HomeMy WebLinkAboutSAFETY DATA SHEET - PERKADOX 26SAFETY DATA SHEET
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Version 1 Revision Date 04/26/2015 Print Date 09/02/2015 US / Z8
THESE PLANS 00 ALL PROPOSED WORK
ARE SUBJECT TO ANY CORRECTIONS
1. PRODUCT AND COMPANY IDENTIFICATION
REQUIRED BY FIELD INSPECTORS THAT
Product name
PERKADOX 26 MAY BE fECEF13 Y Intl ORDO TO
C01A LY WITH ALL APPLt0ASK E C0ES.
Product Use Description
Polymerization initiator
Company
Akzo Nobel Functional Chemicals LLC r`�`�Q
525 West Van Buren 1v 4 p";
Chicago IL 60607-3823 �j®
Telephone
USA
+18008287929
Fax
+13125447188
E-mail address
RegulatoryAffairs@akzonobel.com
Emergency telephone
AkzoNobel: +31 57 06 79211 CHEMTREC - USA: 1-800-424-9300
CANUTEC - CANADA: 1-613-996-6666
2. HAZARDS IDENTIFICATION
Emergency Overview
Appearance
flakes
Color
white
Odor
faint
Hazard Summary
Risk of dust explosion.
GHS Classification
Organic peroxides, Type D
Skin sensitization, Category 1
GHS Label element
Hazard pictograms
Signal Word
Hazard Statements
Precautionary Statements
* 41>
Danger
H242 Heating may cause a fire.
H317 May cause an allergic skin reaction.
Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces. -
No smoking.
P220 Keep away from dirt, rust, chemicals in particular.
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P234 Keep only in original container.
P261 Avoid breathing dust or fume.
P272 Contaminated work clothing must not be allowed out of
the workplace.
P280 Wear protective gloves/ eye protection/ face protection.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P333 + P313 If skin irritation or rash occurs: Get medical
advice/ attention.
P363 Wash contaminated clothing before reuse.
P370 + P378 In case of fire: Use dry sand, dry chemical or
alcohol -resistant foam for extinction.
Storage:
P403 + P235 Store in a well -ventilated place. Keep cool.
P410 Protect from sunlight.
P411 Store at temperatures not exceeding 20°C/ 68T.
P420 Store away from other materials.
Disposal:
P501 Dispose of contents/container in accordance with local
regulation.
Potential Health Effects
Inhalation
Product dust may be irritating to respiratory system.
Skin
Product dust may be irritating to skin.
May cause an allergic skin reaction.
Eyes
Product dust may be irritating to eyes.
Ingestion
May be harmful if swallowed.
Aggravated Medical
None known.
Condition
Symptoms of Overexposure
The symptoms and effects are as expected from the hazards
as shown in section 2. No specific product related symptoms
are known.
Carcinogenicity:
[ARC
No ingredient of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
OSHA
No ingredient of this product present at levels greater than or
equal to 0.1 % is identified as a carcinogen or potential
carcinogen by OSHA.
NTP
No component of this product present at levels greater than or
equal to 0.1 % is identified as a known or anticipated
carcinogen by NTP.
ACGIH
No ingredient of this product present at levels greater thari or
equal to 0.1 % is identified as a carcinogen or potential
carcinogen by ACGIH.
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3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous inaredients
US/Z8
Chemical Name
CAS -No.
Classification
Concentration [%]
D rnyristyl peroxydicarbonate
53220-22-7
Org. Perox. D; H242
Skin Sens.1; H317
90 - 100
Dimynstyl peroxydIcarbonate, neat
For the full text of the H-Statements mentioned in this Section, see Section 16.
4. FIRST AID MEASURES
General advice
Move out of dangerous area.
Consult a physician.
Show this material safety data sheet to the doctor in
attendance.
Inhalation
Remove to fresh air.
Rinse nose and mouth with water.
Skin contact
Take off contaminated clothing and shoes immediately.
Wash the skin immediately with soap and water.
If skin irritation persists, call a physician.
Eye contact
Rinse with plenty of water.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
Ingestion
Clean mouth with water and drink afterwards plenty of water.
Never give anything by mouth to an unconscious person.
Obtain medical attention.
Notes to physician
Symptoms
The symptoms and effects are as expected from the hazards
as shown in section 2. No specific product related symptoms
�I
are known.
Treatment
I
Treat symptomatically.
5. FIRE -FIGHTING MEASURES
Suitable extinguishing media
Use water spray, alcohol -resistant foam, dry chemical or
carbon dioxide.
Unsuitable extinguishing
High volume water jet
media
Specific hazards during fire
CAUTION: reignition may occur.
fighting / Specific .hazards
Supports combustion.
arising from the chemical
Do not use a solid water stream as it may scatter and spread
fire.
Water spray may be ineffective unless used by experienced
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firefighters.
Heating may cause decomposition with release of toxic fumes.
Risks of ignition followed by flame propagation or secondary
explosions shall be prevented by avoiding accumulation of
dust, e.g. on floors and ledges.
Combustion products Fire will produce smoke containing hazardous combustion
products (see section 10).
Special protective equipment In the event of fire, wear self-contained breathing apparatus.
for fire-fighters
Further information Use water spray to cool unopened containers.
See also Section 9. Physical and chemical properties: Safety data
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Use personal. protective equipment.
Avoid dust formation.
Avoid breathing dust.
Ensure adequate ventilation.
Remove all sources of ignition.
Environmental precautions
Prevent product from entering drains.
Methods for cleaning up /
Keep wetted with water.
Methods for containment
Soak up with inert absorbent material and dispose of as
hazardous waste.
Confinement must be avoided.
Pick up and arrange disposal without creating dust.
Keep in suitable, closed containers for disposal.
Never return spills in original containers for re -use.
Additional advice
For personal protection see section 8.
7. HANDLING AND STORAGE
Handling
Advice on safe handling
Advice on protection against
fire and explosion
For personal protection see section 8.
Avoid formation of respirable particles.
Keep away from heat/sparks/open flames/hot surfaces. - No
smoking.
Persons with a history of skin sensitization problems or
asthma, allergies, chronic or recurrent respiratory disease
should not be employed in any process in which this mixture is
being used.
Smoking, eating and drinking should be prohibited in the
application area.
Open drum carefully as content may be under pressure.
Use explosion protected equipment.
Provide appropriate exhaust ventilation at places where dust
is formed.
Keep away from sources of ignition - No smoking.
No sparking tools should be used.
Keep away from reducing agents (e.g. amines), acids, alkalies
and heavy metal compounds (e.g. accelerators, driers, metal
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soaps).
Do not cut or weld on or near this container even when empty.
Keep away from combustible material.
Temperature class It is recommended to use electrical equipment of temperature
group T3. However, autoignition can never be excluded.
Storage
Requirements for storage No smoking.
areas and containers Keep in a dry place.
Observe label precautions.
Electrical installations / working materials must comply with
the technological safety standards.
Store at room temperature in the original container.
Keep only in original container.
Store away from other materials.
Maximum storage 15 °C (59 °F)
temperature:
Other data No decomposition if stored and applied as directed.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines
Contains no substances with occupational
exposure limit values.
Engineering measures
Explosion proof ventilation recommended.
Provide appropriate exhaust ventilation
at places where dust is formed.
Personal protective equipment
Eye/face protection
Tightly fitting safety goggles
Hand protection
Glove material: butyl -rubber
Glove material: Neoprene
Skin and body protection
Protective suit
Respiratory protection
Half mask with a particle filter P2 (EN 143)
Hygiene measures
Handle in accordance with good industrial hygiene and safety
practice.
When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday.
Wash contaminated clothing before re -use.
Environmental exposure controls
General advice : Prevent product from entering drains.
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9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Form
flakes
Color
white
Odor
faint
Odor Threshold
No data available
US/Z8
Safety data
pH
Weakly acidic
Melting point
Decomposes before melting.
Boiling point/boiling range
Decomposes below the boiling point.
Flash point
Not applicable
Evaporation rate
Not applicable
Flammability (solid, gas)
Decomposition products may be flammable.
Lower explosion limit
No data available
Upper explosion limit
No data available
Vapor pressure
Not applicable
Relative vapor density
Not applicable
Relative density
1.28 at 20 °C
Bulk density
480 kg/m3 at 20 °C
Water solubility
at 20 °C
insoluble
Solubility in other solvents
No data available
Partition coefficient: n-
log Pow: 6.5
octanol/water
Autoignition temperature
Test method not applicable
Decomposition temperature
SADT - (Self accelerating decomposition temperature) is the
lowest temperature at which self accelerating decomposition
may occur with a substance in the. packaging as used in
transport. A dangerous self -accelerating decomposition
reaction and, under certain circumstances, explosion or fire
can be caused by thermal decomposition at and above the
SADT. Contact with incompatible substances can cause
decomposition below the SADT.
Self -Accelerating
35 °C
decomposition temperature
(SADT)
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Viscosity, dynamic
Not applicable
Viscosity, kinematic
Not applicable
Explosive properties
Not explosive
Oxidizing properties
Not classified as oxidizing.
Active Oxygen Content
2.98 %
Organic peroxides
> 96 %
This material safety datasheet only contains information relating to safety and does not replace any
product information or product specification.
10. STABILITY AND REACTIVITY
Conditions to avoid
Confinement must be avoided.
Heat, flames and sparks.
For safety, store below:
15 'C
(59 -F)
Materials to avoid
Contact with incompatible materials will result in hazardous
decomposition.
For queries regarding the suitability of other materials please
contact the supplier.
Do not mix with peroxide accelerators, unless under controlled
processing.
Use only stainless steel 316, PP, polyethylene or glass -lined
equipment.
Acids and bases
Iron
Copper
Reducing agents
Heavy metals
Rust
Hazardous decomposition
1-Tetradecanol
products
Carbon oxides
Thermal decomposition
SADT - (Self accelerating decomposition temperature) is the
lowest temperature at which self accelerating decomposition
may occur with a substance in the packaging as used in
transport. A dangerous self -accelerating decomposition
reaction and, under certain circumstances, explosion or fire
can be caused by thermal decomposition at and above the
SADT. Contact with incompatible substances can cause
decomposition below the SADT.
Reactivity
Stable under normal conditions.
Chemical stability
Stable under recommended storage conditions.
Hazardous reactions
Dust may form explosive mixture in air.
Self -Accelerating
35 °C (95 °F)
decomposition temperature
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(SADT)
11. TOXICOLOGICAL INFORMATION
PRODUCT INFORMATION:
Toxicology Assessment
Further information
Carcinogenicity:
IARC
OSHA
NTP
ACGIH
Print Date 09/02/2015
No further data available.
uS/Z8
No ingredient of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
No ingredient of this product present at levels greater than or
equal to 0.1 % is identified as a carcinogen or potential
carcinogen by OSHA.
No component of this product present at levels greater than or
equal to 0.1 % is identified as a known or anticipated
carcinogen by NTP.
No ingredient of this product present at levels greater than or
equal to 0.1 % is identified as a carcinogen or potential
carcinogen by ACGIH.
TOXICOLOGY DATA FOR THE INGREDIENTS:
Test result
Component: Dimyristyl
Peroxydicarbonate
Acute oral toxicity
LD50: > 2,000 mg/kg
Species: Rat
Skin irritation
Species: Rabbit
Result: No skin irritation
Eye irritation
Species: Rabbit
Result: No eye irritation
Sensitization
Species: Mouse
Classification: May cause sensitization by skin contact.
Repeated dose toxicity
Species: Rat
Application Route: Oral
Exposure time: 43 - 48 d Q
NOEL: > 1,000 mg/kg
Germ cell mutagenicity
Genotoxicity in vitro Ames test
Result: negative
Genotoxicity in vivo Result: Not mutagenic.
Reproductive toxicity/Fertility Species: Rat, males
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Application Route: Oral
•
Dose: 0, 100, 300, 1000 milligram per kilogram
General Toxicity Parent: NOAEL (No observed adverse effect
level): 1,000 mg/kg body weight/day
General Toxicity F1: No observed adverse effect level F1:
1,000 mg/kg body weight/day
Fertility: No observed adverse effect level Parent: 1,000 mg/kg
body weight/day
Method: OECD Test Guideline 422
GLP: yes
Result: no effects
Target Organ Systemic
Routes of exposure: Ingestion
Toxicant - Repeated
The substance or mixture is not classified as specific target
exposure
organ toxicant, repeated exposure.
i
Aspiration toxicity
No aspiration toxicity classification
12. ECOLOGICAL INFORMATION
PRODUCT INFORMATION:
Ecotoxicology Assessment
Additional ecological
None known.
information
Further information on ecology
Hazardous to the ozone layer
Regulation
40 CFR Protection of Environment; Part 82 Protection of
Stratospheric Ozone - CAA Section 602 Class I Substances
Remarks
This product neither contains, nor was manufactured with a
Class I or Class 11 ODS as defined by the U.S. Clean Air Act
Section 602 (40 CFR 82, Subpt. A, App.A + B).
INGREDIENTS:
Test result
Component: Dimyristyl peroxydicarbonate
Ecotoxicity effects
Toxicity to fish
LC50: > 1,000 mg/I
Exposure time: 96 h
Species: Poecilia reticulata (guppy)
Toxicity to daphnia and other
EC50: > 100 mg/I
aquatic invertebrates
Exposure time: 48 h
Species: Daphnia magna (Water flea)
Toxicity to algae
ErC50: > 100 mg/I
Exposure time: 72 h
Species: Pseudokirchneriella subcapitata (green algae)
Test Type: Growth inhibition
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Method: OECD Test Guideline 201
NOEC: 100 mg/I
Exposure time: 72 h
Species: Pseudokirchnedella subcapitata (green algae)
Test Type: Growth inhibition
Method: OECD Test Guideline 201
Toxicity to bacteria EC50: > 1,000 mg/I
Exposure time: 0.5 h
Species: activated sludge
Test Type: Respiration inhibition
Method: Domestic OECD Guideline 209
Elimination information (persistence and degradability)
Bioaccumulation BIoconcentration factor (BCF): 381.4
Does not bioaccumulate.
Biodegradability Result: Readily biodegradable.
Method: Closed Bottle test
13. DISPOSAL CONSIDERATIONS
Product
Contaminated packaging
14. TRANSPORT INFORMATION
International Regulation
IATA-DGR
UN/ID No.
Class
IMDG-Code
UN number
Proper shipping name
Class
• Packing group
Labels
EmS Code
Do not dispose of waste into sewer.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Hazardous waste
Dispose of contents/container in accordance with local
regulation.
Empty remaining contents.
Dispose of as unused product.
Do not bum, or use a cutting torch on, the empty drum.
Due to the high risk of contamination recycling/recovery is not
recommended.
Follow all warnings even after the container is emptied.
UN 3116
5.2
Not permitted for transport
UN 3116
ORGANIC PEROXIDE TYPE D, SOLID, TEMPERATURE
CONTROLLED
(Dimydstyl peroxydicarbonate)
5.2
Not Assigned
5.2
F-F, S-R
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Marine pollutant
no
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Further information for transport
Control temperature
20 °C (68 °F)
Emergency temperature
25 °C (77 °F)
Domestic regulation
49 CFR
UN/ID/NA number
UN 3116
Proper shipping name
Organic peroxide type D, solid, temperature controlled
(Dimyristyl peroxydicarbonate, >96%)
Class
5.2
Packing group
:. II
Labels
5.2
ERG Code
148
Marine pollutant
no
Reportable Quantity
This product does not contain an environmentally hazardous
i
substance per49 CFR 172.101, Appendix A.
15. REGULATORY INFORMATION
Notification status
CH INV YES. On the inventory, or in compliance with the inventory
TSCA YES. All chemical substances in this product are either listed on the
TSCA Inventory or in compliance with a TSCA Inventory exemption.
DSL YES. All components of this product are on the Canadian DSL.
AICS YES. On the inventory, or in compliance with the inventory
NZIoC NO. Not in compliance with the inventory
ENCS YES. On the inventory, or in compliance with the inventory
ISHL YES. On the inventory, or in compliance with the inventory
KECI NO. Not in compliance with the inventory
PICCS YES. On the inventory, or in compliance with the inventory
IECSC NO. Not in compliance with the inventory
For explanation of abbreviations, see section 16.
TSCA list Not relevant
OSHA Hazards Combustible dust, Organic Peroxide, Skin sensitizer
EPCRA - Emergency Planning and Community Right -to -Know
CERCLA Reportable Quantity
This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
SARA 311/312 Hazards Reactivity Hazard
Acute Health Hazard
SARA 302 No chemicals in this material are subject to the reporting
requirements of SARA Title III, Section 302. .
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SARA 313 This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.
Clean Air Act
This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air
Act Section 12 (40 CFR 61).
This product does not contain any chemicals subject to disclosure and listed under the U.S. Clean
Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI
Intermediate or Final VOC's (40 CFR 60.489).
Clean WaterAct
This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act,
Section 311, Table 116.4A.
This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act,
Section 311, Table 117.3.
This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307
US State Regulations
Massachusetts Right To Know
No components are subject to the Massachusetts Right to
Know Act.
Pennsylvania Right To Know
Dimyristyl peroxydicarbonate 53220-22-7 90 - 100 %
New Jersey Right To Know
Dimyristyl peroxydicarbonate 53220-22-7 90 - 100 %
California Prop. 65
This product does not contain any chemicals known to the State of California to cause cancer, birth,
or any other reproductive defects.
16. OTHER INFORMATION
Full text of H-Statements
H242 Heating may cause a fire.
H317 May cause an allergic skin reaction.
Further information
HMIS Classification Health Hazard: 1
Flammability: 3
Physical hazards: 3
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NFPA Classification Health Hazard: 2
• j Fire Hazard: 3
Reactivity Hazard: 2
Notification status explanation
REACH 1907/2006 (EU)
CH INV Switzerland. New notified substances and declared preparations
TSCA United States TSCA Inventory
DSL Canadian Domestic Substances List (DSL)
AICS Australia Inventory of Chemical Substances (AICS)
NZIoC New Zealand. Inventory of Chemical Substances
ENCS Japan. ENCS - Existing and New Chemical Substances Inventory
ISHL Japan. ISHL - Inventory of Chemical Substances
KECI Korea. Korean Existing Chemicals Inventory (KECI)
PICCS Philippines Inventory of Chemicals and Chemical Substances
(PICCS)
IECSC China. Inventory of Existing Chemical Substances in China (IECSC)
Further information
Revision Date 04/26/2015
The information in this material safety data sheet should be provided to all who will use, handle,
store, transport or otherwise be exposed to this product. The user must determine the
appropriate measures that need to be implemented for the use and handling of this product in
the c ontext of the user's operations and use of this product. The information contained herein
supersedes all previously issued bulletins on the subject matter covered. If the date on this
document is more than three years old,call to make certain that this sheet is current. No warranty
is made as to the product's merchantability or fitness for any particular purpose, or that any
suggested use will not infringe any patent. User must determine for himself, by preliminary tests
or otherwise, the suitability of this product for his purposes, including mixing with other products.
Nothing contained herein shall be construed as granting or extending any license under any
patent.
The information provided in this Material Safety Data Sheet is correct to the best of our
knowledge, information and belief at the date of its publication. The information given is designed
only as a guidance for safe handling, use, processing, storage, transportation, disposal and
release and is not to be considered a warranty or quality specification. The information relates
only to the specific material designated and may not be valid for such material used in
combination with any other materials or in any process, unless specified in the text.
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