOL 040-0004 MATERIAL SAFETY DATA SHEET 0400004R1 PRECAUTIONS TO BE TAKEN IN HANDLIN Do not store above 100 deg. F. designed to comply with OSHA 19 flame. Keep containers closed leakage. OTHER PRECAUTIONS: Containers should be grounded V. Wash hands after using and befo. may retain hazardous residue an sparks and flames. Do not cut, tainers. Follow all hazard pre container is thoroughly cleaned blended with other components s' catalysts prior to use, read al ponents will have hazards of al. If spraying this material, keep spray dust or overspray in boot: KEEP OUT OF REACH OF CHILDREN Page 5 of 6 AND STORING: Store large quantities in buildings 0.106. Keep away from heat, sparks and hen not in use and upright to prevent en pouring. Do not take internally. e smoking or eating. Emptied containers explosive vapors. Keep away from heat, puncture or weld on or near emptied con- autions given in this data sheet until or destroyed. If this product is ch as thinners, converter, colorants and warning labels. Any mixture of com- components. Follow all precautions. spray booths clean. Avoid buildup of s or ducts. FOR INDUSTRIAL USE ONLY --------------------------------------------------------------------------- SECTION X Sara Title III Information ---------------------------------- 4---------------------------------------- SARA 313 INFORMATION: This product contains the fol_ reporting requirements of Section Amendments and Reauthorization Act STYRENE MONOMER CAS# 000100-42-5 PCT BY WT: 10( ----------------------------------- CCP C( LIMITED WARRANTY ANI LIMITED WARRANTY. Seller warrants 1 to the product sold hereunder, (iiJ to Seller's specifications for the such product will not infringe the product itself, but Seller does not might arise by the use of said pro( products or .arising in the operatic SELLER MAKES NO OTHER WARRANTY OF I WITHOUT LIMITATION ANY WARRANTY OF PARTICULAR PURPOSE, EVEN IF THAT P1 REPRESENTATIONS OR SUGGESTIONS REG! ARE BASED UPON SELLER'S GOOD FAITH CONSTRUED AS AFFIRMATIONS OF FACT, NO WAY BE DEEMED PART OF THE SALE C In particular, and without limitinc_ and use conditions beyond Seller's makes no promise concerning the re: (or the Buyer's customer) with the product. Each user should satisfy j suitability of the product for its LIMITATION OF LIABILITY. (a) Selle arising out of or in connection wit contract, warranty, statutory duty, negligence, shall not exceed the pt such liability arises. Seller shall damage, resulting from the handlinc whether in the manufacturing proces IN NO EVENT SHALL SELLER BE LIABLE DAMAGES, INCLUDING WITHOUT LIMITATI OPPORTUNITY, DOWNTIME COSTS, OR CLP owing substances subject to the 13 of Title III of the. Superfurid of 1986 and 40 CFR. Part 372:. 41IhI11ro, **r**r***xr*******x*w*x*vr***---------- MPOSITES US LIMITATION OF LIABILITY hat: (i) Buyer shall obtain good title at shipment such product, shall conform product; and (iii) the sale or use of claims of any U.S. patent covering the warrant against infringement which uct in any combination with other n of any process. VY KIND, EXPRESS OR IMPLIED, INCLUDING KERCHANTABILITY OR FITNESS FOR ANY RPOSE IS KNOWN TO SELLER. ANY ADDITIONL RDING TEE PRODUCT OR ITS POSSIBLE USES DPINION AND BELIEF, BUT ARE NOT TO BE PROMISES, OR DESCRIPTIONS, AND SHALL IN F PRODUCT. the foregoing, because of environmental control, Seller offers no warranty and ults that may be obtained by the Buyer ?roduct or .the performance of the tself; by adequate testing, of the Darticular application. is total liability for any claim Z this contract, including for breach of or for other tort, including seller's rchase price of such product as to which not be liable for any injury, loss or or use of the product shipped hereunder s or otherwise. FOR SPECIAL, INCIDENTAL OR CONSEQUENTIAL )N LOSS OF PROFITS, CAPITAL OR BUSINESS CMS OF CUSTOMERS OR EMPLOYEES OF BUYER, Page 6 of 6 * STYPOL 040-0004 MATERIAL !SAFETY DATA SHEET * 0400004RI WHETHER IN, AN ACTION UNDER CONTRACT, NEGLIGENCE OR ANY OTHER THEORY, ARISING OUT OF OR IN CONNECTION WITH THIS CONTRACT, OR THE USE, INABILITY TO USE, OR PERFORMANCE OF THE PRODUCT. (b) If Seller furnishes technical or other advice to Buyer, whether or not at Buyer's request, with respect to processing, further manufacture, other use or resale of the products, Seller shall not be liable for, and Buyer assumes all risk of, such advice and the results thereof. (Rev. 01/12)