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Home My WebLink AboutAKZONOBEL MATERIAL SAFETY DATA SHEETMaterial safety data sheet AkzoNobel PERKADOX 16 nI= TNG CI IRCTAAI(`CIPRFPARATInN AMn nG TWF= (:nA4PAMV/I IMnFRTAKiNn Product identifier Di(4-tert-butylcyclohexyl) peroxydicarbonate, powder Supplier SCAN Akzo Nobel Polymer Chemicals LLC �6 B 525 West Van Buren Street Chicago, IL 60607-3823 st Lude County www.-ak.zonobel.com/polymer Emergency telephone transportation emergency +1-914-693-6946 CHEMTREC - USA:1-800-424-9300 Chicago, IL USA CANUTEC - CANADA1-613-996-6666 Relevant identified uses of the substance or mixture polymerization Initiator Date of last Issue / Revision number 2014/05/04 / 3.05 Chemical family peroxides 0 WA7ADns InPnlTil=lr ATInnI Emergency overview DANGERI REFRIGERATED ORGANIC PEROXIDE -MAINTAIN COOLING HEAT OR CONTAMINATION MAY CAUSE HAZARDOUS DECOMPOSITION MAY CAUSE EYE IRRITATION Peroxides and peroxide decomposition products are flammable and can ignite with explosive force if confined. Dust explosion possible In the presence or air. Appearance white powder with faint odor. Health effects Skin contact, eye contact and inhalation are the primary routes of exposure to this product. Dust may be irritating to the respiratory tract and cause symptoms of bronchitis. May cause sensitization by skin contact. Eye contact may cause mild irritation. If swallowed, this product may cause irritation of the mouth, throat, esophagus and stomach. Carbif oedidRy Description Applicable IARC no NTP no OSHA no ACGIH no 3. COMPOSITION/INFORMATION ON INGREDIENTS Information on hazardous Ingredients Chemical description Di(4-tert-butylcyclohexyl) peroxydicarbonate, powder Composition / information on Ingredients Number I %wlw I CAS,number Chemical name 1 1 > 94 015520-11-3 Di(4-tert-butylcyclohexyl) peroxydicarbonate 4. FIRST AID MEASURES Product code 661451 Date of lost Issue 2014105104 Pagel - 8 Date or printinglpdf rite generated 204106103 US -NA global i i l Material safety data sheet AkzoNobel Most important symptoms and effects Dust may be irritating to the respiratory tract and cause symptoms of bronchitis. Description of first aid measures General In all cases of doubt, or when symptoms persist, seek medical attention. Inhalation Remove to fresh air. If not breathing, give artificial respiration. Oxygen may additionally be given, by trained personnel, If it is available. Get medical attention if symptoms occur. Skin Flush skin with plenty of water.. Remove contaminated clothing and shoes. Get medical attention if irritation develops and persists. Wash clothing before reuse. Thoroughly clean or destroy contaminated shoes. Eye Immediately flush eyes with plenty of water. If easy to do, contact lenses should be removed during the flushing, by trained personnel.. Occasionally hold the eyelids apart. during the flushing to ensure rinsing the entire surface of the eye and lids with water. Get medical attention If irritation develops and persists. Ingestion Call a physician or a poison control center immediately. Induce vomiting only if directed by medical personnel. The patient should tie on their left side while vomiting to reduce the risk of aspiration. Never give anything by mouth to an unconscious or convulsing person. Indication of any immediate medical attention and special treatment needed Persons with pre-existing skin, eye, or respiratory disease may be at increased risk from the irritant or allergic properties of this material. Attending physician should treat exposed patients symptomatically. 5. FIRE -FIGHTING MEASURES Extinguishing media waterspray, foam, sand, dry chemical powder, CO2. Unsuitable extinguishing media halons. Hazardous decomposition / combustion products CO2, Carbon monoxide. 4-tert-Butylcyclohexanol. Protective equipment rucnyntma mustwear IIIC rebl8lkllll FIIUICUUV6 6l'IUIIJIIIeIIt. VVeCI Gpp1UVCl] ICsplftltUf and plUIeGUVe gIUVeS. Other information Evacuate all non -essential personnel. Extinguish a small fire with powder or carbon dioxide then apply water to prevent re -ignition. Cool closed containers with water. Water used to extinguish a fire should not be allowed to enter the drainage system or water courses. After a fire, ventilate thoroughly the area and soak with water, clean the walls and metallic surfaces. Fire and explosion hazard CAUTION: reignition may occur. Decomposition under effect of heating (See also Section Hazardous decomposition products). If involved In a fire, it will support combustion. dust explosion hazard. In case of fire and/or explosion do not breathe fumes. NFPAA ratings Hazard classes Rating Health 1 Flammability 3 Reactivity 2 Other information 6. ACCIDENTAL RELEASE MEASURES Product code 661451 Date of last Issue 2014105104 Page 2 - 8 Date of printinglpdf file generated 2014106103 US -NA global Material safety data sheet r „ a: pF62KAnnX i A Personal precautions Do not breathe dust. Avoid contact with skin. For personal protection see Section 8. Environmental precautions Do not allow to enter drains or water courses. Methods and material for containment and cleaning up Stop leakage if possible. Eliminate all sources of ignition, and do not generate flames or sparks. Sweep up and put it Into a container for disposal. Avoid dust generation. Keep contents moist. The waste should NOT be confined. Flush surroundings with large amounts of water and soap. Other information CAUTION: reignition may occur. Evacuate personnel to safe area. 7. HANDLING AND STORAGE Precautions for safe handling Never weigh out in the storage room. When using do not eat, drink or smoke. Do not breathe dust. Handle in well ventilated areas. Eliminate all sources of ignition, and do not generate flames or sparks. Keep away from reducing agents (e.g. amines), acids, alkalies and heavy metal compounds.(e.g. accelerators, driers, metal soaps). Keep product and emptie.d.contalner away from heat and sources of Ignition. Confinement must be avoided. Avoid Incompatible materials (See Section 10). Fire and explosion prevention Use explosion protected equipment Keep away from sources of ignition - No smoking.. Avoid dust generation. Dust explosion possible in the presence of air. Use non -sparking tools in area's where explosive dust air mixtures may occur. Do not cut or weld on or near this container even when empty. Conditions for safe storage Store in accordance with local/national regulations. Keep away from food, drink and animal feedingstuffs. Store in a dry well ventilated place away from sources of heat and direct sunlight. Store separate from other chemicals. Keep only in the original container. Storage For maximum quality store below' 20 *C. For safety, store below 30 °C, Other information It is recommended to use electrical equipment of temperature group T3. However, autoignition can never be excluded. Wash hands thoroughly after handling or contact. Keep work clothes separate and do not take them home. 8. EXPOSURE CONTROLSIPERSONAL PROTECTION Clitoral paraniftcra Ensure good ventilation and local exhaustion of the working area. Explosion proof ventilation recommended. Personal protection Respiratory In case of dust formation use dust mask. Hand Wear suitable protective gloves of neoprene or synthetic rubber. Eye Wear eye/face protection. Skin and body Wear suitable protective clothing. Other information Emergency -shower and facilities for rinsing eyes must be accessible. Launder clothes before reuse. In this country no exposure limit has been established 771 9. PHYSICAL AND CHEMICAL PROPERTIES Product code 661451 Date of last issue 2014105104 Page - 8 Date of printingfpdf fila generated 2014106103 US -NA global Material safety data sheet Ali : s � °(At .1� ;;, i "a� g �'� " 0I=P&CAhr%Y 9R Appearance powder Color white Odor faint Boiling point/range not applicable (Decomposes) Melting point/freezing point Decomposes prior to melting. Flash point not applicable Flammability Decomposition products may be flammable. Explosive properties no Oxidizing properties not applicable Vapor pressure <0.08 kPa (60*0 / 140°F) Density 1130 kg/m' (20°C / 687) Specific gravity = 1.13 (20°C / 68°F) Bulk density 450480 kg/m3 (20°C / 68eF) Specific gravity = 0.45-0.48 (20°C / 68°F) Solubility In water Insoluble (20°C / 68°F) Solubility in otheusolvents Soluble with aliphatic solvents. pH value slightly acidic Partition coefficient n-octanollwater not determined Relative vapor density (air-1) not applicable Viscosity not applicable Active oxygen content 3.8 % Peroxide content 95 % Autoignition temperature Test method not applicable (See Section'7) SADT 40 *C. See also Section 10. Upper/lower flammability or explosive limits not determined Volatile % not determined 10. STABILITY AND REACTIVITY Product code 661451 Date of last Issue 2014105104 Page 4 - 8 Date of printinglpdf file Den erated2014106103 US -NA global Material safety data sheet �tL®1lA11A!/ 4n A Chemical stability SADT - (Self accelerating decomposition temperature) is the lowest temperature at which self accelerating decomposition may occur with a substance in the packaging. as usedin transport. A dangerous self -accelerating decomposition reaction and, under certain circumstances, explosion or fire can be caused by thermal decomposition at and above the following temperature: 40 *C. Contact with incompatible substances can cause decomposition at or below the SADT 40 *C. To Insure against possible exothermic self -accelerating decomposition, storage temperatures must not exceed emergency temperature of 35 *C. Conditions to avoid Under no circumstances should this product be exposed to temperatures above the emergency temperature of 35 *C. If the product temperature exceeds 35 aC all available means shall be used to bring the temperature under control and the emergency procedures shall be started. Emergency procedures will vary depending on conditions. Contact Akzo Nobel for assistance with developing an emergency response plan. To maintain quality store in original closed container below: 20 *C. Confinement must be avoided. Incompatible materials Avoid contact with rust, Iron and Copper. Contact with incompatible materials such as acids, alkalies, heavy metals and reducing agents will result in hazardous decomposition. Do not mix with peroxide accelerators. Use only Stainless steel 316, PP, polyethylene or glass -lined equipment. Contact Akzd Nobel for more information. Possibility of hazardous reactions Polymerization' does not occur. Hazardous decomposition products Hazardous decomposition products; 4-tert-Butylcyclohexanol. Other information Emergency procedures will vary depending on conditions. The customer must have an emergency response plan in place. Contact Akzo Nobel for assistance with developing an emergency response plan. 11. TOXICOLOGICAL INFORMATION Di(4-ter(-butylcyclohexyl) peroxydicarbonate Acute toxicity Oral LD50 LD50 (rat):> 5000 mg/kg (OECD 401) Germ cell mutagenicity Eased ^ a11.b1i. d.t. the ^lam sification criteria e not met . STOT - repeated exposure 28 days (oral): No Observed Adverse Effect Level (NOAEL): 500 mglkg/day (Target organs: liver, thyroid }. (OECD 407) Irritation Skin Non -irritating (24 hours exposure time ) (OECD 404) Eye Mildly irritating (similar to OECD 405). GHS classification : Mildly irritating to eyes (category 213). Sensitization Sensitizing (skin) (OECD 429) Genotoxicity in vitro: similar to OECD 471: Negative. OECD 476: Negative. OECD 478:Negative. 12. ECOLOGICAL INFORMATION Product code 661451 Date of last Issue2014105104 Page - B Date ofprintinglpdffile generated 2014106103 US -NA global Material safety data sheet Ja . v,;' I°io :I o-„* 4 DI(4-tort-butylcyclohexyl) peroxydicarbonate Ecotoxicity fish 96h-LC50 (Oncorhynchus mykiss): 704 mg/I. (OECD 203) No Observed Effect Concentration (NOEC) (96h):320 mgll. daphnia 48h-EC50 (Daphnia magna): 42 mg/I. (OECD 202) algae 72h-IC50 (Desmodesmus subspicatus ): approx. 39 mgll. ,(OECD 201) No Observed Effect Concentration (NOEC) (72h ):'17 mgll. LOEC (72h ): 39mg/I. bacteria No Observed Effect Concentration (NOEC) (5 days): 20 mg/l. (similar to OECD 301D) Fate Degradation Abiotic Hydrolysis: Stable in water. Degradation Biotic Not readily biodegradable ( Closed bottle test). (OECD301 B) Bioaccumulation Bio Concentration Factor (BCF): 2926 L/kg. Fate Log Pow: 5.08 IJ. UlW UJAL UUNJIULKAI IUNJ Product Due to the high risk of contamination recycling/recovery is not recommended. Waste disposal in accordance with regulations (mast probably controlled incineration). Contaminated packaging According to local regulations. Emptied container might retain product residues, Follow all warnings even after the container is emptied. Do not wash residues Into drains or other waterways. For further.advice contact manufacturer. 1A TPAN.gPr)PT IAIFr1PhAATfr1hi Land transport Transport hazard class 5.2 TREM-Card or ERG number NA ERG No: 148 UN number 3114 Proper Shipping Name Organic peroxide type C, solid, temperature controlled ( DI(4-tert-butylcyclohexyl) peroxydicarbonate, 95% ) Other information This product does not contain an environmentally hazardous substance per 49 CFR 172,101, Appendix A. Required labels 5.2 EMERGENCY TEMPERATURE: 35 'C. Product code 661451 Dale of last issue2014106104 Page 6 - 8 Date of printinglpdf file generated MOWN US -NA global Material safetyd<j,t« il'"t;'r kko bel CONTROL TEMPERATURE: 30 *C. The control temperature is the maximum temperature at which the formulation can be transported safely during a prolonged period of time. Sea fransport (IMO / IMDG-code) Transport hazard class 5.2 UN number 3114 EMS F-F, S-R Marine pollutant no Proper Shipping Name Organic peroxide type C, solid, temperature controlled ( DI(4-tert-butylcyclohexyl) peroxydicarbonate ) Other information Label(s): 5.2 EMERGENCY TEMPERATURE: 35 *C. CONTROL TEMPERATURE: 30 *C. The control .temperature is the maximum temperature at which the formulation can be transported safely during a prolonged period of time. Air transport (ICAO-TI11ATA-DGR) UN number Forbidden 15. REGULATORY INFORMATION Product and or components listed below are subject to the following VI(Y-teli-Y1.I1�/11.,y%1:IVlleltyilJ paroxydicaMbortate New Jersey R-T-K_Hazard. Sub. yes US Toxic. Subst. Cont. Act (TSCA) yes Non -Domestic Subst.List-Canada no Domestic Substance List -Canada yes Connecticut Hazardous Material Survey yes Hazard classes Description Applicable EPA Immediate health yes EPA Delayed health no EPA Fire yes EPA Pressure no Product code 661451 Date of last Issue20141os104 Pagel - 8 Data of printing1pdf file generated 2014106103 US -NA global Material •l' ;f epI=1 safety atV i .f data sheet i ,Y� i r' . .F�F 4". }( e�^ ��e h_ D1=Pv,AnnY ,tr, EPA Reactive yes EHS Material no Hazard Rating Source HMIS HMIS Health 1 HMIS Flammability 3 HMIS Reactivity 2 WHMIS Hazard classes C,D-2B,F e Otherregulatory information This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains allrof the information required by the Controlled Products Regulations. 16'. OTHER INFORMATION History Other information PERKADOX: This is a registered trademark of Akzo Nobel Chemicals BV or any of its affiliated companies in one or more territories in the world. Date of printing! pdf file generated 2014/06/03 Revision 3.05 Composed by Regulatory Affairs - North America, T +1-312-544-7000. Regulatory Affairs - Europe, Changes were made in section GHS/EU Classification: not relevant to NAFTA The Information In this material safety data sheet should be provided to all who will use, handle, stare, transport or otherwise be exposed to this product. All infordallen cencemIng this product andfor suggestions for handling and use contained herein are offered In good faith and are believed to be reliable as of the date of publication. However, no warranty Is made as to the accuracy of andfor sufficiency of such Informatian andfor suggestions as to the merchantability or fitness of the product for any particular purpose, or that any suggested use will not infringe any patent. Nothing In here shall be construed as granting or extending any license under any patent. Buyer must determine for himself, by preliminary tests or otherwise, the suitability of this product for his purposes, including mixing wilh other products. The Information contained herein supersedes all previously Issued bulletins on the subject matter covered. If the date on this document is more than three years old, call to make certain that this sheet Is current. Product code 661451 Date of last Issue2014105104 Page 8 - 8 Date of printinglpdf file generated 2014106103 US -NA global