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Home My WebLink AboutSAFETY DATA SHEETManutactwers o/ Qua4tyFbVer a Pool FhMes 0110ANNED BY Lulls SAFETY DATA SHEET 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER: GM-XXXX PRODUCT NAME: Florida GEM COMPANY ADDRESS: Florida Stucco Corp. 21195 Boca Rio Rd Boca Raton, FL 33433 Tel: 561-487-1301 2 HAZARDS IDENTIFICATION Hazard Pictogram: Signal Word: Hazard Statement: DANGER This material containing Portland cement poses immediate hazard. A single short-term exposure to the dry powder is not likely to cause serious harm. However, exposure of sufficient duration to this product can cause serious, potentially irreversible tissue (skin or eye) destruction in the form of chemical (caustic) burns. The same type of tissue destruction can occur if wet or moist areas of the body are exposed forsufficient duration to dry Portland cement. Relevant routes of Exposure Eye contact, Skin contact, inhalation, and ingestion File Coo Effects Resulting in Eve Contact -Exposure to airborne dust may cause immediate or delayed irritation or inflammation. Eye contact by large amounts of dry powder or splashes of wet Portland cement may cause effects ranging from moderate eye irritation to chemical burns and blindness. Such exposures require immediate first aid and medical attention to prevent significant damage to the eye. Effects Resulting from Skin Contact — discomfort or pain cannot be relied upon to alert a person to hazardous skin exposure. Consequently, the only effective means of avoiding skin injury or illness involves minimizing skin contact, particularly with wet cement. Exposed personnel may not feel effects until hours after exposure has ended and significant injury has occurred. Dry Portland cement contacting wet skin or exposure to moist or wet masonry cement may cause more severe skin effects including thickening, cracking or fissuring of the skin. Prolonged exposure can cause severe damage in the form of (alkali) chemical burns. Some individuals may exhibit an allergic response upon exposure to this material, possibly due to trace elements of chromium. The response may appear in varying forms ranging from a mild rash to severe skin ulcers. Person already sensitized may react on their first contact with the product. Others may experience the effect for the first time after years of contact with this material. Inhalation: Repeated or prolonged inhalation can cause Silicosis, a fibrosis (scarring) of the lungs. Silicosis may be progressive; may lead to disability or death. Studies indicate an increased incidence in -Chronic Bronchitis and Emphysema when exposed to respirable Crystalline Silica. Silicosis increases the risk of tuberculosis. Three types of Silicosis can occur: Simple Chronic Silicosis — results from a long-term exposure (more than 20 years) to low amounts of silica dust. The silica dust causes swelling in the lungs and chest lymph nodes. This disease may cause trouble breathing. Accelerated Silicosis — occurs after exposure to large amounts of silica over a shorter period of time (5-15 years). Swelling in the lungs and symptoms occur faster than in simple Silicosis. Acute Silicosis — results from short-term exposure to very. large amounts of silica. `The lungs become inflamed and can fill with fluid, causing severe shortness of breath and low blood oxygen levels. Progressive Massive Fibrosis can occur in either Simple or Accelerated Silicosis, but is more common in the Accelerated form. Progressive massive Fibrosis causes severe lung scarring and destroys normal lung structures. Lung Cancer: Crystalline silica (Quartz) is classified as a carcinogen when inhaled. Note: The State of California requires the following statement: "Airborne particles of respirable size crystalline silica are known to the State of California to cause cancer" Ingestion: Internal discomfort and ill effects are possible if large quantities are swallowed Precautionary Statement: - Do not handle until all safety data in this SDS has been read and understood - Do not breathe dust - Use respiratory protection to prevent inhalation of dust - Wear protective gloves for skin protection and safety glasses/goggles for eye protection - Do not eat, drink or smoke when in contact with this product - Wash hands thoroughly after handling. - If exposed, seek medical attention - If inhaled, move victim to fresh air and keep in comfortable position - In case of eye exposure, gently flush with water continuously for several minutes - Contaminated clothing should be rinsed and washed before reuse - Avoid creating dust when using or handling this product - Dispose of product in accordance with local/regional/national/international regulations 3 COMPOSITION/INFORMATION ON INGREDIENTS Chemical .and/or Common Name % Content CAS NUMBER Portland White Cement See Below - 'Portland Cement 92-97 65977-15-1 ACGIH TLV-TWA (1996) = 10mg total dust/m3 OSHA PEL (8-hour TWA) 15 mg total dust/m3 OSHA PEL (8-hour TWA) 5 mg respirable dust/m3 - Gypsum 0-10 7778-18-9 ACGIH TLV-TWA (1996) = 10 mg total dust/m3 OSHA PEL (8-hour TWA) 10 mg total dust/m3 OSHA PEL (8-hour TWA) 5 mg respirable dust/m3 - Respirable Quartz 0-15 14808-60-7 ACGIH TLV-TWA (1996) = .10mg total. dust/m3 OSHA PEL (8-hour TWA) (10 mg respirable dust/m3 (percent silica +2)) NIOSH REL (8-hour TWA) .05 mg respirable dust/m3 - Chromates 0-0.005 1317-65-3 ACGIH TLV-TWA (1996) = 0.05mg (Cr)/m3 - OSHA PEL (8-hour TWA) .1 mg (CrO3)/m3 - Nuisance dust ACGIH TLV-TWA (1996) = 5 mg respirable dust/m3 ACGIH TLV-TWA =10 mg total dust/m3 OSHA PEL (8-hour TWA) 15 mg total dust/m3 OSHA PEL (8-hour TWA) 5 mg respirable dust/m3 Silica Sand ACGIH TLV-TWA _ .025mg respirable dust/m3 OSHA PEL (8-hour TWA) 15 mg total dust/m3 OSHA PEL (8-hour TWA) 5 mg respirable dust/m3 - Quartz (Crystalline 99.0-99.9 14808-60-7 Silica) - Iron Oxide <.6 1309-37-1 - Aluminum Oxide <.3 1344-28-1 - Titanium Oxide < I 13463-67-7 COBALT ALUMINATE BLUE 100 1345-16-0 Proprietary Ingredient See Below - Magnesium Silicate 67-68 14807-96-6 ACGIH TLV-TWA = 2 Hydrate mg dust/m3 OSHA PEL 10 mg dust/m3 - Polyethylene Pulp 5-6 9002-88-4 N/A - Bentonite 27-28 12199-37-0 ACGIH TLV-TWA = 10 mg dust/m3 OSHA PEL 5 mg dust/m3 Water Dispersible Polymer 100 Unknown Cobalt Chromite Green Spinel 100 68187-49-5 Black Pigment 100 1317-61-9 Any Concentration shown as a range to protect confidentiality or it is due to process variation 4 FIRST -AID MEASURES GENERAL: Ensure Medical personnel are aware of the material(s) involved and take precautions to protect themselves. EYE: Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 15 minutes. Chemical burns must be treated promptly by a physician. SKIN CONTACT: Heavy exposure to Portland cement dust, wet concrete or associated water requires prompt attention. Quickly remove contaminated clothing, shoes, and leather goods such as watchbands and belts. Quickly and gently'blot or brush away excess Portland cement. Immediately wash thoroughly with lukewarm, gently flowing water and non-abrasive pH neutral soap. Seek medical attention for rashes, burns, irritation, dermatitis, and prolonged unprotected exposures to wet cement, cement mixtures or liquids from wet cement. Burns should be treated as caustic burns. INGESTION:,Get medical attention immediately. Call a poison center or physician. Have victim rinse mouth thoroughly with water. DO NOT INDUCE VOMITING unless directed to-do so by medical personnel. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Have victim drink 60 to 240 mL (2 to 8 oz.) of water. Stop giving water if the exposed person feels sick as vomiting may be dangerous. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. INHALATION: Seek medical help if coughing or other symptoms persist. Inhalation of large amounts of Portland cement requires immediate attention. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If the individual is not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery' position and get medical attention immediately. Maintain an open airway. POTENTIAL SYMTOMS AND EFFECTS FROM ACUTE EXPOSURES (delayed or immediate) Eye Contact: 5 FIREFIGHTING MEASURES EXTINGUISHING MEDIA Suitable extinguishing media: Non-flammable. Use an extinguishing agent suitable for the surrounding fire. Specific hazards arising from the No specific fire or explosive hazard chemical: Hazardous thermal decomposition, Decomposition products may include the following products: materials: carbon dioxide, carbon monoxide, sulfur oxides and metal oxide/oxides products: Special protective actions for firefighters: Evacuate area. Fight fire with normal precautions from a reasonable distance. Move containers from the fire area if this can be done without risk. Special protective equipment for Positive pressure self-contained breathing apparatus firefighters: (SCBA) and structural firefighters' protective clothing will provide adequate protection. 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES For Emergency responders and non -emergency personnel: Do not breathe in dust. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. For personal protective clothing requirements, please see Section 8. Environmental precautions: Avoid release into the environment. Contain the spill to avoid the discharge of spilled material into drains, surface waters and/or groundwater. If the spilled material enters the drainage systems, surface waters and/or groundwater, follow all the applicable local, state, and federal laws and regulations for additional; clean-up and/or reporting requirements. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP Small and Large Spills: Wear appropriate personal protective equipment as described in Section 8 for cleaning, containing and removing the spill. Minimize generation of dust. For small spills, clean with a vacuum sufficient to remove and prevent recirculation of cement dust (a vacuum equipped with a high - efficiency particulate air (HEPA) filter is recommended.) For large spilss, use control dust measures and carefully scoop or shovel into a clean dry container for later use or disposal. DO NOT USE COMPRESSED AIR TO CLEAN SPILLS. 7 HANDLING AND STORAGE HANDLING/STORAGE: Keep in a clean and dry environment and follow directions for safe use. CLOTHING: Promptly remove dusty clothing or clothing which is wet with cement fluids and launder before use. Wash thoroughly after exposure to dust or wet cement mixtures or fluids SENSITIVITY TO STATIC ELECTRICITY: N/A 8 EXPOSURE CONTROLS/PERSONAL PROTECTION RESIRATORY PROTECTION: NIOSH/MSHA approved respirator EYE PROTECTION: Use ANSI -approved, properly fitting safety googles. PROTECTIVE GLOVES: Use appropriate, impervious gloves. Do not rely on barrier creams in place of gloves. OTHER PROTECTIVE CLOTHING/EQUIPMENT: Protect skin from exposure. Use barrier creams and/or imperious footwear and clothing. VENTILATION REQUIREMENTS: Use exhaust fans to keep dust below TLV. Provide ANSI- approved emergency eyewash and deluge shower. 9 PHYSICAL AND CHEMICAL PROPERTIES PURE SUBSTANCE OR MIXTURE: Mixture PHYSICAL FORM: Powder COLOR: White, Blue, Teal, Black, or Grey ODOR: Odorless FLASHPOINT: None PHYSICAL STATE: Solid 10 STABILITY AND REACTIVITY REACTIVITY: Reacts slowly with water forming hydrated compounds, releasing heat and producing a strong alkaline solution until reaction is substantially complete. CHEMICL STABILITY: Stable CONDITIONS TO AVOID: Unintentional contact with water INCOMPATABILITY: Reactivity or incompatible with the following products: oxidizing materials, acids, aluminum and ammonium salt, fluorine, chlorine trifluoride, oxygen difluoride. This material is highly alkaline and will react with acids to produce a violent, heat generating reaction. Toxic vapors may be given off depending on the acids involved. HAZARDOUS DECOMPOSITION PRODUCTS: Under normal conditions, none. 11 TOXICOLOGICAL INFORMATION Irritation/Corrosion: Skin May cause serious burns in the presence of moisture Eves — Causes serious eye damage. May cause burns in the presence of moisture. Respiratory — May cause respiratory tract irritation Sensitization: May cause sensitization due to the potential presence of trace amounts of hexavalent chromium Mutagenicity Not classified Reproductive toxicity Not classified Teratogenicity Not classified Aspiration hazard Not classified Silicosis Chronic Accelerated and Acute Silicosis, caused by inhalation of airborne respirable crystalline silica dust Cancer The International Agency of Research on Cancer ([ARC) states that there is sufficient evidence to conclude crystalline silica is a known carcinogenic risk to humans. The role that smoking plays in the development of lung cancer as related to the silica exposure and cancer, silicosis, and other diseases has not been completely delineated. 12 ECOLOGICAL INFORMATION Etoxicity— No known effect on the environment. No know effects to plants and animals. 13 DISPOSAL CONSIDERATIONS Dispose of waste material according to local, state,.and federal laws and regulations. Dispose of bags in an approved landfill or incinerator 14 TRANSPORATION INFORMATION Hazardous Materials Description/ Proper Shipping Name: Material is not considered hazardous under Department of Transportation (DOT) Regulation Hazardous Class: Not applicable Identification Number: Not applicable Required Text Label: Not applicable Hazardous Substance/Reportable Quantities (RO): Not applicable s I 4 15 REGULATORY INFORMATION i Status under USDOL-OSHA & MSHA Hazard Communication Rule 29 CFR 1920.1200: - Portland cement is considered a hazardous material under this regulation and should be part of any hazardous. communication program. This material contains Portland cement. STATUS UNDER CERCLA/SUPERFUND 40 CFR 116 AND 302: - Not Listed Hazard Category under SARA (Title III) Section 311 and 312: - Portland cement qualifies as a hazardous substance with delayed health effects. This material contains Portland cement. Status under SARA (Title III) Section 313: Not subject to reporting requirements under Section 313 of the Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR Part 372 in concentration above diminutive levels. Status under TSCA: - Some substances in Portland cement are on the TSCA inventory list. - Crystalline Silica (quartz) appears on the TSCA inventory list under CAS No. 14808-50-7 Status under the Federal Hazardous Substances Acts: - Portland cement is a "hazardous substance" subject to statutes promulgated under the subject act OSHA Carcinogen Crystalline Silica in this material is a carcinogen. Status under California Proposition 65 - This product contains up to 50% of material known to the State of California to cause cancer, birth defects, or other reproductive harm. California law requires the manufacturer to give the above warning in the absence of definitive testing to prove that the defined risks do not exist. 16 OTHER INFORMATION Revision History: Revise 15 Nov 2015 Revision Info: Revised to new MSDS format NOTICE TO READER While the information and recommendations set forth herein are believed to be accurate as of the date hereof, THE MANUFACTURER MAKES NO WARRANTY WITH RESPECT THERETO AND DISCLAIMS ALL LIABILITY FROM RELIANCE THEREON 856 23rd Avenue. 772.770.4420 Vero Beach, FL 32960 hitechpools@comcastnet C) pf- 8 L, r lu ebvKeg egf r - ry 60E_ to (0k) NO tj\r; N6 A10ly -v 6e, ADD RECEIVED AUG 3 0 7017 Permitting Department - St. Lucie County No jo1VlNc www.hitechpoolrenovations.com ---- -- ---- 5/16 -fi 542038 File Copy CERTIFICATION OF COMPLIANCE 12" x 12" SQUARE GRATE: P/N 640 Contents: 1 Part Number. 640-4720 y Description: Square Grate Sae: 12" x 12" Open Area: 62.4 inz V. GPM @ 1.5 fps: 292 Floor Flow Rate: . 356 GPM VGB Wall Flow Rate: 280 GPM 2068 Date of Manufacture: An 2 1 2117 r This product has been tested to ANSI/ASME 112.19.8-2007 (addendum 8a-2008) per §1404 of the Virginia Graham Baker (VGB 2008) Pool and Spa Safety Act. Certified by: Underwriters Laboratories, Inc., 2929 E. Imperial Highway, Suite 100, Brea, CA 92821-6729 This product is certified to.comply with §1404 of theVirginia Graham Baker (VGB 2008) Pool and Spa Safety Act. A copy of the test results for the above may be found atwww.waterwayplastics.com or go to www.ul.com. This product is manufactured by Waterway Plastics, Oxnard, CA 93030 Madeln the USA m 2200 East Sturgis Road, Oxnard, CA 93030 • Ph. (805) 981-0262 • Fax (805) 981-9403 emi:wnamye s www.waterwaolas.tics.com-waterway@waterwayplastics.com 810-0253.0412 File COPY Front: Nichole Family Pools Inc[mailto:nicholeCafamilypoolsinc.com] Sent' Wednesday, September 19, 2018 10:33 AM To: Michael Terrell Subject: Re: permit Hopethis helps! Famil?,� Pools Inc. 873 SW South Macedo Blvd. Port SiI Lucie, FL 34983 772-878-8452 Local 1-866- 94-4011 Toll Free 772-78�-9558 Fax 772-361-3439 Text On Wed, I�ep 19, 2018 at 9:54 AM, Michael Terrell <hitechpools a comcast.net> wrote: Thank Y Mike T z -Tech Pools & Pavers 23rd. Ave. Vero Beach FL 32960 770.4420 Office