Loading...
HomeMy WebLinkAboutSAFETY DATA SHEET - TRIGONOX Cr SGHNNED St LucPy ie County Version 1 Revision Date 06/10/2015 Print Date 08/06/2015 Us / Z8 1. PRODUCT AND COMPANY IDENTIFICATION Product name TRIGONOX C Product Use Description Polymerization initiator Company Akzo Nobel functional Chemicals LLC 625 West. Van Buren Chicago IL 60607-3823 USA Telephone : +98008287929. Fax +13125447188 E-mail address RegulatoryAffairs@akzonobel.com Emergency telephone AkzoNobel: +31 57 06 79211 CHEMTREC -USA: 1-800424-9300 CANUTEC - CANADA: 1-613-996-6666 2. HAZARDS IDENTIFICATION Emergency. Overview Appearance liquid Color colorless Odor Faint.. GHS Classification Organic peroxides, Type C Acute toxicity, Category 4, Inhalation ,Skin irritation, Category 2 Skin sensitization, Category 1 Acute aquatic toxicity, Category 1 Chronic' aquatic toxicity, Category 3 GHS Label element Hazard pictograms Signal Word : Danger Hazard Statements H242 Heating may cause a fire. H316 Causes skin:initation. H317 May cause an allergic skin reaction. H332 Harmful if inhaled. H400 Very toxic to aquatic life. 1/18 'ers!on 1 Revision Date06/10/2015 Print Date *06/2015 U$ / H412 Harmful to aquatic life with long lasting effects. Precautionary Statements Prevention: •P210 Keep away'from heat/sparks/open flameslhot surfaces. - No smoking. P220 Keep away from dirt, rust, chemicals; in particular. P234 Keep_.only,in original container. P261 Avoid breathing 'mist, vapours or spray. P264 Wash" skin thoroughly. after handling. P271 Use only outdoors or in a well -ventilated area. P272 Contaminated -work clothing must not be allowed out of the workplace. P273 Avoid° release to the environment. P280 Wear protective ;gloves/ eye protection/ face protection. Response: P302 + P362 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P312 Call a POISON CENTER or doctor/ physician if you feel unwell. P333 + P313 If, skin irritation or rash occurs: Get medical advice/ attention. P362 Take off contaminated -clothing and wash before reuse. P363 Wash contaminated clothing before reuse. P370 + P3791h case of fire:.Use water spray, alcohol -resistant foam, dry chemical or carbon dioxide. to extinguish. P391 Collect spillage. Storage: P403 + P235 Store in a well -ventilated place. Keep cool. P410 Protect from,sunlight. P420 Store away from other materials. Disposal: P501 Dispose of contents/container in accordance' with local regulation. Potential Health Effects Inhalation : Inhalation of aerosols may cause irritation to mucous membranes. Thermal decomposition can lead to release of irritating gases and vapors. Harmful if inhaled. Skin Causes skin irritation. May cause an allergic skin reaction. Eyes May cause eye irritation. Ingestion May cause irritation of the, mucous membranes. Aggravated Medical None known: Condition Symptoms of Overexposure The symptoms and effects are as. expected from the hazards as shown in section 2. No specific product related symptoms are known. Carcinogenicity: IARG No ingredient of this product present at levels greater than :or 2/18 TRI'aON®X C Version 1 Revision Date 06/1 0/201 5 ~ Print Date 08/06/2015 US / Z8 equal, to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA _ No ingredient of this product present at levels, greater than or equal to 0.1% is identified as a.carcinogenL or potential carcinogen by OSHA. NTP No. component of this product present at levels greater than or equal to 0.10% is identified as a.known: or -anticipated carcinogen by NTP. ACG[H No ingredient of this product present at levels greater than or equal to- 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. 3/18 TRIGONOX C Version 1 Revision Date 06/16/2015 Print Date 08/06/2015 US / Z8 3. COMPOSITION/INFORM /1FOR C?N IftiIGREiD(ENTS Hazardous Ingredients Chemical Jbrne CAS -No. Classification Concentration ['/o] tert-ButyIperox Thenzoate 614-45-9 Org. Perox. C;-H242 90 - 100 Acute Tox. 4;'H332 .Skin brit. 2; H315 Skin Sens.1; H317 Aquatic Acute 1; H400 Aquatic Chronic3, H412 NWactor (Acute):1 Pert -Butyl peroxybenzoate, neat For the full text of the H,Statements mentioned in this Section, see Section 16. 4. FIRST Alu MEASURES General advice Move out of dangerous area. Consult a physician. Show,this material safety data sheet to the doctor in attendance. Inhalation If breathed in, move person into fresh air. Consult• a physicianafter significant exposure. Skin contact Take off contaminated clothing and shoes immediately. Rinse immediately with plenty of water: If, skin irritation persists, calla, physician. Eye contact Rinse with plenty of water. Remove contact lenses. • Protect. unharmed eye. Keep eye.wide open while rinsing. if eye irritation persists, consult a specialist. Ingestion Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an unconscious person. Obtain medical attention. Notes to physician Symptoms The symptoms. and effects are as expected from the hazards as shown in section 2. No specific product related symptoms are known. Treatment Treat symptomatically. 5. FIRE FIGHTING MEASURES —. Suitable extinguishing media Use water spray, alcohol -resistant foam, dry chemical or carbon dioxide. Unsuitable extinguishing High volume water jet 4/18 Version 1 Revision Date 06/10/201.5 Print Date 08/06/2015 US:./ Z8 media Specific hazards during fire fighting / Specific hazards CAUTIOW reignition may occur. arising from the chemical Supports combustion. Do not use a solid water stream as it may scatter and spread fire. Water spray may be ineffective unless used by experienced firefighters. Heating may cause decomposition with release of toxic fumes. Do not allow run-off from fire fighting to enter drains. or water courses. ; Combustion products Fire will produce smoke containing hazardous combustion Products (see section 1.0), Special protective equipment for fire-fighters In the event of fire, wear self-contained breathing apparatus. .i Further information Usewater spray'to coot unopened container's. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. See also Section 9. Physical and chemical properties: Safety data 6. ACGIDENTAiL RELEASE MEASURES Personal precautions Use personal protective equipment. Ensure adequate ventilation. Remove all sources of ignition. Beware of vapors accumulating to form explosive concentrations. Vapor; can accumulate in low areas. Environmental precautions ; Prevent product from entering drains. If the product contaminates rivers and lakes or drains inform respective authorities: Methods for cleaning up / Methods for containment Keep wetted with water. Soak up with inert absorbent material and dispose of as. hazardous :waste. Confinement must be avoided. Never return spills in original containers: for re ;use. Additional advice For personal protection see section 8. 7. HANDLING AND STORAGE Handling Advice on safe handling For.personal protection see section 8. Persons. with a history of skin sensitization problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in this which mixture is being used. 'Smoking, eating and drinking should be prohibited in the application area. Provide sufficient air exchange and/or exhaust in work rooms. Open drum carefully as content may be under pressure. 5/18 TRIGONOX C • Version 9 RevisionDafe06/1012015 Print Date 08100/2015 US/Z8 ' Dispose of rinse water. in accordance- with local and national regulations. Avoid contact with skin, eyes and clothing. Advice on protection against fire and explosion Use explosion protected equipment. Keep away from sources of ignition - No smoking. No sparking. tools should be used. Keep away from reducing agents (e.g. amines), acids, alkalies; ' and heavy metal compounds (e.g, accelerators, driers, metal soaps). Do not cut or weld on or near this. container 'even when empty. Keep away from combustible material: Temperature class It is recommended to use electrical .equipment of temperature group T3,. However, au(oignition can'never be excluded. Storage Requirements for storage No smoking. .areas and containers Electrical installations / working materials must 'comply with the technological safety standards. Keep only in original container: Store:away from other materials. Minimum storage Avoid temperatures below: temperature: 10 °C (50 OF) _ Maximum storage 25 'C (77 OF) temperature: Other data No decomposition.if stored and applied as directed. If product freezes .or separates; contact Akzo'Nobel 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Contains no substances with occupational exposure limit values. Occupational exposure limits of decomposition or6rhjr-+im 6/18 TRIGONOX C Version 1 Revision Date06/1.0/2015 Print Date 08/06/2015 US'/Z8 Further Ca: Flotential Occupational Carcinogen information I I See Appendix A ST I 1 ppm I 2013-10-0$ I NIOSH RR information • (a): This standard applies to the industry segments exempt f romthe 1 ppm 8-hour TWA and 5 ppm STH. of the benzene standard at 1910,1028. r i runner r • This -standard applies to the industry segments exempt fromthe 1 ppm )ur TWA -and 5 ppm STEL of the benzene standard at 1910.1028. information (a): This standard applies to the industry segments exempt from the 1 ppm 8-hourTWA and 5 ppm STH. of the benzene standard at 1910.1028. Further See 1910.1028. See Table 4-2 for the limits applicable in the operations or information sectors excluded in 1910.1028 d: The final benzene standard in 1910.1028 applies, to all occupational exposures to benzene'except some subsegments of industry where exposures are consistently under the action level (i.e., distribution and sale of fuels, sealed containers and pipelines, coke production, oil and gas drilling and production, natural gas processing, and the percentage exclusion for liquid mixtures); for the excepted subsegments, the benzene limits in Table Z-2 aooly. .-ILJubrance usreo; Tor more tntormation see OSHA document 1910.1028 information See Table Z-2 for the lints applicable in the operations or sectors excluded in 1910.1028d. (d)Thefinal benzene standard in 1910.1028 applies to all occupational -exposures to benzene except in some circumstances the distrbution and sale of fuels. sealed containers and pipelines, coke production, oil and gas drilling and production, natural gas processing, and the percentage exclusion for liquid mixtures; for the exceptedsubsegments, the benzene limits in Table Z-2 apply. See 1910.1028 for specific rirnimc fdn na'.. �'Ppm 2012-04-03 OSWACAROFurther 1910.1 information This section applies to all occupational exposures to benzene. Chemical Abstracts Service Registry M. 71-43-2, exceptas provided in paragraphs (a)(2).and (a)(3) of this'section. Paragraph (a)(2): This section does not applyto: (i) The storage, transportation, distribution, dispensing, sale or use of gasoline, motor fuels, or other fuels containing benzene subsequent to its final' discharge from bulk wholesale storage facilities, except that operations w here gasoline or motor fuels are dispensed for more than 4 hours per day in an indoor location are covered by this section. (ii) Loading and unloading operations at bulk w holesale storage facilities w hich use vapor control systems for all loading and unloading operations, except for the provisions of 29 CFR 1910.1200 as incorporated into ,this section and the emergency provisions of paragraphs (g) and (i)(4) of this section. (Iii) The storage, transportation, distribution or sale of benzene orliquid .matures containing more than 0:1 percent benzene in intact containers or in transportation pipelines w hile sealed in such a manner as to contain benzene vapors or liquid, exceptfor the provisions of 29 CFR 1910.1200 as incorporated into this section and the emergency provisions of paragraphs (g) and (i)(4)of this section. (N) Containers and pipelines carrying mixtures w ith less than 0.1 percent benzeneand natural gas processing plants processing gas with less than 0.1 percentbenzene.(v) Workoperations w here the only exposure to benzene is fromllquid rrodures containing 0.5 percent or less of benzene by volume, or the vapors released fromsuch liquids until September 12, 1988; work operations where the only exposure to benzene is from liquid mixtures containing 0.3 percent or less of benzene by volume or the vapors released fromsuch liquids fromSeptember 12, 1988, toSepteriter 12, 1989; and work operations where the only exposure to benzene is from liquid mixtures containing 0.1 percent or less of benzene by volume or the vapors released fromsuchliquids after September 12,1989; exceptthattire building machine operators using solvents with more than 0.1 percent benzene are covered by paragraph (1) of this section. (vi) Oil and gas drilling, production and servicing operations. (vfi) Coke oven batteries. Paragraph (a)(3): The 7/18 - Version 1 Revision Date 0611 W2015 Print Date 08/06/2015 US/Z8 cleaning and repair of barges and tankersw hich have contained benzene are excluded from paragraph (f) methods of compliance, paragraph,(e)(1) exposure monitoring -general, and paragraph (e)(6) acouracyof monitoring. Engineering and w ork practice controls shall be used to keep exposures below 10 ppm unless it is proven to be not feasible. Benzene(C6HB) (CAS Registry No 71-43-2) means liquefied or gaseous benzene. it includes benzene contained in liquid rxtures and the benzene vapors released by these liquids. it does not include trace amounts of unreacted benzene contained in solid materials OSHA specifically regulated —,---en 5 ppm 1 1 2012-04n3 ncue information This section applies to all occupationalexposures to benzene. Chemical Abstractsservice registry No.71-43-2. except as provided in paragraphs (a)(2) and (a)(3) of this section. Paragraph (a)(2):' This section does not -apply to: (i) The storage, transportation, distribution, dispensing, sale or use of gasoline, motor fueis;orotherfuels containing benzene subsequent toits final discharge ftam bulkw' holesale storage facilities, except that operations w here gasoline or ►rotor fuels are dispensed for more than 4 hours per day In an indoor location are covered by this section. 01) Loading and unloading operations at bulk whole-tale storage facuitiesw hich use vaporcontrol systems -for all loading and unloading operations, except for the provisions of 29 CFR 1910.1200 as incorporated into this section and the emergency Provisions of paragraphs (g) and (i)(4)of this section. (III) The storage, transportation, distribution or sale Of benzene or liquid mixtures containing more than 0.1 percent benzene in intact containers or in transportation n pipelines w hile sealed in such a manner as to contain benzene vapors or liquid, exceptfor.the provisions of 29 CFR 1910.1200 as incorporated into this section and the emergency provisions of 'paragraphs (g) and,(i)(4) of this section. (iv) Containers and pipelines carrying matures with less than0.1 Percent benzene and natural gas processing plants processing gas with less than 0.1 percent benzene. (v) Work operations w here the only exposure to benzene is from liquid mixtures containing 0.5percent or less of benzene by volume, or the vapors released from such liquids until September 12, 1988; work operations where the only exposure to benzene is from liquid mixtures containing 0.3 percent or less of benzene by volume or the vapors released fromsuch liquids from September 12, 1988, to September 12, 1989; and work operations where theonly exposure to benzene is from liquid mixtures containing'0.1 percent or less of benzene by volume ofthe vapors released from such liquids after September 12,1989; exceptthattire building machine operators using solvents.with more than 0A percent benzene are covered by paragraph (I) of this section. (vi) Oil and gas drilling, production and servicing operations. (vii)'Coke oven batteries. Paragraph(a)(3): The cleaning and repair of barges and tankers w hich have contained benzene are.excluded fromparagraph(f) methods of compliance, paragraph(e)(1) expgsurenanitoring-general, and paragraph (e)(6) accuracyof monitoring. Engineering and w ork practice controls shall be used to keep exposures below 10 ppm unless it is proven to be not feasible. Benzene (C61-16) (CAS Registry M. 71-43-2) means liquefied or gaseous benzene, it includes benzene contained in liquid mixtures and the benzene vapors released by these liquids. it does not include trace amounts of unreacted benzene contained in solid materials information A4: Not ciassifiableas a 7VVA 100 ppm 300 mg/m3 ST 150 ppm 450 mg/m3 ?WA, 100 ppm 300 mg/m3 Further (b): The value in mg/m3 i information. TWA 100 ppm 450 mg/r Itch exane; 107-83-5, TWA 500 ppm isohexane 107-83-5 9118 Version.1 Revision Date 06/10/2015 Print Date 08/06/2015 US / Z8 information LlUpper Respiratory Tract irritation Upper TEL 9 ,0()0 ppm 20'! 2-01 ACI IH Further Central Alervous System impairment Information Upper Respiratory Tract irritation Eye -irritation TWA 500 ppm 1989 01-19 OSHA ru 1,800 rw/m3 information ppm Acetone 67-64-1, 67- 90 mnute ceiling value iWA 50DPPm 2013 03-01 ACGiy 64-1 Further information Central Nervous System impairment Hematologic effects Upper Respiratory Tract irritation Eye irritation ().- Adopted values or notations enclosed are those for which changes are Proposed in the NIC See Notice of intended Changes (NIC) Bp: Substances forwhich there is a Biological Exposure index or Indices (see BEM section) A4: Not classifiable as ahucman nnrr7nn _ Further information information matologic .effects Upper Respiratory Tract irritation Eye irritation O: Adopted values or notatlons•enctosed are those f or w hich:changes are Proposed in the NIC. See Notice of Intended Changes (NIC) BEI: Substances forwhich there is a Biological Exposure Index or Indices (see BEM section) A4: Not classifiable as a human carcinooen information I I is in effecfforatlothersectors. Engineering measures Explosion- proof ventilation recommended: Effective exhaust ventilation system Personal protective equipment Eye/face protection Tightly fitting safety goggles Hand protection Glove material: butyl -rubber Glove material: Neoprene Skin and bodv protection : Protective suit 9/18 Version 1 Revision Date 06/10/2015 Print Date 08/06/2015 US/Z8 Respiratory protection In the case of vapor or'aerosol formation use a respirator with an approved filter. Filter A Hygiene measures Handle in accordance with good industrial .hygiene and safety practice. When using do not eat !or drink. When using do not smoke. Wash hands before breaks and at the end of workday. Wash contaminated clothing before re -use. Environmental exposure controls General advice Prevent product from entering drains. If the product contaminates rivers and lakes or drains inform 'respective authorities. 9. PHY,. ICAL AND CHEMICAL PROPERTIES Appearance Form liquid Color colorless Odor Faint. Odor Threshold No data available Safety data pH neutral Melting point 9 - 11 °C Boiling point/boiling range : Decomposes below the boiling g point. Flash point Above the SADT value Evaporation rate No data available Flammability (solid, gas) Decomposition products may be flammable. Lower explosion limit I No data available Upper explosion limit No data available Vapor pressure .0.4 hP'a at 50 °C Relative vapor density : No data available Relative density : 1.04 at 20 °C Bulk density : Not applicable Water solubility : at 20 °C immiscible Solubility in other solvents Soluble in most organic solvents. 10 / 18 TRIGGNGX C Version Revision Date 06/1012015 Print Date 08/06/2015 US/Z8 Partition coefficient: n- a log Pow: 3 octanol/water at 25 °C Autoignitiontemperature Test method not applicable, Decomposition temperature SADT - (Self accelerating decomposition temperature) is the lowest temperature at which self accelerating decomposition may occur with a substance in the packaging as used in transport. A dangerous self -accelerating decomposition reaction and, under certain_ circumstances, explosion or fire can be caused by thermal decomposition at and above the SADT. Contact with incompatible substances can cause decomposition below the SADT. Self -Accelerating : 60 o C decomposition temperature (SADT) Viscosity, dynamic 6 mPa.s at 20 °C Viscosity, kinematic 5.77 mm2/s at 20 'C Explosive properties Not explosive Oxidizing properties Not classified as oxidizing. Active Oxygen Content ; 8 ova Organic peroxides 98 This, material safety datasheet only contains information relating to safety and does not replace- any product information or product specification. 10. S IAWLI1,Y AND REACTIVITY Conditions to avoid Confinement must be avoided. Heat, flames and, sparks, For safety, store below: 25� °C (77 'F) Materials to avoid Contact with incompatible materials will result in hazardous decomposition. For queries regarding the�suitability of other materials please contact the supplier. Do not mix with peroxide accelerators, unless under controlled processing. Use only stainless steel 316,. PP, polyethylene or glass -lined equipment. Acids and bases Iron Copper Reducing agents Heavy 'metals Rust Hazardous decomposition Benzene products tent-Butanol 11 / 18 Version 1 Revision Date06/10/2015 Print Date 08106/20IS US/Z8 Isohexane Acetone Carbon oxides Thermal decomposition SADT - (Self accelerating decomposition temperature) is the lowest temperature at which self accelerating decomposition may occur'with a substance in,the packaging as used in transport. A dangerous self -accelerating decomposition reaction and, under certain circumstances, explosion or fire can be. caused by thermal decomposition at and above the SADT: Contact with incompatible substances cause .can decomposition below the SADT. Reactivity Stable under normal conditions. Chemical stability Stable under recommended, storage conditions. Hazardous reactions No dangerous reaction ,known under conditions of normal use. Self -Accelerating 60 °C (140 "F) decomposition temperature (SADT) 11. TOXICOLOGICAL INFORMATION PRODUCT INFORMATION: Toxicology Assessment Further information No further data available. Carcinogenicity: IARC No ingredient of this product present at levels greater than or equal to 0.1 % is identified as, probable, possible or confirmed human carcinogen by [ARC.. OSHA No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential NTP carcinogen by OSHA. No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated ACGIH carcinogen by NTP. No ingredient .of this product present, at levels greater than or equal to 0.I is identified as a carcinogen or potential carcinogen by ACGIH. TOXICOLOGY DATA FOR THE INGREDIENTS: Test result Component: tert=ButvI aeroxybenzoate Acute inhalation toxicity LC50 : > 1.01 mg/I Exposure time: 4 h Test atmosphere: aerosol Assessment: The component/mixture is moderately toxic after short term inhalation. 12 / 18 Version 1 Revision Date 06/10/2015 Print Date 08/0612015 US/Z8 Skin irritation Species: Rabbit Result: 'Skin irritation Eye irritation Species: Rabbit Result No eye irritation Repeated dose toxicity Species: Rat Application Route: Oral Exposure time: 90 d O NOEL: 30 mg/kg Germ cell mutagenicity Genotoxicity in vitro In vitro gene mutation study in mammalian cells -Result: positive Ames test Result: positive Method: OECD Test Guideline 471 Chromosome aberration test in vitro Result: positive Genotoxicity in viw In vivo micronucleus test Method: OECD Test Guideline 474 Result: negative Reproductive toxicity/Fertility : Species: Rat, male and female Application Route: Oral Dose: 0, 100, 300. 750, 100o milligram per kilogram General Toxicity Parent: NOAEL (No observed adverse effect level): 300 mg/kg body weight/day General Toxicity F1: No observed adverse effect level F1: 300 mg/kg body weight/day Method: OECD Test Guideline 421 GLP: yes Target Organ Systemic Toxicant - Repeated The substance or mixture is not classified as specific target exposure organ toxicant, repeated exposure. Aspiration toxicity No aspiration toxicity classification 12. ECOLOGICAL INFORMATION PRODUCT INFORMATION: Ecotoxicology Assessment Additional ecological An environmental hazard cannot be excluded in the event of information unprofessional handling or disposal. Very toxic to aquatic life with long lasting effects. Harmful to aquatic life with long lasting effects. 13 /118 TR«ONOX C Version 1 Revision Date06/10/2015 Print Date 08/06/2015 US/Z8 Further information on ecology Hazardous to the ozone layer Regulation 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class.I Substances Remarks This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR`82, Subpt. A, App.A + B). INGREDIENTS: Ecotoxicology Assessment Component-. tert-Butyl peroxvbenzoate Acute aquatic toxicity : Very toxic to aquatic fife. Chronic raquatic toxicity, : Harmful .to aquatic life with. longlasting effects. Test result Com__ponent• tert-Butyl oeroxvbenzoaie Ecotoxicity effects Toxicity to fish LC50: 1.6'mgti Exposure time: 96 h Species: D.anio' rerio (zebra fish) Toxicity to daphnia and other EC50: 11 mg/I aquatic invertebrates Exposure, time: 48 h Species: Daphnia magna (Waterflea) Test Type: static test Method: OECD. Test Guideline.202 Toxicity to algae EC10: 0.44 mg/I Exposure time: 72 h Species: Pseudokirchneriella subcapitata `(green algae) Test Type: -Growth inhibition Method: OECD Test Guideline 201 ErC50: 0.8 mg/I Exposure time: 72 h Species: Pseudokirchneriella subcapitata (green algae) Test Type: Growth inhibition Method: OECD Test Guideline 201 M-Factor 1 Toxicity to bacteria EC50: 43 mg/I Exposure time: 0.5 h Species: activated sludge Test Type: Respiration inhibition Method: Domestic OECD Guideline 209 Elimination information (persistence and degradability) 14 / 18 TRIGONOX C Version 1 Revision Date 06/1'0/2015 Print Date 08/06/2015 Biodegradability . : Result: Readily biodegradable. 13. DISPOSAL CONSIDERATIONS Product The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Hazardous waste Dispose of contents/container in accordance with local regulation. US/Z8 Contaminated packaging Empty remaining contents. Dispose. of as unused product.. Do not bum,- or use a cutting torch on, the empty drum. Due to -the High risk of contamination recycling/recovery is not recommended. Follow all warnings even after the container is emptied. 14. TRANSPORT INFORMATION International Regulation IATA-DGR UN/ID No. Proper shipping name Class Subsidiary risk Packing group Labels Packing instruction (cargo aircraft) Packing instruction (passenger aircraft) Environmentally hazardous IMDG-Code UN number Proper shipping name UN 3103 Organic peroxide type C, liquid (tert-Butyl peroxybenzoate) 5.2 HEAT Not Assigned 5.2 (HEAT) 570 570 yes. UN 3103 ORGANIC PEROXIDE TYPE C, LIQUID Class (tert-Butyl peroxybenzoate) 5.2 Packing group Not Assigned Labels 5.2 EmS Code F-J, S-R Marine pollutant yes (tent -Butyl peroxybenzoate) Transport in, bulk according to Annex II of MARPOL 73/78 and -the IBC Code Not applicable for product -as supplied. Domestic regulation 49 CFR UN/1D/NA number UN 3103 Proper shipping name Organic. peroxide type C, liquid (fed Butyl peroxybenzoate, 98%) 15 / 18 TRIGC NOX C -- Versionl, Revision Date06110/2015 Print Date 08/06/2o15 US, / Z8 Class 5.2 • Packing group : 11 Labels, 5.2 ERG Code, 146 Marine pollutant : yes Reportable Quantity (tert-Butyl peroxybenzoate) This product does ,not contain an environmentally hazardous substance per 49 CFR 172,101, Appendix A. 15,'REGuLA1ORY INFORMATION Notification status CH INV TSCA YES. On the inventory, or in compliance with the inventory YES. All chemical substances in this product are either listed on the DSL s. TSCA Inventory or in compliance with a TSCA Inventory exemption. YES. All components of thisproduct are the Canadian AILS NZIoC on DSL. YES. On the inventory., or in compliance with the inventory ; ENDS YES. On the inventory, or in compliance with'the inventory YES. On the 'inventory, or in ISHL : compliance with the inventory YES. On the inventory, :or in compliance with the inventory. KECI PICCS YES. On the inventory, -or incompliance with the inventory IECSC YES. On the inventory, or'in compliance with the inventory YES. On the inventory, or in compliance with1he inventory For explanation of abbreviations, see section 16. TSCA list Not relevant OSHA Hazards Organic Peroxide, Toxic by inhalation., Skin sensitizer, Moderate skin Irritant EPCRA - Emergency Planning and Community Right=to-Know CERCLA Reportable Quantity This material does not contain any 'components.with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards Reactivity Hazard Acute Health Hazard SARA 302 No chemicals in this material are subject to the reporting requirements of SARA Title ill, Section .302. SARA 313 This material does not contain any chemical components. with known CAS numbers .that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Ciean.AirAct This product does, not contain .any -hazardous. air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61). This product does not contain any chemicals subject to disclosure and listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F): -- This- product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489). Clean Wafer Act /18 - Version 1 Revision Date 06/10/2015 Print Date 08/06/2015 US] Z8 This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, • Section 311, Table 116.4A. This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311,, Table 117.3. This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307 US State Regulations Massachusetts Right To Know tert-Butyl perozybenzoate 614-45-9 96 —100 % Pennsylvania Right To Know tert-Butyl peroxybenzoate 614-45-9 90 -100 New Jersey Right To Know tert-Butyl peroxybenzoate 614-45-9 90 - 100 California Prop. 65 This product does not contain any chemicals, known to the.State of Califomia to cause cancer, birth, or any other reproductive defects. 16. OTHER INFORMATION Full text of H-Statements H242 H315 H311 H332 H400 H412 Further information HMIS Classification NFPA Classification Heating may cause'a fire. Causes _skin irritation. May cause an allergic skin reaction. Harmful if inhaled. Very toxic to aquatic. life. Harmful to aquatic life with long lasting effects. Health Hazard: 2 Flammability: 1 Physical hazards 3 Health Hazard: 2 Fire Hazard: 2 Reactivity. Hazard: 3 Notification status explanation REACH 1907/2006 (EU) CH INV TSCA Svvitzedand. New notified substances and declared. preparations United States TSCA Inventory DSL Canadian Domestic Substances List(DSL) AICS 'Australia Inventory of Chemical Substances (AICS) NZJ60 New Zealand. inventory of Chemical Substances ENCS ISHL Japan. ENCS - Existing and New. Chemical Substances Inventory Japan. ISHL - Inventory of Chemical Substances 17 / 18 TRIGONOX C ^R • Version 1 Revision Date 06/10/2015 Print Date 08/06/2015 US/Z8 KECI Korea. Korean' Existing Chemicals Invenfo PICCS Philippines Inventory of Chemicals .and Che icalCSubstances IECSC (PICCS) China. Inventory of Existing Chemical :Substances ,in China (IECSC) Further information Revision Date 06/10/2015 'The Information in this material safety data sheet should be provided to all who will use, handle, store, transport or otherwise be exposed to this product. The user must determine the appropriate measures that need to be implemented for the use and handling of 'this product in the.c ontext of the user's operations, and use' this product. The information contained herein supersedes all previously Issued bulletins on the subject -matter covered. If the date on this document is more than three years old;call to make certain. that this sheet is current. No, warranty is made as to the product's merchantability. or fitness for any particular purpose,,, or that any suggested use will not infringe any patent. User must determine for himself, b or otherwise, the suitability of this product for his purposes, including mixing with other products. Nothing contained herein shall be construed as granting or extending any license under any patent. The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is. designed only as, a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or: quality'speciffcation. The information relates only to the specific material designated and may not be. valid for such material used in combination with any other materials or in any process, unless specified in the text. 1.8 / 18.