HomeMy WebLinkAboutMATERIAL SAFETY DATA SHEETPage 2 of 6
* STYPOL 040-0004 #
* MATERIAL SAFETY DATA SHEET
* 0400004RI
Boiling Range: High- -N/A F Low- 293.0 F
Vapor Pressure: See Section II C Theoretical Weight per Gallon, Calculated: 7.5300 LB/GL SCANNED
Theoretical Specific Gravity, Calculated: .905 ®®gyp
Theoretical VOC, Calculated: 7.530 LB/GL ® e
--If applicable , see Section X for further V"OC information-- �L LUCI@ V0U11$�d Physical State: LIQUID `y
Appearance: CLEAR, COLORLESS
Odor: CHARACTERISTIC STYRENE
Odor Threshold: -N/A
pH: -N/A
Freezing Point: -N/A
Water Solubility: INSOLUBLE
Coefficient of Water/Oil Distribution: -N/A
Mechanical Impact Explosion: NO KNOWN HAZARD
Static Electricity Explosion: AVOID STATIC CHARGE
s HAP BY WEIGHT 100.000
MONOMER BY WEIGHT 100.000
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SECTION IV FIRE AND EXPLOSION HAZARD DATA
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FLAMMABILITY CHARACTERISTICS:
Lowest Closed Cup Flashpoint: 88.0 degrees F
For Flash Points 73 to 100 deg. F.
OSHA Flammability Classification: Class IC
DOT Flammability Classification: Flammable Liquid
Lower Flammable Limit in Air: Lower- 1.1 o by volume
DOT Shipping Name:
UN2055, STYRENE MONOMER, STABILIZED, 3,PG III
EXTINGUISHING MEDIA:
Foam, carbon dioxide, dry chemical, water fog.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
If polymerization takes place in a container, there is possibility of
violent rupture of the container. Vapors are uninhibited and may form
polymers in vents or flame arrestors of storage tanks resulting in
stoppage of vents. Vapors may cause flash fire. Keep containers
tightly closed and isolate from heat, electrical equipment, sparks and
flame. Never use welding or cutting torch on or near drum (even empty)
because product (even just residue) can ignite explosively.
SPECIAL FIRE FIGHTING PROCEDURES:
Full protective equipment including self-contained breathing apparatus
should be used. Water spray may be ineffective. If water is used, fog
nozzles are preferable. Water may be used to cool closed containers to
prevent pressure build-up and possible auto -ignition or explosion when
exposed to extreme heat.
ADDITIONAL TRANSPORTATION INFORMATION:
Freight Classification:
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* STYPOL 040-0004
* MATERIAL SAFETY DATA SHEET
* 0400004R1
NMFC: 46750 STYRENE LTL CLASS 70
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SECTION V HEALTH HAZARD DATA
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EFFECTS OF EXCESSIVE OVEREXPOSURE. PRIMARY ROUTES OF ENTRY ARE:
EYE CONTACT:
Irritation. Symptoms are tearing, redness and discomfort.
SKIN CONTACT:
Irritation. Can cause defatting of skin which may lead to dermatitis.
INHALATION:
Irritation to nose and throat. Extended or repeated exposure to con-
centrations above the recommended exposure limits may cause brain or
nervous system depression, with symptoms such as dizziness, headache
or nausea and if continued indefinitely, loss of consciousness, liver
and kidney damage.
Reports have associated repeated and prolonged occupational over-
exposure to solvents with permanent brain and nervous system damage.
INGESTION:
May cause mouth, throat, esophagus and stomach irritation, nausea,
vomiting and diarrhea. Aspiration into lungs can cause pneumonitis
which can be fatal.
MEDICAL CONDITIONS THAT MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT.
Preexisting eye, skin, liver, kidney and respiratory disorders.
EMERGENCY AND FIRST AID PROCEDURES:
In case of eve contact, flush immediately with plenty of water for at
least 15 minutes and get medical attention; for skin, wash thoroughly
with soap and water. If affected by inhalation of vapors or spray mist, !
remove to fresh air. If swallowed, get medical attention immediately.
Aspiration into lungs can cause pneumonitis which can be fatal.
Based on the presence of components (01)
CALIFOR14IA PROPOSITION 65 INFORMATION:
WARNING - This product contains a chemical(s) known to the State of
California to cause cancer.
OTHER HEALTH HAZARDS:
STYRENE MONOMER
The 12th Report on Carcinogens issued by the National Toxicology Program
lists styrene as a "reasonably anticipated" carcinogen, but ',be Report
cautions that the NTP listing does not mean that. styrene presents a risk
to persons in their daily lives. The Styrene Information and Research
Center does not agree with the classification as it did not include a
review of all available data. SIRC states: "HHS included styrene in the
12th RoC despite Life face that European Union regulators have determined j
styrene does not represent a human cancer concern. E.U. scientists f
reviewed the full styrene database, weighing all of the available data
in reaching their conclusion."
The International Agency for Research on Cancer (IARC) has reclassified
styrene as Group 2B "possibly carcinogenic to humans". This new
classification is not based on new health data relating to either
humans or animals, but on a change in the IP.RC classification system.
The Styrene Information and Research Center does not agree with the
reclassification and has published the following statement. "Recently
published studies tracing 50,000 workers exposed to high occupational
levels of styrene over a period of 45 years showed no association i
between styrene and cancer, no increase in cancer among styrene
workers (as opposed to the average among all workers), and no increase
in mortality related to styrene."
An increased incidence of lung tumors was observed in mice from a recent
inhalation study. The relevance of this finding is uncertain. Data
from other long-term animal studies and from epidemiology studies of
workers exposed to styrene do not provide a basis to conclude that
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* STYPOL 040-0004 ,
MATERIAL SAFETY DATA SHEET
* 0400004RI
styrene is carcinogenic.
Lung effects have been observed in the mouse following repeated exposure
to styrene.
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SECTION VI REACTIVITY DATA
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STABILITY: Stable HAZARDOUS POLYMERIZATION: May occur.
CONDITIONS TO AVOID:
Elevated temperatures.
INCOMPATABILITY (MATERIALS TO AVOID):
Oxidizers, reducing agents, peroxides, strong acids, bases, UV light,
or any source of free radicals and mild steel.
HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition or combustion can produce fumes containing organic
acids, carbon dioxide and carbon monoxide.
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SECTION VII SPILL OR LEAK PROCEDURES
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STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
Remove all sources of ignition (flames, hot surfaces, and electrical,
static, or frictional sparks). Avoid breathing vapors. Ventilate area.
Contain and remove with inert absorbent and non -sparking tools.
WASTE DISPOSAL METHOD:
Dispose of in accordance with local, state and ,federal regulations. Do
not incinerate closed containers. Incinerate in approved facility.
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SECTION VIII SPECIAL PROTECTION INFORMATION
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RESPIRATORY PROTECTION:
Do not breathe vapors or spray mist. Wear an appropriate, properly
fitted respirator (NIOSH/MSHA approved) during application and other use
oP this product until vapors and mists are exhausted, unless air moni-
toring demonstrates vapor and mist levels are below applicable limits.
Follow respirator manufacturer's directions for respirator use. Observe
OSHA Standard 29CFR 1910.134.
VENTILATION:
Provide general clean air dilution or local exhaust ventilation in
volume and pattern to keep the air contaminant concentration below the
lower explosion limit and below current applicable exposure limits.
Refer to OSHA SLIULddrd. 1910.94.
NOTE: Heavy solvent vapors should be removed from lower levels of the work
area and all ignition sources (nonexplosion-proof motors, etc.)
should be eliminated.
PROTECTIVE GLOVES:
Use solvent impermeable gloves to avoid contact with product.
EYE PROTECTION:
Do not get in eyes. Use safety eyeo:ear with splash guards or side
shields, chemical goggles, face shields.
OTHER PROTECTIVE EQUIPMENT:
Avoid contact with skin. Use protective clothing. Prevent contact with
contaminated clothing. Wash contaminated clothing, including shoes,
before reuse.
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SECTIGN IX SPECIAL PRECAUTIONS
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* STY20L 040-0004 =
x MATER.IAL SAFETY DATA SHEET F
0400004RI
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING:
Do not store above 100 deg. F. Store large quantities in buildings
designed to comply with OSHA 1910.106. Keep away from heat, sparks and
flame. Keep containers closed when not in use and upright to prevent
leakage.
OTHER PRECAUTIONS:
Containers should be grounded when pouring. Do not take internally.
Wash hands after using and before smoking or eating. Emptied containers
may retain hazardous residue and explosive vapors. Keep away from heat,
sparks and flames. Do not cut, puncture or weld on or near emptied con-
tainers. Follow all hazard precautions given in this data sheet until
container is thoroughly cleaned or destroyed. I= this product is
blended with other components such as thinners, converter, colorants and
catalysts prior to use, read all warning labels. Any mixture of com-
ponents will have hazards of all components. Follow all precautions.
If spraying this material, keep spray booths clean. Avoid buildup of
spray dust or overspray in booths or ducts.
KEEP OUT OF REACH OF CHILDREN FOR INDUSTRIAL USE ONLY
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SECTION X Sara Title III Information
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SARA 313 INFORMATION:
This product contains the following substances subject to the
reporting requirements of Section 313 of Title III of the Superfund
Amendments and Reauthorization Act of 1986 and 40 CFR. Part 372:
STYRENE MONOMER
CAS# 000100-42-5 PCT BY WT: 100.0000
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CCP COMPOSITES US
LIMITED WARRANTY AND LIMITATION OF LIABILITY
LIMITED WARRANTY. Seller warrants that: (i) Buyer shall obtain good title
to the product sold hereunder, (ii) at shipment such product shall conform
to Seller's specifications for the product; and (iii) the sale or use of
such product will not infringe the claims of any U.S. patent covering the
product itself, but Seller does not warrant against infringement which
might arise by the use of said product in any combination with other
products or arising in the operation of any process.
SELLER MAKES NO OTHER WARRANTY OF ANY KIND, EXPRESS OR IMPLIED, INCLUDING
WITHOUT LIMITATION ANY WARRANTY OF MERCHANTABILITY OR FITNESS FOR ANY
PARTICULAR PURPOSE, EVEN IB THAT PURPOSE IS KNOW14 TO SELLER. ANY ADDITIONL
REPRESENTATIONS OR SUGGESTIONS REGARDING THE PRODUCT OR ITS POSS113LE USES
ARE BASED UPON SELLER'S GOOD FAITH OPINION AND BELIEF, BUT ARE NOT TO BE
CONSTRUED AS AFFIRMATIONS OF FACT, PROMISES, OR DESCRIPTIONS, AND SHALL IN
NO WAY BE DEEMED PART OF THE SALE OF PRODUCT.
In particular, and without limiting the foregoing, because of environmental
and use conditions beyond Seller's control, Seller offers no warranty and
makes no promise concerning the results that may be obtained by the Buyer
(or the Buyer's customer) with the product or the performance of the
product. Each user should satisfy itself, by adequate testing, of the
suitability of the product for its particular application.
LIMITATION OF LIABILITY. (a) Seller's total liability for any claim
arising out of or in connection with this contract, including for breach of
contract, warranty, statutory duty, or for other tort, including seller's
negligence, shall not exceed the purchase price of such product as to which
such liability arises. Seller shall not be liable for any injury, loss or
damage, resulting from the handling or use of the product shipped hereunder
whether in the manufacturing process or otherwise.
IN NO EVENT SHALL SELLER BE LIABLE FOR SPECIAL, INCIDENTAL OR CONSEQUENTIAL
DAMAGES, INCLUDING WITHOUT LIMITATION LOSS OF PROFITS, CAPITAL OR BUSINESS
OPPORTUNITY, DOWNTIME COSTS, OR CLAIMS OF CUSTOMERS OR EMPLOYEES Or BUYER,
Page 6 of 6
STYPOL 040-0004
MATERIAL SAFETY DATA SHEET
* 0400004R1
WHETHER IN AN ACTION UNDER CONTRACT, NEGLIGENCE OR ANY OTHER THEORY,
ARISING OUT OF OR IN CONNECTION WITH THIS CONTRACT, OR THE USE, INABILITY
TO USE, OR PERFORMANCE OF THE PRODUCT.
(b) If Seller furnishes technical or other advice to Buyer, whether or not
at Buyer's request, with respect to processing, further manufacture, other
use or resale of the products, Seller shall not be liable for, and Buyer
assumes all risk of, such advice and the results thereof. (Rev. 01/12)