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Home My WebLink AboutAOC MATERIAL SAFETY DATA SHEETanaterrial Wety Mal sheei, , MSDS #: 16662V2 WHMIS (Canada) NFPA (USA) HMIS (USA) Protective clothing Fire Health Reactivity 3 }`I?hystcdl l�-N'urJ � �.Wa�` 2 B-2 D-2A D-28 Specific hazard Personal protection ®R Section 1. Chemical product and company identification SCANNED. j Trade name L704-NET•14BY Product type Polyester Resin Solution Chemical family Aromatic. Material uses Used in the manufacture of thermoset plastic parts. Manufacturer AOC, LC In case of emergency 950 Highway 57 East Collierville, TN U.S.A. 38017 CHEMTREC (US): 24 hours/7 days (800) 424-9300 Website: www.aoc-resins.com CANUTEC (Canada): 24 hours/7 days (613) 996-6666 Phone Number: (901) 854-2800 8am-5pm (Central Time) Mon -Fri Section 2. Hazards identification OSHA status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Routes of entry Eye contact, Skin contact, Inhalation, Ingestion Potential acute health Eyes: Severe eye irritant which may result in redness, burning, tearing and blurred vision. effects Skin: Skin irritant which may result in burning sensation. Repeated or prolonged skin contact may cause dermatitis. Ingestion: Ingestion may result in mouth, throat and gastrointestinal irritation, nausea, vomiting and diarrhea. Inhalation: Inhalation of spray mist or liquid vapors may cause upper respiratory irritation and possible central nervous system effects including headaches, nausea, vomiting, dizziness, drowsiness, loss of coordination, impaired judgement and general weakness. Potential chronic health CARCINOGENIC EFFECTS: effects S rene: Classified A4 (not classifiable for human or animal) by ACGIH: Classified 2B (possible for human) by IARC. Classified as "reasonably anticipated to be a human carcinogen" by NTP. An increased incidence of lung tumors was observed in mice from a recent inhalation study. The relevance of this finding is uncertain since data from other long-term animal studies and from epidemiology studies of workers exposed to styrene do not provide a basis to conclude that styrene is carcinogenic to humans. Silica, Amorphous: Classified 3 (not classifiable for human) by IARC. MUTAGENIC or TERATOGENIC EFFECTS: No known effect according to our database. Effective Date: 02tO8/2013 Supersedes Date: 10129/2012 Page:1/5 L704-NET•14 Section I. Compositionlintformation on ingredients Name 1) Styrene CAS # % by weight 2) Silica, Amorphous 100-42-5 40.7 7631-86 9 1-5 Section 4. First aid measures Eye contact Flush with a continuous flow of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Use of buffered baby shampoo will aid in removal. Seek medical attention. Skin contact Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap. If irritation persists, seek medical attention. Inhalation Move the victim to a safe area as soon as possible. Allow the victim to rest in a well -ventilated area. If breathing is difficult, give oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention. Ingestion Do not induce vomiting. Seek immediate medical attention. Section S. Fire -righting measures The product is: Flammable liquid, Class IC. ignition temperature 914°F(490°C) Styrene point 87.6°F (31 °C) Styrene iableIimits Lower:0.9% Upper: 6.8% (Styrene) .ts of combustion May produce carbon monoxide, carbon dioxide, and irritating or toxic vapors, gases or particulate. Fire hazard Flammable in the presence of open flames, sparks, or heat Explosion hazard Can react with oxidizing materials. Explosive in the form of vapor when exposed to heat or flame. Material may Polymerize when container is exposed to heat (fire) and polymerization will increasein ,pressure a closed container which may cause the container to rupture violently. Fire -fighting media and i structlons SMALL FIRE: Use carbon dioxide, foam, dry chemical or water fog to extinguish. LARGE FIRE: Evar-.ii U,_ Carbon to Wear self-contained breathing apparatus (SCBA) and full fire -fighting protective clothing. Cool cxiae, toam, dry chemical or wateroontain ng extinguish. vessels with water spray in order to j prevent pressure build-up,.autoignition or explosion. Prevent run off to sewers or other water ways. Section 6. Accidental release measures Small spill Absorb with an inert material and place in an appropriate waste disposal container. Large spill Stop leak if without risk. Eliminate all ignition sources. Contain with an inert material, recover as much as possible and place the remainder in an appropriate waste disposal container. Warn unauthorized personnel to move away. Prevent entryy into sewers or confined areas. Section 7. Handling and storage Handling WARNING! Use only in well -ventilated areas, Store away.from direct sunlight. Avoid inhalation and contact with eyes, skin, and clothing. Wear appropriate personal protective equipment for your task. Ground and bond all containers when transferring the material. Empty containers may retain product and product vapor. Do not expose to heat, flame; sparks or other ignition I sources such as cutting, welding, drilling, grinding or static electricity. Do not pressurize. Provide adequate safety showers and eyewashes in the area of use, Eff Iclive Date: 02108/2013 Supersedes Date: 10/29/2012 Page: 215 MSDS M 16662V2 L704-MET•14 Section 7. Handling and storage j Storage Keep away from heat. Keep away from Sources of ignition. Keep container tightly closed. Keep in a cool, well - ventilated place. Containers should be grounded. Section B. Exposure controls/personal protection Exposure limits Styrene ACGIH TLV (United States, 3/2012). Absorbed through skin. TWA: 20 ppm 8 hour(s). TWA: 85 mg/m' 8 hour(s). STEL: 40 ppm 15 minute(s). STEL:170 mg/m' 15 minute(s). OSHA PEL Z2 (United States,1112006). TWA: 100 ppm 8 hour(s). AMP: 600 ppm 5 minute(s). CEIL: 200 ppm NIOSH REL (United States, 612009). TWA: 50 ppm 10 hour(s), TWA: 215 mglm' 10 hour(s). STEL:100 ppm 15 minute(s). STEL: 425 mg/m' 15 minute(s). Silica, Amorphous NIOSH REL (United States, 6/2009). TWA: 6 mg/m' 10 hour(s). Engineering controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective occupational exposure limits. Provide adequate safety showers and eyewashes in the area of use. Personal protection Personal protective equipment may vary depending on the job being performed. Eyelface; Wear eye protection such as safety glasses with side shields, splash goggles or face shield with safety glasses. Skin: Avoid skin contact. Impervious gloves should be worn. Other items may include long sleeves, lab coats, or impervious jackets. Respiratory: Determine if airborne concentrations are below the recommended exposure limits in accordance your. company's PPE program and regulatory requirements. If they are not, select a NIOSH-approved respirator that provides. adequate protection from the concentration levels encountered. Air -purifying respirators are generally adequate for organic vapors. Use positive pressure, supplied -air respirators if there is potential for an uncontrolled release, if exposure levels are unknown, or under circumstances where air -purifying respirators may not provide adequate protection. Reference OSHA 29 CFR 1910.134. Personal protection in case Chemical resistant gloves, fuli_protective suit, and boots. Respiratory protection in accordance with OSHA of a large spill regulation 29 CFR 1910,134. A self-contained breathing apparatus should be used to avoid inhalation of the r�r� .Section 9. Physical and chemical properties Physical state Liquid. Color Clear to Amber. bdor Aromatic. Molecular weight (glmol) 1000 to 15000 Boiling point 293°F(145°C) Styrene point I Not available. pH (1% soln/water) Not applicable. Vapor pressure 4.5 mm Hg@ 687 (20°C) Styrene Vapor density 3.59 Styrene (Air =1) Specific gravity 1.1 (Water = 1) Partition coefficient: n- Not available. o ctanollwater Effective Date: 0210812013 Supersedes Date: 10/29/2012 Page: 3l5 U1 L704-NET•14 j Section 9, Physical and chemical properties Evaporation rate Not available. Odor threshold 0.14 ppm.Styrene Solubility in water Slight. Dispersibility properties Not dispersed in water. Section 10. Stability and reactivity Stability This product,is normally stable, but can become unstable at elevated temperatures and undergo Polymerization, which could produce heat and fumes resulting i container. n over -pressurization and rupture in a closed Instability temperature >170'F (77'C) Conditions of instability Neat. Incompatibility with various Polymerizes in the presence of organic peroxides, oxidizing materialsor ht. substances , ea f Corrosivity, Our database contains no additional remark on the corrosivity of this product Section 11. Toxicological information Toxicity to animals Name Result Species Styrene Dose Exposure LD50 Intrapedtoneal Rat L050 Oral 898 mg/kg - Rat LD50 Oral Rat 5000 mglkg 2650 mg/kg _ TDLo Dermal Rat LC50 Inhalation Rat 26.4.mglkg - 11000 mglm3 Vapor 4 hours Special remarks on toxicity LC50 Inhalation Gas. Rat Lung 2770 ppm. 4 hours to animals effects that have been observed in mouse studies have been shown in somt e studies t o be the result of mouse specific enzymes (not in humans) that enable the mechanism Special remarks on chronic for producing cancer mice. effects on humans A study of long term effects of workers exposed to styrene levels in the range of 25-35 ppm, 8 hour TWA, indicated a possible mild hearing loss. Speclal remarks on other .nYlllall.^i No additional remark. 1 Dn 12. Ecological information ;icily Toxic to aquatic organisms. She Ad not be released to sewage system or other bodies of water at j concentrations above limits established in regulations or permits. )n 13. Disposal considerations disposal Recycle to,process,'if possible. Consult your local or regional authorities. Ignitable characteristic. n 14. Transport information UN1866; Resin Solution; 3; III. Labels UN1866; Resin Solution; 3; III. UN1866; Resin Solution; 3; III Date: 02108/2013 1' Supersedes Date: 10/29/2012 Page: 4l5 a I MSDS #: 16662V2 L704•NET-14 Section 14. Transport information Additional information US regulations require the reporting of spills when the amount exceeds the Reportable Quantity (RQ) for specific components of this material. See CERCLA in Section 15, Regulatory Information, for the Reportable Quantities. ection 15. Regulatory information Cher regulations This section does not reference all applicable regulatory compliance lists. TSCA: All ingredients are listed or compliant with TSCA. DSL: All ingredients are listed or compliant with the NSNR. Proposition 65 IIfaming: This product contains a chemical(s) known to the State of California to cause cancer, birth defects and/or reproductive harm. i SARA 302 component(s): None. SARA 313 component(s): Styrene.. CERCLA(RQ): Styrene -1000 lbs. (453.6 kg) Section 16.Other information Prepared by AOC, LLC - Corporate Regulatory Affairs. CA I LEGAL DISCLAIMER The information contained in this data -sheet Is furnished in good faith and without warranty, representation, or inducement or license of any kind, except that it is accurate to the best of AOC, LLC`s knowledge, or was obtained from sources believed by AOC, LLC to be reliable. The accuracy, adequacy or completeness of health and safety precautions set forth herein cannot be guaranteed, and the buyer is solely responsible for ensuring that the product is used, handled, stored, and disposed of safely and in compliance with applicable federal, state or provincial, and local laws. AOC, LLC disclaims liability for any loss, damage orpersonal injury that arises from, or is in any way related to, use of the information contained in this data sheet. Date: 02/08/2013 Supersedes Date: 10/29/2012 Page: 515