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Home My WebLink AboutDATA SAFETY SHEETS - GORDON AND GORDONJanuary 29, 2019 St. Lucie County Planning & Development Services Building & Code Regulation Division Attn: Mr. Carl Peterson 2300 Virginia Avenue Fort Pierce, FL 34982 Subject: FBC [F]414.1.3 Hazard Identification Report 7485 Commercial Circle Fort Pierce, FL 34951 St. Lucie County Permit Number: 1809-0254 Dear Mr. Peterson: C7 GORDONGOROON ENGINEERING SCANNED BY at. Lumcbmy In my capacity as a Florida Registered Professional Engineer, I have been retained by Boat Builder Central, 7485 Commercial Cir, Fort Pierce, FL, to respond to comments that were received on September 18, 2018 and January 8, 2018 relative to the Boat Builder Central Phase II Commercial Renovation (Permit Number 1809-0254). The comments below have been addressed as follows: 1. COMMENT: IDENTIFY THE MAXIMUM EXPECTED QUANTITIES OF HAZARDOUS MATERIALS TO BE (A) STORED, (B) USED IN A CLOSED SYSTEM AND (C) USED IN AN OPEN SYSTEM. IDENTIFY THE METHODS OF PROTECTION FROM SUCH HAZARDS, INCLUDING BUT NOT LIMITED TO CONTROL AREAS, FIRE PROTECTION SYSTEMS AND GROUP H OCCUPANCIES SHALL BE INDICATED IN THE REPORT AND ON THE CONSTRUCTION DOCUMENTS. THE OPINION AND REPORT SHALL BE PREPARED BY A QUALIFIED PERSON, FIRM OR CORPORATION APPROVED BY THE BUILDING OFFICIAL. RESPONSE: Please refer to the enclosed report, which has been signed and sealed by a professional engineer (PE 80462). 2. COMMENT: THE LETTER DATED 1/3/19 FROM WILLIAM J MORROW STATES EPDXY PRODUCTS WILL BE STOCKED. ADDITIONAL INFORMATION IS REQUIRED PER ([F] 414.1.3). Mr. Carl Peterson January 29, 2019 Page 2 Permit Number: 1809-0254 6 BOROONGORDON ENGINEERING RESPONSE: Please refer to Table 1 in the enclosed report for a detailed list of all chemicals that will be stored onsite. 3. COMMENT: PROVIDE THE MAXIMUM EXPECTED QUANTITIES TO BE STORED. (IF] 414.1.3). RESPONSE: Please refer to Table 1 in the enclosed report for a detailed list of all chemicals and maximum expected quanitites that will be stored onsite. 4. COMMENT: CLASSIFY EACH MATERIAL ACCORDING TO THE CATEGORIES BASED ON TABLES 307.1(1) AND 307.1(2) OF THE FLORIDA BUILDING CODE. RESPONSE: Please refer to Table 1 in the enclosed report for a detailed list of all chemicals and Hazard Classifications. S. SHOW CONTROL AREAS ON THE PLANS. RESPONSE: Since none of the materials that are being stored are High Hazard (Group H) materials, separate control areas have not been established. The entire building is to be considered one control area. If you have any questions regarding the enclosed report and information provided, please do not hesitate to contact me at 321-652-7884. Respectfully, I-3/-l9 Stacy G don, PE (80462) Gordon & Gordon Engineering, LLC (CA # 32802) Mr. Carl Peterson January 29, 2019 Page 3 6 Permit Number: 1809-0254 GORDONGOROON ENGINEERING Background An evaluation was performed based on information that was provided by Boat Builder Central, including drawings (Appendix A), safety data sheets for all materials that will be stored/used (Appendix B), and a description of work that will be performed onsite. It must be understood that the Engineer's evaluation is based soley on the information that was provided, and is assumed to be accurate and authentic. Findings and Recommendations A thorough review of all safety data sheets was performed to determine if any of the materials that will be stored/used onsite are subject to the requirements found in FBC [F] 307.1, High - Hazard Group H, as methods of protection from such hazards, including but not limited to, control areas, fire protection systems, and group H occupancies are required for high -hazard materials. Findings are summarized in Table 1. Although many of the materials are considered nonflammable solids, nonflammable and noncombustible liquids, with health -hazards that are both corrosive and toxic, none of the materials are classified as high -hazard materials that would be subject to Group H occupancy requirements. Further, the estimated quantity to be stored for all materials is less than the maximum allowable quantity per control area in accordance with FBC [F] Table 414.2.5 (1) and 414.2.5 (2). Table 1: Hazardous Material Summary Product Name Stored, Closed System, or Open System Estimated Storage Quantity (gallons) Method of Protection (if required) Occupancy Group Hazard(s) axrmum Allowable Quantity per Control Area Unit Applicable Code Reference Raka UV Inhibited Part B Stored 1 N/A Storage (S-1) Corrosive 975 gallons FBC414.2.5 (1) Toxic 100 gallons FBC 414.2.5 (1) Raka Epoxy Resin UV'Inhibite&PArt A Stored) , 16, ". 'N/A ' Storage ,(S-1).NonrHazardous N/A ). N/A '."_ N/A ', Raka Curing Agents 610, 608, 606, and 260 Tropical Stored 17 N/A Storage (S-1) Corrosive 975 gallons FBC 414.2.5 (1) Toxic 100 gallons FBC 414.2.5 (1) Raka Table Top Hardener 'Stored '2 N/A Storage.(S-1) Corrosive. 975 " • gallons • FBC414.2:5�(1), _ _.... _ Toxic.... _ .100 I. gallons ,FBC 414.2.5 (1)' E-Z Fillet Hardener, Part B Stored 3 N/A Storage (5-1) Corrosive 975 Igallons FBC 414.2.5 (1) Toxic 100 gallons FBC 414.2.5 (1) E-Z Fillet Resin,-PartA ` - - '.Stored'. 7 N/A - Storage (S-1) Toxic' i 100 gallons -FBC414.2.5 (1). Gel Magic Hardener, Part B Stored 4 N/A Storage (S-1) Corrosive 975 gallons FBC 414.2.5 (1) GelMagic Resin, Part A �. ' • .: Stored. - .7 _ N/A _ Storage,(S-1). Toxic 100. I . gallons , FBC 414.2.5 (1). QuikFair Hardener Part B Stored 4 N/A Storage (S-1) Corrosive 975 gallons FBC 414.2.5 (1) Toxic 100 gallons FBC 414.2.5 (1) QuikFair Resin Part A - Stored 9, N/A - ' Storage (S-1) Toxic 100 ; gallons FBC 414.2.5 (1): SilverTip Coating and Laminating Resin Stored 20 N/A I Storage (S-1) Toxic 100 lgallons FBC 414.2.5 (1) SilverTip Fast.Hardener,,PartB. - - .Stored 11 N/A I..Storage (S-1) Corrosive 975 ;. gallons FBC 414.2.5 (1). :..• ' . - -.. .. .• .e; - .,, _.f'. ,,. ._ , .: .._ _ ,.-.... _.. _ Toxic 100 (�: gallons : FBC .414.25.(1); SilverTip Slow Hardener, Part B Stored 15 N/A Storage (S-1) Corrosive 975 gallons FBC 414.2.5 (1) -' - - -= '" •' SilverTip-Yacht, Primer, Part A. - -- - Stored' - .8 ' - N/A .. Storage (S-1) Combustible LiquiddllA, Unsprinklered '1600'!'`- . gallons FBC 414.15 (2). - _ - - - Toxic 100 ''1 '.gallons -FBC 414.2.5 (1): SilverTip Yacht Primer, Part B Stored 2 N/A Toxic 100 gallons FBC 414.2.5 (1) + - '• - -'. - Marine -Plywood • - - Stored' 800sheets' N/A- Storage'(S-1) Non -Hazardous- palletized storage.' Wood,will;nothe machined on -site;-- therefore, combustible- clusts and%or fibers will not be present. ' 't Ij{ N/A :N/A ` . N/A Mr. Carl Peterson January 29, 2019 Page 5 6 Permit Number: 1809-0254 SOROONGOROON ENGINEERING Certification In my capacity as a Florida Registered Professional Engineer (PE 80462) with Environmental and Advanced Building Code endorsements recognized bythe Florida Board of Professional Engineers (FBPE) and the Florida Department of Business and Professional Regulation (DBPR), I, Stacy Nichole Gordon, P.E., certify as follows: 1. 1 have personally researched and reviewed the facts and performed the engineering calculations stated in this transmittal. 2. 1 am informed and believe that, within the limits of the information that was provided, that the proposed materials and quantities to be stored onsite at 7485 Commercial Circle, Fort Pierce, FL 34951, are not subject to High Hazard, Group H Occupancy requirements found in FBC [F] 307.1. Further, the proposed materials and quantities are within the maximum allowable quantites for nonflammable solids, nonflammable, and noncombustible liquids in accordance with FBC [F] Tables 414.2.5 (1) and 414.2.5 (2) for S Occupancies. The information herein has been prepared from referenced sources including relevant specifications, drawings, reports, and engineering calculations. This information is believed to be accurate, authentic, and assumed to be conveyed by persons so authorized. I do not warrant the accuracy of the source material. The conclusions presented herein are made to a reasonable degree of engineering judgement, and is based on my ABET accredited undergraduate engineering education, specialized training, professional engineering licensure, technical certifications, and experience in the environmental, health, and safety field. Respectfully Submitted, Stacy Gordon, P.E. FL P.E. # 80462 Gordon & Gordon Engineering, LLC (CA #. 32802) r ' 0 GOROONGORDON ENGINEERING APPENDIX A Design Drawings A. AA.mR ear mu NAMEDME ASSONE FMOR n MIN. MAY PANG pFWIECNWd MEEx :GG MW BM NR MY DOE10M GO EASS omm 1 OBE MAIMCIA a �E nr CL ¢H gSOrvgYVxrt M CEx CdUMX FEY CORM WARWOM T IN, mM RWION NYVUS MOD C9Nn GWON AO OG CATURED XN OBC BOUGHE SXENG ft BAR CARY BE G EACH .1 D gx90xgIM Sn DOME GUCNAO4 SIR FOR ENGmMR OF RECORD k0 LOR, OUGH MEM m HE NNGNNSM ME, P] HEMMER n9 GA SAME W GO fAAMIGNE TpR NEW CRYG M NOT W Vi C NEW HATERD. WN HR FROUND To vrsuuwoN WHO µ E65CFRZAREWM WON AMAL AWIATERWL .I. NOTTIRSOUT O .STRAND WAgO PEmW/PO ExMAAUINM URPPEOV.LREEmi HEEaUIRE. dEM KING STRATEGIWN, AXN EMO MRAL. SOUIMWIYEUOW NNE yRUq RNEM SAU<1U04 wG41At5mDP MWflE )OPOf PFWHG TYPICAL FRAIDNEGIND WEAN WAD ¢6 ) WFXWW Sheet List FEW ND SIRml Name Nttt Numppr 1 Cerenl Nota SOL 2 LiEe yLeW INGE, 150.2 3 HmEPlanand DMUPrtS A iGW PUM PdneISCMduleand PREFUNN. sm-N R.l S1.2 5 .. WdII X(40DSdRd DMdIIS 53.1 SMPEOFWORK: 1. WSLSAE LBµIF ON.RWASMN lP OVEDBV51NEE5/INDURTWO/5l0RAG EUSEINTIEPAST. INISPERMRWESNWWEaNEGNLDINWUCRLOADBGRINGRWF,WU MD ONORE RIOR WALLS A RENWATER]3SOUAREFEECOFSPACE FOR BUSINESSUSE E. CHANGE EYISRNG FACTORY/INDUSTRIAL AREAS TO STORAGE WNPANCY. ENSUREIXn LEWIS ANDEMERGENCYUGHISAREPROWDEDASSHOWN. 2. ADDWALLSTOENCLGSEMEOFFICEARGO 3. ADDDWB¢ WOR BEIWEEN OFFICE AREA AND WAREHOUSE. 4. ADOWINWW BETUEENOFFICEAREAµDWARNOUSE 5. ADDAIR CONDITIONING To OFFICE ONLY PER ENERGY CALCUIES unO. G. ADD WARRA XEATABOVE RESTRWMS FOR MOPSINKµOTWD UAPTUBJESIN PES@WMS, ). IXIEND C G UNG FRM3ING PER PLAINS TO MERGE CEILING FOR OFFICE 8. EPLSRNG GATHROONS AND FUTURES M REMAIN, WNUNALYOTMEM L COME TOT DUPMIxW BEI GBOU. AWxZXm IN ACCORDANCE WITH CM[VIE0.5 M AND BUT OF ME HONDA SERNEEE M ESE mO1ME Dr MEDORDCE 1. REpUWEMMROi: XG W DE DSM ED W N BUIIpXG, ftC hPRITERGENG, MFOANIULCODEFWM. OMIPIC WDEMCk14 20E .CAPWM,IMED EF04P. 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' EN�INEERIND PHASE 11 COMMERCIAL RENOVATION °Tp• n,�3097� CAk 32295 STATUS: PERMITSET a; 3 o LL n :: p1 z u 7485 COMMERCIAL CIRCLE Wort of P 1555 INDIAN RIVER BLDV. SUITE 8.145 i ' DRAWN BY: EC N a�sfa Gei o,,iG�p° VERO BEACH, FL32960 �� riirim "�� 772.360.4998 n FT. PIERCE, FL ST. LUCIE COUNTY, 34951 STRUCrURALFL@GMAIL.COM REVIEWED BY: TS I ... .......e �m �+vmv...mm�..m..mc ynrvvmveymmeuenennewryurvmarvmmrwm'+wvirsnrmmvrwwrveoymercecgngolwbw�u'Wnem)euMnlbnarrt¢mil6bbenrdeaeem,umWpmrknmmvrrm,wwuuenmfuaevlrwnawmmc vvvgr reew4mnvygweunelmeuvrwrgmrun.mnrnmrpnpgnwmr. APPENDIX B Safety Data Sheets Raka UV Inhibited Part B Slow/Fast MATERIAL SAFETY DATA SHEET SECTION 1- MATERIAL IDENTIFICATION PRODUCT NAME: Raka UV Inhibited Part B Slow/Fast ADDRESS: RAKA INC. 3490 Oleander Ave. Ft. Pierce. FI.34982 MANUFACTURER: RAKA INC. MSDS REVISION NUMBER:1 TELEPHONE NUMBER: (772)489-4070 DATE PREPARED: 6-1-2015 EMERGENCY OVERVIEW HMIS HEALTH RATING 2 FLAMMABILITY 1 REACTIVITY 0 PHYSICAL FORM Mobile Liquid COLOR Amber ODOR Ammoniacal HAZARDS Moderate eye irritant. Moderate respiratory tract irritant. Moderate skin irritant. May cause skin sensitization. EXTINGUISHING MEDIA Ignition will give rise to a Class B fire. In case of large fire, use: Alcohol Foam, Water Spray. In case of small fire, use: CO2, Dry Chemical, Dry Sand, or Limestone. C.A.S. CHEMICAL NAME Mixture EMPIRACAL FORMULA Mixture SYNONYMS None INTENDED USE Curing Agent CHEMICAL FAMILY CycloaliphaticAmine SECTION 2—INGREDIENTS # % CAS Number and Chemical Name 1. >25.00 100-51-6 BENZYLALCOHOL 2. <5.00 1761-71-3 METHYLENEBISCYCLOHEX AN AMINE, 4,4' - THE REMAINING COMPONENTS ARE TRADE SERETS. OSHA (ACGIH) EXPOSURE LIMITS STEL - CEILING ITWA ppm mg/m3 ppm mg/m3 ppm mg/m3 1.OSHA N/E N/E N/E N/E N/E N/E k[ ACGIH N/E N/E N/E N/E N/E N/E N/E N/E N/E N/E N/E N/E !{2.OSHA ACGIH N/E N/E N/E N/E N/E N/E N/E = Not Established. SECTION 3 —HEALTH HAZARDS ROUTES OF EXPOSURE TARGET ORGANS HEALTH HAZARDS Eye Contact Eye Moderate eye irritant. Skin Contact Skin Moderate skin irritant. Ingestion May cause skin sensitization. Skin Absorption EXPOSURE STANDARDS No standards established for the product. Maintain air contaminant concentrations in the workplace at the lowest feasible levels. SIGNS AND SYMPTOMS OF EXPOSURE (Acute effects) Contact with the skin may cause dryness (defeating), itching, and/or rash. Inhalation of mists may cause irritation I I P a g e Raka UV Inhibited Part B Slow/Fast in the respiratory tract. Contact with the skin or eyes causes moderate eye and skin irritation, redness and discomfort which is transient. Coughing and chest pain may result. Product is absorbed through the skin and may cause nausea, headache and general discomfort. SIGNS AND SYMPTOMS OF EXPOSURE (Possible Long Term Effects) Repeated and/or prolonged exposure may cause allergic reaction/sensitization. Repeated and/or prolonged exposures may result in: adverse eye effects (such as conjunctivitis or corneal damage), adverse skin effects (such as defeating, rash, or irritation ). Dryness of nasal passages may be experienced when material is inhaled over a long period of time. MEDICAL CONDITIONS GENERALLY AGGRAVATED BYEXPOSURE Eye disease Skin disorders and allergies CARCINOGENS UNDER OSHA, ACGIH, NTP, IARC, OTHER This product contains no carcinogens in concentration of 0.1 percent or greater. SECTION 4 - FIRST AID EYE CONTACT Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. Seek medical advice. SKIN CONTACT Remove product and immediately flush affected area with water for at least 15 minutes. Remove contaminated clothing and shoes. Seek medical advice. Launder contaminated clothing prior to reuse. INHALATION Move patient to fresh air. If breathing has stopped or is labored give assisted respiration (e.g. mouth -to mouth). Prevent aspiration of vomit. Turn victim's head to the side. Seek medical advice. INGESTION If swallowed, call a physician immediately. Note to Physicians: Remove stomach contents by gastric suction or induce vomiting only as directed by medical personnel. Never give anything by mouth to an unconscious person. SECTION 5 — FIRE AND EXPLOSION DATA FLASH POINT (closed cup) 103.89 C (219)F UPPER EXPLOSION LIMIT (UEL) No data LOWER EXPLOSION LIMIT (LEL) No data AUTOIGNITION TEMPERATURE No data FIRE HAZARD CLASSIFICATION (OSHA/NFPA) Class 11113 EXTINGUISHING MEDIA Ignition will give rise to a Class B fire. In case of large fore use: Water Spray, Alcohol Foam. In case of small fire use Carbon Dioxide (002), Dry chemical, dry sand or limestone. SPECIAL FIRE FIGHTING PROCEDURES Firefighters should wear butyl rubber boots, gloves, and body suit and a self-contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARDS May generate toxic or irritating combustion products. May generate carbon monoxide gas. May generate toxic nitrogen oxide gases. May generate ammonia gas. SECTION 6 - ACCIDENTAL RELEASE MEASURES CANTAM I N ENT TECHNIQUES (Removal of ignition sources, diking etc.) Stop the leak, if possible. Reduce vapor spreading with a water spray. Shut off or remove all ignition sources. Construct a dike to prevent spreading. CLEAN-UP PROCEDURES If recovery is not feasible, admix with dry soil, sand or non -reactive absorbent (sodium bisulfate) and place in a container or dumpster pending disposal. Flush area with water spray. Clean-up personnel must be equipped with self-contained breathing apparatus and butyl rubber protective clothing. For large spills, recover spilled material with a vacuum truck. OTHER EMERGENCY ADVICE Wear protective clothing, boots, gloves, and eye protections SECTION 7 - HANDLING AND STORAGE STORAGE Keep away from: acids, alkalis, and oxidizers. Keep in cool, dry, ventilated storage and inclosed 2 1 P a g e Raka UV Inhibited Part B Slow/Fast containers. Store in steel containers located outdoors, above ground, and surrounded by dikes to contain spills or leaks. Do not store in iron or other reactive metal containers. HANDLING Avoid with skin or eyes. When handling, do not drink, or smoke. SECTION 8 - PERSONAL PROTECTION/EXPOSURE CONTROLS EYE PROTECTION Splash proof goggles. In emergency, use goggles with a full -face shield. or cuffed butyl gloves. RESPIRATORY PROTECTION Not required under normal clothing. WORK AND HYGENIC PRACTICES Provide accessible eye wash stations and safety showers. Wash at end of each workshift. Use appropriate skin lotion. Discard contaminated leather articles. SECTION 9 -TYPICAL PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL FORM Mobile liquid COLOR ODOR Ammoniacal ph VAPOR PRESSURE (MM Hg at 21C (70F)) 0.70 VAPOR DENSITY (Air-1) No Data BOILING POINT 222.00 C (431.60 F) MELTING POINT No Data SOLUBILITY IN WATER Slight (0.1-1 %) SPECIFIC GRAVITY (Water=1) 1.06 MOLECULAR WEIGHT Mixture HAND PROTECTION Neoprene rubber, impermeable, PROTECTIVE CLOHTING Long sleeved clothing. Alkaline Amber SECTION 10 -STABILITY AND REACTIVITY CHEMICAL STABILITY Stable INCOMPATABILITY (Materials to avoid) Mineral acids (i.e. sulfuric, phosphoric, etc.). Alkalis (i.e. sodium or potassium hydroxide etc.). Organic acids (i.e. acetic acid, citric acid, etc.). oxidizing agents (i.e. perchlorates, nitrates, etc.) Reactive metals (i.e. sodium, calcium, zinc, etc.). Sodium or Calcium Hypochlorite. CAUTION! N-Nitrosamines, many of which are known to be potent carcinogens, may be formed when the product comes in contact with nitrous acid, nitrites or atmospheres with high nitrous oxide concentrations. Product slowly corrodes copper, aluminum, zinc and galvanized surfaces. Amine reaction with peroxides may result in violent decomposition of peroxide possibly creating an explosion. Materials reactive with hydroxyl compounds. Nitrates, nitrosating agents. A reaction accompanies by large heat release occurs when the product is mixed with acids. Heat generated may be sufficient to cause vigorous boiling creating a hazard due to splashing or splattering of hot material. HAZARDOUS DECOMOSITION PRODUCTS (from burning, heating or reaction with other materials). Carbon monoxide in a fire. Carbon dioxide in a fire. Ammonia when heated. Nitrogen oxides in a fire. Irritating and toxic fumes at elevated temperatures. Nitric acid in a fire. Nitosamines and Aldehydes. Organic acid vapors. Nitrogen oxide can react with water vapors to form corrosive nitric acid. HAZARDOUS POLYMERIZATION Will not occur. SECTION 11-TOXICOLOGICAL PROPERTIES ACUTE ORATL TOXICITY (LD 50, RAT) > IOOO.00mg/kg (no deaths) (estimate) CHRONIC/SUBCHRONIC DATA Allergic sensitization in humans. ACUTE DERMAL TOXICITY (LD50, RABBIT) > 2000.00mg/kg (no deaths) (estimate) ACUTE INHALATION TOXICITY (LC50, RAT) No data IRRITATION EFFECTS DATA Moderate irritation to the skin of a rabbit. SECTION 12 - ECOLOGICAL INFORMATION Ecotoxicity no data Environmental Fate no data Additional Information waste may present long term enviro hazards. 3 1 P a g e Raka UV Inhibited Part B Slow/Fast SECTION 13-DISPOSAL CONDERATIONS WASTE DISPOSAL Comply with all Federal, State and Local Regulations. SECTION 14 -TRANSPORT INFORMATION DOT NON -BULK SHIPPING NAME RESIN COMPOUND -Not DOT Regulated. DOT BULK SHIPPING NAME RESIN COMPOUND -Not DOT Regulated. ICAO/IATA SHIPPING DATA RESIN COMPOUND -Not LATA Regulated. IMO SHIPPING DATA RESIN COMPOUND -Not IMO Regulated SECTION 15 LABEL ELEMENTS Labeling according to Regulations (EC) No 1272/2008 Hazard Pictograms: Signal Word: DANGER Hazard Statements: if Causes severe skin burns and eye damage Suspected of damaging fertility or the unborn child Very toxic to aquatic life Very toxic to aquatic life with long lasting effects Precautionary Statements: - Obtain specialinstructions before use Do not handle until all safety precautions have been read and understood - Do not breathe mist,,vapors , - Wash Skin thoroughly after handling - Do not eat, drink or smoke when using this product Avoid release to the environment Wear eye protection, face protection, protective clothing, protective gloves +P312 - if swallowed: Call a POISON CENTER or doctor/physician if you feel unwell +P330+P331- If swallowed: rinse mouth. Do NOT induce vomiting +P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with - If inhaled: Remove person to fresh air and keep comfortable for breathing W338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present do. Continue rinsing - If exposed or concerned:: Get medical advice/attention P310 - Immediately call a POISON CENTER or —Rinse mouth —Wash contaminated clothing before reuse - -Collect spillage P405— Store locked up — Dispose of contents/container imaccordance with local, regional, national, and/or international 4 1 P a g e Raka-127,900,Table Top, UV Inhibited, and Superfast Resin MATERIAL SAFETY DATA SHEET RAKA INC. Oleander Ave. Ft. Pierce, FL. 34982 Emergency Phone (772) 489-4070 PRODUCT NAME: RAKA EPDXY RESINS: 127, 900, 1500, UV Inhibited Part A, Tabletop Resin, Superfast Resin Effective Date: 6-1-2015 Product Code: Raka -127, Raka - 900, Raka -Table Top, and Raka Superfast Resin 1. INGREDIENTS: Reaction products of Epichlorohydrin and Bisphenol A CAS # 025-085-99-8 >80% Alkyl Glycidyl Ether CAS # 068609-97-2 <20% Benzyl Alcohol CAS # 100-51-6 <10% The balance of materials are trade secrets CAS # Proprietary <5% This document is prepared pursuant to the OSHA Hazard Communication Standard (29 CFR 1910.1200). In addition, other substances Not Hazardous per this OSHA Standard may be listed. Where proprietary ingredients are shown, the identity may be made available as provided in this standard. 2. PHYSICAL DATA: BOILING POINT: not applicable VAP PRESS: not applicable VAP DENSITY: not applicable SOL. In WATER: none SP. GRAVITY: 1.12-1.14 APPEARANCE: straw colored liquid 3. FIRE AND EXPLOSION HAZARD DATA: FLASHPOINT:245 F METHOD USED: PMCC FLAMMABLE LIMITS: LFL: not applicable UFL: not applicable EXTINGUISHING MEDIA: foam, CO2, dry chemical FIRE AND EXPLOSION HAZARDS: none FIRE FIGHTING EQUIPMENT: Wear positive.pressure self-contained breathing apparatus. 4. REACTIVITY DATA: STABILITY: (CONDITIONS TO AVOID) Excess heating over long periods of time degrades the resin. INCOMP AT ABILITY: (SPECIFIC MATERIALS TO AVOID) Base. HAZARDOUS DECOMPOSITION PRODUCTS: The by-products expected in incomplete prolysis or combustion of epoxy resins Are mainly phenolics, carbon monoxide, and water. The thermal decompression products of epoxy resins therefore should be treated as potentially hazardous substance. Appropriate precautions should be taken. 5. ENVIROMENTAL AND DISPOSAL INFORMATION: ACTION TO TAKE FOR SPILLS / LEAKS: Soak up in absorbent material and collect in suitable containers. Residual may be removed using steam or hot soapy water. DISPOSAL METHOD: Burn in adequate incinerator or bury in an approved landfill; in accordance with local, state, and federal regulations. 6. HEALTH HAZARD DATA: EYE: Minor transient irritation, No corneal injury is likely. SKIN CONTACT: May cause allergic skin reaction in susceptible individuals. Prolonged exposure not likely to cause significant skin irritation. Repeated exposure may cause skin irritation. SKIN ABSORPTION: A single prolonged exposure is not likely to result in the material being absorbed through skin in harmful amounts. The LD50 for skin absorption in rabbits is 20,000 mg/kg. INGESTION: Low acute oral toxicity; LD50 (rat) greater than 400 mg/kg. No hazards anticipated from ingestion incidental to industrial exposure. 11Page Raka-127,900,Table Top, UV Inhibited, and Superfast Resin INHALATION: Vapors are unlikely due to physical properties. Not a problem unless healed to high temperature. SYSTEMIC AND OTHER EFFECTS: Except for skin sensitization, repeated exposure to low molecular weight epoxy resins of this type are not anticipated to cause any significant adverse effects. A poorly characterized sample of molecular weight epoxy resin of this type has Been reported to produce skin cancer in a highly sensitive strain of mice. However, high levels of impurity compromise the validity of manufacturing processes is not believed to be a cancer hazard to humans. Results of mutagen city tests in animals have been negative. It has been shown to be negative in some in vitro mutagen city tests and positive in others. 7. FIRSTAID: EYES: Irrigation of the eye immediately with water for five minutes is good safety practice. SKIN: Contact will probably cause no more than irritation. Wash off in flowing water or shower. Wash clothing before reuse. INGESTION: Remove to fresh air if effects occur. Consult medical personnel. NOTE TO PHYSICIAN: No specific antidote. Supportive care. Treatment based on judgment of the physician in response to reactions of the patient. 8. HANDLING PRECAUTIONS: VENTILATION: Good room ventilation usually adequate for most operations. RESPIRATORY PROTECTION: None needed. SKIN PROTECTION: For brief contact, no precautions other than clean body -covering clothing should be needed. Use impervious gloves when prolonged or frequently repeated contact could occur. EYE PROTECTION: Use chemical goggles. 9. ADDITIONAL INFORMATION: SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Practice good caution and personnel cleanliness to avoid skin and eye contact. Avoid breathing vapors of heated material. 10. NFPA HAZARD RATING: STATUS ON SUBSTANCE LISTS: The concentrations shown in this document are maximum or ceiling levels (expressed in weight %, unless otherwise specific) to be used for regulations. Trade Secrets are indicated by "TS". FEDERALEPA COMPREHENSIVE ENVIRONMENTAL RESPONSE. COMPENSATION. AND LIABILITY ACT OF 1980 (CERCLAY): Requires notification of the National Response Center of release of quantities of Hazardous Substances equal to or greater than the reportable quantities (R(Xs) in 40 CFR 302.4. Components present in this product at level, which could require reporting under the statute are: Chemical Name CAS Number % By Weight NONE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SAR) TITLE III: Sections 301-304 require emergency planning based on Threshold Planning Quantities (TPQ's) and release reporting based on Reportable Quantities (RQS) in 40 CFR 355. Components.present in this product at level, which could require reporting under the statute are: Chemical Name CAS Number % By Weight NONE Sections 311-312 require products to be reviewed and applicable EPA Hazard Definitions be identified. EPA HAZARD CLASSIFICATIONS: Acute Chronic Fire Pressure Reactive Hazard Hazard Hazard Hazard Hazard No No No No No Section 313 requires submission of annual reports of releases of toxic chemicals that appear in 40 CFR 372 (for 2 1 P a g e Raka-127,900,Table Top, UV Inhibited, and Superfast Resin SARA 313). This information must be included in all MSD's that are copied and distributed for this material. Components present in this product at level, which could require reporting under the statute are: Chemical Name CAS Number % By Weight NONE If you are unsure if you must report more information, call the EPA Emergency Planning and Right -To -Know Hot line: 800-535-0202 or 202-479-2449. TOXIC SUBSTANCES CONTROL ACT ITSCA): The components of this product are contained on the chemical substance inventory list. OTHER REGULATORY INFORMATION: D.O.T. Shipping Name: Not Regulated The information herein is given in good faith, but no warranty expressed or implied is made. 11. LABEL ELEMENTS: Labeling according to Regulations (EC) No 1272/2008 Hazard Pictograms: GHS07 Signal Word: WARNING Hazard -determining components of labelling: Bisphenol A based Epoxy Resin Hazard Statements: H312: Harmful in contact with skin H317: May cause an allergic skin reaction H412: Harmful to aquatic life with long lasting effects Precautionary Statements: P264: Wash hands thoroughly after handling P270: Do not eat, drink, or smoke when using this product P271: Use only in well ventilated area P273: Avoid release to the environment P280: Wear Protective gloves/protective clothing/eye protection/face protection P337+13313: If eye irritation persist: Get medical advice/attention P370+P378: In case of fire: Use for extinction: CO2, powder, or water spray P302+13352: If on skin: Wash with plenty of soap and water P391 Collect spillage P304+P235: Store in well -ventilated place. Keep cool P501: Dispose of contents/container in accordance with local/regional/national/international regulations 3 1 P a g e RAKA 610, RAKA 608, RAKA 606, RAKA 260 Tropical MATERIAL SAFETY DATA SHEET RAKA INC. 3490 Oleander Ave. Ft. Pierce FI.34982 Emergency Phone: 772-489-4070 MSDS for Three Raka Epoxy Curing Agents B Side PRODUCT NAME: RAKA 610, 608 and 606 curing agents (hardeners). Effective Date: 6-1- 2015 Product Code: RAKA 610, RAKA 608, RAKA 606, RAKA 260 Tropical 1. INGREDIENTS: Polyamine Cas # 140-31-8 < 40% Alkylphenol Cas # 25154-52-3 < 40% Balance of ingredients are trade secrets: Epoxy Additives and Modified Cycloaliphatic Amine Reaction Products: CAS#: Proprietary This document is prepared pursuant to the OSHA Hazard Communication Standard (29 CFR 1910.1200) in addition, other substances not hazardous per this OSHA Standard may be listed. Where proprietary Ingredient shows, the identity may be made available as provided in this standard. 2. PHYSICAL DATA: BOILING POINT: > 400°F VAP PRESSURE: <1 mmHg@ 20°C, 68°F VAP DENSITY: >1 SOL. IN WATER: Moderately soluble SP. GRAVITY: 0.96 APPEARANCE: Pale straw-colored liquid ODOR: Amine odor. 3. FIRE AND EXPLOSION HAZARD DATA: FLASHPOINT: 200°F, 93°C METHOD USED: PMCC FLAMMABLE LIMITS LFL: Not determined UFL: Not determined EXTINGUISHING MEDIA: Water fog, alcohol foam, CO2, dry chemical. FIRE & EXPLOSION HAZARDS: Use full protective clothing (see Section 8) FIRE -FIGHTING EQUIPMENT: Use a positive pressure, self-contained breathing apparatus. 4. REACTIVITY DATA: STABILITY: (CONDITIONS TO AVOID) Can react strongly with epoxy resins at elevated temperatures. INCOMPATABILITY: (SPECIFIC MATERIALS TO AVOID) Epoxy resins under uncontrolled conditions. HASARDOUS DECOMPOSITION PRODUCTS: Nitrogen oxides when burned. HAZARDOUS POLYMERIZATION: Will not occur. S. ENVIROMENTAL AND DISPOSAL INFORMATION: ACTION TO TAKE FOR SPILLS/LEAKS: Large spill —dike up and pump into appropriate containers. Small spill —use noncombustible absorbent material/sand and shovel into suitable containers. DISPOSAL METHOD: Large quantities should be recovered. Collect small quantities in waste metal drums for removal to an approved landfill, or incinerate in accordance with local, state, and federal regulations. 6. HEALTH HAZARD DATA: EYE: May cause severe corneal injury, which may result in permanent impairment of vision, even 1(Page RAKA 610, RAKA 608, RAKA 606, RAKA 260 Tropical blindness. Vapors may irritate eyes. SKIN CONTACT: May cause severe injury to skin following prolonged or repeated contact, and may cause skin sensitization or other allergic reactions. SKIN ABSORPTION: A single prolonged exposure may result in the material being absorbed in harmful amounts. The LD50 for skin absorption in rabbits is 880 mg/kg. INGESTON: Single dose oral toxicity is low. The oral LD50 for female rats is>1000mg/kg. Ingestion may cause gastrointestinal irritation or ulceration. Ingestion may cause burns of mouth and throat. INHALATION: May cause respiratory sensitization or asthma in susceptible individuals. Excessive exposure may cause irritation to respiratory tract. SYSTEMIC AND OTHER EFFECTS: Results of in vitro ("test tube") mutagen city test have been negative. 7. FIRST AID: EYES: Irrigation of the eye immediately with water for at least 30 minutes is required. Promptly seek medical attention. SKIN: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing, preferably under a safety shower. Seek medical attention immediately. Avoid prolonged or repeated contact to skin. Wash thoroughly after handling. INGESTION: Do not induce vomiting. Give large amounts of water or milk if available and transport to medical facility. INHALATION: Remove to fresh air if effects occur. Consult medical personnel. NOTE TO PHYSICIAN: Corrosive. May cause stricture. If lavage is performed, suggest endotracheal and /or esophagoscopic control. If burn is present, treat as any thermal burn, after decontamination. No specific antidote. Supportive care. Treatment based on judgment of the physician in response to reactions of the patient. 8. HANDLING PRECAUTIONS: EXPOSURE GUIDELINE: None established. VENTILATION: Control airborne concentration below the exposure guideline. Use only with adequate ventilation. Local exhaust ventilation may be necessary for some operations. RESPIRATORY PROTECTION: Atmospheric levels should be maintained below the exposure guideline. When respiratory protection is required for certain operations, use an approved air -purifying respirator. SKIN PROTECTION: Use protective clothing impervious to this material. Selection of specific items such as gloves, boots, apron, or full -body sit will depend on operation. Safety shower should be located in immediate work area. Remove contaminated clothing immediately, wash skin area with soap and water, and clothing before reuse. Contaminate leather items, such as shoes, belts and watchbands, should be removed and destroyed. EYE PROTECTION: Use chemical goggles. If vapor causes eye irritation, use full -face respirator. Eye wash fountain should be located in immediate work area. 9. ADDITIONAL INFORMATION: SPECIAL PRECAUTIONS TO BETAKEN IN HANDLING AND STORAGE: Ground all transfer equipment. Hold bulk storage under a nitrogen blanket. This product should not come in contact with copper of copper -bearing alloys. Good general housekeeping procedure should be followed. 10. NFPA HAZARD RATING: (4 = EXTREME 3 = HIGH 2 = MODERATE 1= SLIGHT 0 = INSIGNIFICANT) HEALTH - 2 FIRE -1 REACTIVITY - 0 SPECIFIC - 0 2 1 P a g e RAKA 610, RAKA 608, RAKA 606, RAKA 260 Tropical 11. REGULATORY INFORMATION: STATUS ON SUBSTANCE LISTS: The concentrations shown in this document are maximum or ceiling levels (expressed in weight unless otherwise specified) to be used for regulations. Trade Secrets are indicated by "TS". FEDERALEPA COMPRHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT OF 1980 CERCLA : Requires notification of the National Response Center of release of quantities of Hazardous Substances equal to or greater than the reportable quantities (RQ's) in 40 CFR 302.4. Components present in this product at level, which could require reporting under the statute are: Chemical Name CAS Number % By Weight RO NONE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SAR) TITLE III: Sections 301-304 require emergency planning based on Threshold Planning Quantities (TPQ's) and release reporting based on Reportable Quantities (RQS) in 40CFR 355. Components present in this product at level, which could require reporting under the statute are: Chemical Name CAS Number %By Weight NONE Sections 311-312 require products to be reviewed and applicable EPA Hazard Definitions are identified. EPA HAZARD CLASSIFICATIONS: Acute Chronic Fire Pressure Reactive Hazard Hazard Hazard Hazard Hazard Yes Yes No No No Section 313 requires submission of annual reports of releases of toxic chemicals that appear in 40 CFR 372 (for SARA 313). This information must be included in all MSD's that are copied and distributed for this material. Components present in this product at level, which could require reporting under the statute are: Chemical Name CAS Number %By Weight NONE If you are unsure if you must report more information, call the EPA Emergency Planning and Right -To - Know Hot line:800-535-0202 or202-4792449. TOXIC SUBSTANCES CONTROL ACT (TSCA): The components of this product are contained on the chemical substance inventory list. OTHER REGULATORY INFORMATION: D.O.T. Shipping Name: Not Regulated The information herein is given in good faith, but no warranty expressed or implied is made. SECTION 14 - TRANSPORT INFORMATION DOT NON -BULK SHIPPING NAME RESIN COMPOUND -Not DOT Regulated. DOT BULK SHIPPING NAME RESIN COMPOUND -Not DOT Regulated. ICAO/IATA SHIPPING DATA RESIN COMPOUND -Not LATA Regulated. IMO SHIPPING DATA RESIN COMPOUND -Not IMO Regulated SECTION 15 LABEL ELEMENTS Labeling according to Regulations (EC) No 1272/2008 Hazard Pictograms: 3 1 P a g e RAKA 610, RAKA 608, RAKA 606, RAKA 260 Tropical Signal Word: DANGER Hazard Statements: H302 - Harmful ifs`wallowed 1314 - Causes'severe skin burns and eye damage 1361- Suspected,of damaging fertility_ or the unborn child H400 - Very toxic to aquatic life f 416 - Very toxic to aquatic life with, long lasting effects, Precautionary Statements: - Obtain special instructions before use - Do not handle until all safety precautions have been read and understood - Do not breathe, mist, vapors - Wash Skin thoroughly after handling - Do not eat, drink or smoke when, using this product - Avoid release to the environment - Wear eye protection,face protection, protective clothing, protective gloves i-P312 - if swallowed: Calla POISON CENTER,or if you feel unwell' I-P330+P331- If swallowed: rinse mouth. Do NOT induce vomiting, W361+P353 - If on skin (ortiair): Take off immediately all contaminated clothing. Rinse skin with 140-- If inhaled: Remove person to fresh air and keep comfortable for breathing 151+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contactlenses, if and easy to do. Continue rinsing 113 - If exposed or concerned: Get medical advice/attention P310'- Immediately call a POISON ordoctor/physician. — Rinse mouth —Wash contaminated clothing before reuse — Collect spillage 'P405-Store locked up —Dispose,of contents/container in accordance with local, regional, national, and/or international 4 1 P a g e Raka Table Top Hardener MATERIAL SAFETY DATA SHEET RAKA INC. 3490 Oleander Ave. Ft. Pierce Fl. 34982 Emergency Phone: 772-489-4070 PRODUCT NAME: RAKA Table Too Hardener Effective Date: 6-1-2015 Product Code: Raka Table Top Hardener 1. INGREDIENTS: Polvamine Cas SS 140-31-8 <40% Alkvlphenol Cas SS 25154-52-3 <40% Balance of ingredients are trade secrets: Epoxy Additives and Modified Cycloaliphatic Amine Reaction Products: CASTS: Proprietary This document is prepared pursuant to the OSHA Hazard Communication Standard (29 CFR 1910.1200) in addition, other substances not hazardous per this OSHA Standard may be listed-. Where proprietary Ingredient shows, the identity may be made available as provided in this standard. 2. PHYSICAL DATA: BOILING POINT: > 400°F VAP PRESSURE: <1 mmHg(a) 20°C, 68°F VAP DENSITY: >3 SOL. IN WATER: Moderately soluble SP. GRAVITY: 0.96 APPEARANCE: Pale straw colored liquid ODOR: Amine odor. 3. FIRE AND EXPLOSION HAZARD DATA: FLASHPOINT: 200°F, 93°C METHOD USED: PMCC FLAMMABLE LIMITS LFL: Not determined UFL: Not determined EXTINGUISHING MEDIA: Water fog. alcohol foam. CO2, dry chemical. FIRE & EXPLOSION HAZARDS: Use full protective clothing (see Section 8) FIRE -FIGHTING EQUIPMENT: Use a positive pressure, self- contained breathing apparatus. 4. REACTIVITY DATA: STABILITY: (CONDITIONS TO AVOID) Can react strongly with epoxy resins at elevated temperatures. INCOMPATABILITY: (SPECIFIC MATERIALS TO AVOID) Epoxy resins under uncontrolled conditions. HASARDOUS DECOMPOSITION PRODUCTS: Nitrogen oxides when burned. HAZARDOUS POLYMERIZATION: Will not occur. 5. ENVIROMENTAL AND DISPOSAL INFORMATION: ACTION TO TAKE FOR SPILLS/LEAKS: Large spill —dike up and pump into appropriate containers. Small spill —use non combustible absorbent material/sand and shovel into suitable containers. DISPOSAL METHOD: Large quantities should be recovered. Collect small quantities in waste metal drums for removal to an approved landfill, or incinerate in accordance with local, state, and federal regulations. 6. HEALTH HAZARD DATA: EYE: May cause severe corneal injury, which may result in permanent impairment of vision, even blindness. Vapors may irritate eyes. SKIN CONTACT: Mav cause severe injury to skin following prolonged or repeated contact, and may cause skin sensitization or other allergic reactions. SKIN ABSORPTION: A single prolonged exposure may result in the material being absorbed in harmful amounts. The LD50 for skin absorption in rabbits is 880 mg/kg. INGESTON: Single dose oral toxicity is low. The oral LD50 for female rats is>1000mg/kg. Ingestion may cause gastrointestinal irritation or ulceration. Ingestion may cause burns of mouth and throat. INHALATION: Mav cause respiratory sensitization or asthma in susceptible individuals. Excessive exposure may cause irritation to respiratory tract. SYSTEMIC AND OTHER EFFECTS: Results of in vitro ("test tube") mutagen city test have been negative. 7. FIRSTAID: EYES: Irrigation of the eve immediately with water for at least 30 minutes is required. Promptly seek medical attention. SKIN: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated I I P a g e Raka Table Top Hardener clothing, preferably under a safety shower. Seek medical attention immediately. Avoid prolonged or repeated contact to skin. Wash thoroughly after handling. INGESTION: Do not induce vomiting. Give large amounts of water or milk if available and transport to medical facility. INHALATION: Remove to fresh air if effects occur. Consult medical personnel. NOTE TO PHYSICIAN: Corrosive. Mav cause stricture. If lavage is performed, suggest endotracheal and /or esophagoscopic control. If burn is present, treat as any thermal burn, after decontamination. No specific antidote. Supportive care. Treatment based on judgment of the physician in response to reactions of the patient. 8. HANDLING PRECAUTIONS: EXPOSURE GUIDELINE: None established. VENTILATION: Control airborne concentration below the exposure guideline. Use only with adequate ventilation. Local exhaust ventilation may be necessary for some operations. RESPIRATORY PROTECTION: Atmospheric levels should be maintained below the exposure guideline. When respiratory protection is required for certain operations, use an approved air -purifying respirator. SKIN PROTECTION: Use protective clothing impervious to this material. Selection of specific items such as gloves, boots, apron, or full -body sit will depend on operation. Safety shower should be located in immediate work area. Remove contaminated clothing immediately, wash skin area with soap and water, and clothing before reuse. Contaminate leather items, such as shoes, belts and watchbands, should be removed and destroyed. EYE PROTECTION: Use chemical goggles. If vapor causes eve irritation, use full -face respirator. Eve wash fountain should be located in immediate work area. 9. ADDITIONAL INFORMATION: SPECIAL PRECAUTIONS TO BETAKEN IN HANDLING AND STORAGE: Ground all transfer equipment. Hold bulk storage under a nitrogen blanket. This product should not come in contact with cooper of copper -bearing alloys. Good general housekeeping procedure should be followed. 10. NFPA HAZARD RATING: (4 = EXTREME 3 = HIGH 2 = MODERATE 1= SLIGHT 0 = INSIGNIFICANT) HEALTH - 2 FIRE -1 REACTIVITY - 0 SPECIFIC -0 11. REGULATORY INFORMATION: STATUS ON SUBSTANCE LISTS: The concentrations shown in this document are maximum or ceiling levels (expressed in weight %, unless otherwise specified) to be used for regulations. Trade Secrets are indicated by "TS". FEDERALEPA COMPRHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT OF 1980 (CERCLA): Requires notification of the National Response Center of release of quantities of Hazardous Substances equal to or greater than the reportable quantities (RQ's) in 40 CFR 302.4. Components present in this product at level, which could require reporting under the statute are: Chemical Name CAS Number % By Weight RO NONE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SAR) TITLE III: Sections 301-304 require emergency planning based on Threshold Planning Quantities (TPQ's) and release reporting based on Reportable Quantities (RQS) in 40CFR 355. Components present in this product at level, which could require reporting under the statute are: Chemical Name CAS Number % By Weight NONE Sections 311-312 require products to be reviewed and applicable EPA Hazard Definitions are identified. EPA HAZARD CLASSIFICATIONS: Acute Chronic Fire Pressure Reactive Hazard Hazard Hazard Hazard Hazard Yes Yes No No No Section 313 requires submission of annual reports of releases of toxic chemicals that appear in 40 CFR 372 (for SARA 313). This information must be included in all MSD's that are copied and distributed for this material. Components present in this product at levelwhich could require reporting under the statute are: Chemical Name CAS Number %By Weight NONE If you are unsure if you must report more information, call the EPA Emergency Planning and Right -To -Know Hot line:800-535-0202 or202-4792449. 2 1 P a g e Raka Table Top Hardener TOXIC SUBSTANCES CONTROL ACT (TSCAI: The components of this product are contained on the chemical substance inventory list. OTHER REGULATORY INFORMATION: D.O.T. Shipping Name: Not Regulated The information herein is given in good faith, but no warranty expressed or implied is made. SECTION 15 LABEL ELEMENTS Labeling according to Regulations (EC) No 1272/2008 Hazard Pictograms: Signal Word: DANGER Hazard Statements: H302 - Harmful if swallows H314 - Causes severe skin I H361-Suspected ofdama H400.-_Very toxic toa uati H410- VerV_toxic toa uati Precautionary Statements: 3 1 P a g e SYSTEENNEE8 1. Product Identification SAFETY DATA SHEET Product name EZ-Fillet Hardener, Part B SIDS Number 1430B00 Product type Epoxy curing agent. Recommended use of the chemical and Directed at, but not limited to, the filling and reinforcing of wood structures. restrictions on use Restrictions Manufacturer/Supplier information Company name Address Telephone Website Email Emergency Contact 2. Haza Identification Classification of substance or mixture/Signal Word GHS Label Elements Hazard Pictograms Hazard Statements/Classification of substance or mixture Precautionary statements None known. SYSTEM THREE RESINS, INC. 3500 W. Valley Hwy, Suite Suite 105 Auburn, WA 98001-2436 United States 1-253-333-8118 www.systemthree.com support-08@systemthree.com CHEMTREC (U.S. and CANADA) 1-800-424-9300 CHEMTREC (Outside the U.S.) 1-703-527-0585 DANGER ACUTE TOXCITY: ORAL — Category 4 SKIN CORROSION/IRRITATION —Category 1 SERIOUS EYE DAMAGE/EYE IRRITATION —Category 1 SKIN SENSITIZATION —Category 1 TOXIC TO REPRODUCTION [Fertility] — Category 1 TOXIC TO REPRODUCTION [Unborn child] — Category 1 H302 Harmful if swallowed. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H360 May damage fertility or the unborn child. Precautionary Statements P201 Obtain special instructions before use. Prevention P202 Do not handle until all safety precautions have been read and understood. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 P271 P272 work P280 Response P313 P301 Wash hands thoroughly after handling. Use only outdoors or in a well -ventilated area. Contaminated work clothing should not be allowed out of the dace. Wear protective gloves. Wear eye or face protection. Call a POISON CENTER or doctor/physician if you feel unwell. F330+331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting P303+361+353 IF ON SKIN (or hair): Takeoff immediately all contaminated clothing. Rinse skin with water/shower. P304+340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. Storage P401 Store at room temperature in a well -ventilated area. Disposal P501 Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified (HNOC) None Available. 3. Composition/Information On Ingredients Chemical Name CAS Number Content (%) Modified Polyamines Trade Secret 80 — 90% Benzyl Alcohol 100-51-6 15 — 25% There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. 4. First -Aid Measures Skin contact Remove contaminated clothing and shoes and wipe excess off skin. Wash the affected area with plenty of soap and water until no evidence of the chemical remains (at least 15-20 minutes). Launder clothes before reuse. If skin irritation occurs: Get medical advice/attention. Eye contact Rinse immediately with plenty of water for at least 15 minutes. Flush longer if there is an indication of residual chemical in the eye. Ensure adequate flushing of the eyes by separating the eyelids with fingers and roll eyes in a circular motion. Check for and remove any contact lenses. Continue rinsing for 10 minutes. If eye irritation persists: Get medical advice/attention. Ingestion Do not induce vomiting. Never give anything by mouth to an unconscious person. Rinse out the mouth with water. Get medical attention immediately. Inhalation If affected, remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Call a POISON CENTER or doctor/physician if you feel unwell. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored for at least48 hours. Specific treatments No specific treatment. 5. Fire -Fighting Measures Suitable extinguishing media Alcohol -resistant foam. Carbon dioxide (CO2). Dry chemical Water Fog Unsuitable extinguishing media None known. Specific hazards arising from the chemical In a fire or if heated, a pressure increase will occur and the container may burst. Incomplete combustion may form carbon monoxide. May generate ammonia gas. May generate toxic nitrogen oxide gases. Burning produces noxious and toxic fumes. Downwind personnel must be evacuated. Hazardous decomposition products Decomposition products may include the following materials: Carbon dioxide Carbon monoxide Nitrogen oxides Special protective actions for fire-fighters Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective equipment for fire- Fire-fighters should wear appropriate protective equipment and self-contained fighters breathing apparatus (SCBA) with a full face -piece operated in positive pressure mode. Further information Do not allow run-off from firefighting to enter drains or water courses. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. 6. Accidental Release Measures Personal precautions No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Wear proper protective clothing, gloves and eye/face protection. Emergency procedures If material is spilled, avoid contact with material. Persons not wearing appropriate protective equipment should leave the area of the spill until cleanup is complete. Methods and materials for Stop leak if without risk. Move containers from spill area. Approach release containment/cleanup from upwind. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). 7. Handling and Storage Precautions for safe handling Put on appropriate personal protective equipment. Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid contact with skin and eyes. Do not ingest. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. When using, do not eat, drink or smoke. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Precautions/Recommendations for Store in accordance with local regulations. Store in original container protected safe/proper storage from direct sunlight in a dry, cool and well -ventilated area, away from incompatible materials and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. 8. Exposure Controls/Personal Protection Occupational Exposure Limits None established. Appropriate engineering controls Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Environmental exposure controls Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Do not allow spill to enter sewers or waterways. Individual protection measures/Personal protective equipment Eye/face protection Splash -proof goggles or safety spectacles with side shields are recommended. Always wear eye protection when sanding cured epoxy resins to avoid dust in eyes. Hand protection Always wear impervious gloves: butyl rubber, nitrile rubber, Neoprene, PVC disposable gloves, Skin protection Wear clean, body -covering clothing to avoid skin contact. Respiratory protection Use a properly fitted, air -purifying or air -fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Special instructions for protection and Wear gloves at all times when handling product, avoid direct contact with skin. hygiene When finished using product, dispose of gloves properly and wash hands with warm, soapy water. 9. Physical and Chemical Properties Chemical family Appearance Physical State Form Color Odor Density (Specific Gravity) Viscosity Amine curing agent Green paste Paste Green Amine -like odor 1.06 100,000 CPS @77°F (25"C) pH Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability limit (by volume) Upper flammability limit (by volume) Lower flammability limit (by volume) Material VOC Vapor density Relative density Solubility in water Partition coefficient: n-octanol/water Auto -ignition temperature Decomposition temperature 10.Stability and Reactivity Reactivity Chemical Stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products Other hazards 11. Toxicological Information N/A N/A N/A >250°F(Pensky-Martins Closed Cup) Slower than Ether N/A N/A N/A N/A None Heavier than Air N/A Negligible N/A N/A N/A Stable. Stable under normal conditions. Under normal conditions of storage and use, hazardous reactions will not occur. Epoxy resins and epoxy resin hardeners react with each other producing heat. They should not be mixed with each other under uncontrolled conditions or in large mass the ensuing exotherm may result in heat and smoke. Strong oxidizing agents, mineral acids. Oxides of carbon, nitrogen. None known. Acute Health Hazard (components) No comprehensive data (ingestion, inhalation, dermal) on mixture (product). Component Result Species Dose Exposure Benzyl Alcohol Inhalation LC50 Rat >4178 mg/m3 4 h, aerosol Oral LD50 Rat 1620 mg/kg Irritation/Corrosion (components) Classifies as skin corrosion Category 1 based on GHS cut-off values/concentration limits in the product. Causes serious eye damage (Category 1). Component Result Species Test Exposure Benzyl Alcohol Non-irritant Rabbit OECD 404—Skin - Irritant Rabbit OECD 405—Eye - Modified Polyamines Corrosive Calculated sensitization Weight of evidence classifies product to be skin sensitizing. Component Route of Exposure Species Results Modified Polyamines Skin Guinea pig Sensitizing Mutagenicity No information on the product itself. Carcinogenicity No information on the product itself. Reproductive Toxicity No information on the product itself. Teratogenicity No information on the product itself. Specific target organ toxicity (single No information on the product itself. exposure) Specific target organ toxicity (repeated No information on the product itself. exposure) Aspiration hazard No information on the product itself. Potential acute health effects Eye Contact Causes serious eye damage. Inhalation May give off gas, vapor or dust that is very irritating or corrosive to the respiratory system. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Skin Contact Causes severe burns. Toxic in contact with skin. May cause an allergic skin reaction. Ingestion Harmful if swallowed. May cause burns to mouth, throat, and stomach. Svmotoms related to the ohvsical. chemical and toxicological characteristics Eye Contact Adverse symptoms may include the following: Pain Watering Redness Inhalation Adverse symptoms may include the following: Reduced fetal weight Increase in fetal deaths Skin Contact Adverse symptoms may include the following: Pain or irritation Redness Blistering may occur Reduced fetal weight Increase in fetal deaths Ingestion Adverse symptoms may include the following: Stomach pains Reduced fetal weight Increase in fetal deaths Delayed and immediate effects and also No information on the product itself. chronic effects from short and long term exposure Potential chronic health effects General Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels Carcinogenicity Mutagenicity Teratogenicity Developmental effects Fertility effects Numerical measures of toxicity Acute toxicity estimates (ATEmix) No known significant effects or critical hazards. No known significant effects or critical hazards. Suspected of damaging the unborn child. No known significant effects or critical hazards. Suspected of damaging fertility. Route ATE value Oral 1915.6 mg/kg Dermal 3251 mg/kg Inhalation (vapors) 50.99 mg/I 12. Ecological Information Ecotoxicity No comprehensive data on the product itself. Component Test Endpoint Exposure Species Result Benzyl Alcohol - Acute EC50 48 hrs Invertebrates 230 mg/I - Acute LC50 96 hrs Fish 460 mg/I Acute EC50 72 hrs Algae 770 mg/I Persistence and degradability No information on the product itself. Component Test Period Result Benzyl Alcohol Readily Biodegradable Bioaccumulative Potential No information on the product itself. Component LogPow BCF Potential Benzyl Alcohol 1.05 1.37 (calculated) Low Mobility in Soil Soil/water partition coefficient (KOC) Other adverse effects 13. Disposal Considerations Waste from residues/ unused products Contaminated packaging 14.Transoort Information No information on the product itself. No information on the product itself. None known. Product should not be allowed to enter drains, water courses or the soil; dispose of this material and its containers in a safe way. Contact supplier if guidance is required. Dispose of container and unused contents in accordance with federal, state and local requirements. The data provided in this section is for information only and may not be specific to your package size or mode of transport. You will need to apply the appropriate regulations to properly classify your shipment for transportation. International Transport Regulations Regulatory UN/NA number Proper Shipping Name Classes/•PG Additional information Information DOT UN3259 Polyamine, solid, corrosive, n.o.s. (n- Class 8 III Aminoethylpiperazine) TOG UN3259 Polyamine, solid, corrosive, n.o.s. (n- Class 8 III Aminoethylpiperazine) IMO/IMDG UN3259 Polyamine, solid, corrosive, n.o.s. (n- Class 8 III Aminoethylpiperazine) IATA (Cargo) UN3259 Polyamine, solid, corrosive, n.o.s. (n- Class 8111 Aminoethylpiperazine) "PG: Packing group Special precautions for user: Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. 15. Regulatory Information UNITED STATES U.S. Federal Regulations United States —TSCA 12(b) — Chemical export notification: None Required. United States —TSCA 5(a)2 — Final significant new use rules: Not Listed. United States —TSCA 5(a)2 — Proposed significant new use rules: Not Listed. United States —TSCA 5(e) —Substance consent order: Not listed. Clean Air Act— Ozone Depleting This product does not contain nor is it manufactured with ozone depleting Substances (ODS) substances. Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs) Pennsylvania — RTK California Prop. 65 EPA SARA 302 Extremely Hazardous Substances EPA SARA 302/304/311/312 Hazardous Chemicals SARA 313 Form R — Reporting requirements CERCLA Hazardous substances United States inventory (TSCA 8b) CANADA WHMIS (Canada) Canadian NPRI CEPA Toxic substances INTERNATIONAL REGULATIONS Product Name Concentration % Diethanolamine V-Aminoethylpiperazine, Diethanolamine This product does not contain any chemicals known to State of California to cause cancer, birth defects or any other harm. None. Acute Health Hazard, Chronic Health Hazard Product Name Concentration % Diethanolamine 1% Component % Section 304 CERCLA Product CERCLA Reportable Reportable Hazardous Quantity Quantity Substance (Lbs) (Lbs) Diethanolamine 1% 100 All components are listed or exempted. Class D-213: Material causing other toxic effects (Toxic). Class E: Corrosive material. None required. None required. International Lists Australia inventory (AILS): All components are listed or exempted. Canada inventory: All components are listed or exempted. Korea inventory: All components are listed or exempted. Japan inventory: All components are listed or exempted. China inventory (IECSC): All components are listed or exempted. New Zealand inventory (NZIoC): All components are listed or exempted. Philippines inventory (PICCS): All components are listed or exempted. Taiwan inventory (CSNN): All components are listed or exempted. 16. Other Information, Including Date of Preparation or Last Revision HMIS Rating Date of Preparation February 9, 2017 Date of Last Revision Revision # 1.0 More Information 1-253-333-8118 Prepared by N. Kim, System Three Resins Inc. The information contained herein is based on the data available to us and is believed to be correct. However, System Three Resins, Inc. makes no warranty, expressed or implied, regarding the accuracy of these data or the results to be obtained from the use thereof. System Three assumes no responsibility for injury from the use of the product described herein. SYSTEMBREE6 1. Product Identification SAFETY DATA SHEET Product name EZ-Fillet Resin, Part A SIDS Number 1430A00 Product type Epoxy polymer mixture. Recommended use of the chemical and Directed at, but not limited to, the filling and reinforcing of wood structures. restrictions on use Restrictions Manufacturer/Supplier information Company name Address Telephone Website Email Emergency Contact 2. Hazard(s) Identification None known. SYSTEM THREE RESINS, INC. 3500 W. Valley Hwy, Suite Suite 105 Auburn, WA 98001-2436 United States 1-253-333-8118 www.systemthree.com support-08@systemthree.com CHEMTREC (U.S. and CANADA) 1-800-424-9300 CHEMTREC (Outside the U.S.) 1-703-527-0585 Classification of substance or WARNING. mixture/Signal Word Skin Corrosion/Irritation - Category 2 Serious Eye Damage/Eye Irritation - Category 2 Skin Sensitizer — Category 1 Specific Target Organ Toxicity (Single Exposure) [Respiratory tract irritation] — Category 3 GHS Label Elements Hazard Pictograms ' • Hazard Statements/Classification of H315 Causes skin irritation. substance or mixture H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H335 May cause respiratory irritation. Precautionary statements Precautionary Statements P261 Avoid breathing vapors. Prevention P264 Wash hands thoroughly after handling. P271 Use only outdoors or in a well -ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves. Wear eye or face protection. Response P302 + P352 IF ON SKIN: Wash with soap and water. P304+ P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+ P313 If exposed or concerned: Get medical attention. P312 Call a POISON CENTER/doctor if you feel unwell. P332 + P313 If skin irritation occurs: Get medical advice/attention. P337 + P313 If eye irritation persists: Get medical advice/attention. P362 + P364 Take off contaminated clothing and wash it before reuse. Storage P403 + P233 Store in a well -ventilated place. Keep container tightly closed. P405 Store locked up. Disposal P501 Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified (HNOC) None Available 3. Composition/Information On Ingredients Chemical Name CAS Number Content (%) Diglycidyl Ether of Bisphenol A 25068-38-6 50— 60 % Alkyl Glycidyl Ether 17557-23-2 10-15% Benzyl Alcohol 100-51-6 1-10% Diglycidyl Ether of Bisphenol F 28064-14-4 1-10% There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. 4. First -Aid Measures Skin contact Remove material from skin immediately by washing with soap and plenty of water. Remove contaminated clothing and shoes while washing. Seek medical attention if irritation persists. Wash clothing before reuse. Discard items which cannot be decontaminated, including leather articles such as shoes, belts and watch bands. Eye contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 15 minutes. Suitable emergency eye wash facility should be available in work area. Get medical attention immediately if irritation persists. Ingestion Get medical attention immediately. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt orwaistband. Inhalation Get medical attention immediately. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments No specific treatment. 5. Fire -Fighting Measures Suitable extinguishing media Alcohol -resistant foam, dry chemical, water fog or carbon dioxide (CO2). Unsuitable extinguishing media None known. Specific hazards arising from the chemical In a fire or if heated, a pressure increase will occur and the container may burst. This material is toxic to aquatic life with long lasting effects. Fire water contaminated must be contained and prevented from being discharged to any waterway, sewer or drain. Hazardous decomposition products Decomposition products may include the following materials: Carbon dioxide Carbon monoxide Special protective actions for fire-fighters Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective equipment for fire- Fire-fighters should wear appropriate protective equipment and self-contained fighters breathing apparatus (SCBA) with a full face -piece operated in positive pressure mode. Further information Do not allow run-off from firefighting to enter drains or water courses. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. 6. Accidental Release Measures Personal precautions No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Wear proper protective clothing, gloves and eye/face protection. Emergency procedures If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. Methods and materials for Stop leak if without risk. Move containers from spill area. Approach release containment/cleanup from upwind. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to localregulations. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). 7. Handling and Storage Precautions for safe handling Put on appropriate personal protective equipment. Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid contact with skin and eyes. Do not ingest. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. When using, do not eat, drink or smoke. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Precautions/Recommendations for Store in accordance with local regulations. Store in original container protected safe/proper storage from direct sunlight in a dry, cool and well -ventilated area, away from incompatible materials and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. 8. Exposure Controls/Personal Protection Occupational Exposure Limits None established. Appropriate engineering controls Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Environmental exposure controls Use appropriate containment to avoid environmental contamination. Do not allow spill to enter sewers or waterways. Individual protection measures/Personal protective equipment Eye/face protection Splash -proof goggles or safety spectacles with side shields are recommended. Always wear eye protection when sanding cured epoxy resins to avoid dust in eyes. Hand protection Always wear impervious gloves: butyl rubber, nitrile rubber, Neoprene, PVC disposable gloves, Skin protection Wear clean, body -covering clothing to avoid skin contact. Respiratory protection Use a properly fitted, air -purifying or air -fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Special instructions for protection and Discard contaminated leather articles. Remove contaminated clothing. Wash at hygiene the end of each work shift and before eating smoking or using the toilet. Provide readily accessible eye wash stations and safety showers. 9. Physical and Chemical Properties Chemical family Appearance Physical State Form Color Odor Density (Specific Gravity) Viscosity PH Melting point/freezing point Initial boiling point and boiling range Flash point Epoxy Resin Reddish -Brown Paste Epoxy polymer mixture Paste Reddish -Brown Little to no odor 1.13 150,000 — 250,000 CPS @77-F N/A N/A N/A >300°F (Pensky-Martens Closed Cup) Evaporation rate Slower than ether Flammability (solid, gas) N/A Upper/lower flammability limit (by volume) N/A Upper flammability limit (by volume) N/A Lower flammability limit (by volume) N/A Material VOC None Vapor density Heavier than air Relative density N/A Solubility in water Negligible Partition coefficient: n-octanol/water N/A Auto -ignition temperature N/A Decomposition temperature N/A 1O.Stability and Reactivity Reactivity Stable Chemical Stability Stable under normal conditions. Possibility of hazardous reactions Under normal conditions of storage and use, hazardous reactions will not occur. Conditions to avoid Extremes of temperature and direct sunlight. Incompatible materials Reactive or incompatible with the following materials: Strong oxidizing agents Strong acids Aliphatic amines Hazardous decomposition products Other hazards 11. Toxicological Information Under normal conditions of storage and use, hazardous decomposition products should not be produced. Reacts with considerable heat release with some curing agents. Acute Health Hazard (components) No comprehensive data (ingestion, inhalation, dermal) on mixture (product). Component Result Species Dose Exposure Diglycidyl Ether of Bisphenol A LD50 Oral Rat 11,400 mg/kg LD50 Dermal Rat 2,000 mg/kg - Alkyl Glycidyl Ether LD50 Oral Rat 4,500 mg/kg Diglycidyl Ether of Bisphenol F LD50 Oral Rat >2,000 mg/kg - LD50 Dermal Rat >2,000 mg/kg - BenzylAlcohol LD50 Oral Rat 1620 mg/kg - LC50 Inhalation Rat >4178 mg/m3 4 h, aerosol Irritation/Corrosion (components) No data is available for this product. Component Result Species Test Exposure k Diglycidyl Ether of Bisphenol A Moderate to severe irritation Rabbit Skin 4 h Mild irritation Rabbit Eye 24 h Diglycidyl Ether of Bisphenol F Mild irritant Rabbit Skin Mild irritant Rabbit Eye - Benzyl Alcohol Non-irritant Rabbit Skin Irritant Rabbit Eye - Sensitization Mutagenicity Carcinogenicity Reproductive Toxicity Teratogenicity Specific target organ toxicity (single exposure) No data is available for this product. No data is available for this product. No data is available for this product. No data is available for this product. No data is available for this product. No data is available for this product. Component Category Route of exposure Target organs Diglycidyl Ether of Bisphenol A Category 3 Respiratory tract irritation Alkyl Glycidyl Ether Category 3 Respiratory tract irritation Diglycidyl Ether of Bisphenol F Category 3 Respiratory tract irritation Specific tareet organ toxicity (repeated exposure) Aspiration hazard Potential acute health effects Eye Contact Inhalation Skin Contact Ingestion Symptoms related to the physical, chemical and toxicological characteristics Eye Contact No data is available for this product. No data is available for this product. Causes serious eye irritation. May cause respiratory irritation. Causes skin irritation. May cause an allergic skin reaction. Irritating to mouth, throat and stomach. Adverse symptoms may include the following: Pain or irritation Watering Redness Inhalation Adverse symptoms may include the following: Respiratory tract irritation Coughing Skin Contact Adverse symptoms may include the following: Irritation Pain Redness Ingestion No specific data Delayed and immediate effects and also Not available. chronic effects from short and long term exposure Potential chronic health effects General Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. Carcinogenicity No known significant effects or critical hazards. Mutagenicity No known significant effects or critical hazards. Teratogenicity No known significant effects or critical hazards. Developmental effects No known significant effects or critical hazards. Fertility effects No known significant effects or critical hazards. Numerical measures of toxicity Acute toxicity estimates (ATEmix) Not available. 12. Ecological Information Ecotoxicity No information on the product itself. Component Test Species Result Exposure Diglycidyl Ether of Bisphenol A LC50 Fish 1.3 mg/I 96 h LC50 Daphnia 2.1 mg/I 48 h Diglycidyl Ether of Bisphenol F LC50 Fish 1.5 mg/I 96 h LC50 Daphnia 1.7 mg/I 48 h Chronic NOEC Daphnia 0.3 mg/I 21 d Benzyl Alcohol LC50 Fish 460 mg/I 96 h EC50 Invertebrates 230 mg/I 48 h EC50 Algae 770 mg/I 72 h Chronic NOEC Algae 310 mg/I 72 h Persistence and degradability No information on the product itself. Component Test Period Result Diglycidyl Ether of Bisphenol A OECD 302E 28 d 12% Diglycidyl Ether of Bisphenol F OECD 301F Derived 28 d 5% Benzyl Alcohol Readily Biodegradable Bloaccumulatiye Potential No information on the product itself. Component LogPow - BCF Potential Diglycidyl Ether of Bisphenol A 2.64-3.78 3-31 Low Diglycidyl Ether of Bisphenol F 3.242 31 Low Alkyl glycidyl Ether 0.23 - Low Mobility in Soil Soil/water partition coefficient (KOC) Other adverse effects 13. Disaosal Considerations Waste from residues/ unused products No information on the product itself. No know significant effects or critical hazards. The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Product should not be allowed to enter drains, water courses or the soil; dispose of this material and its containers in a safe way. Contact supplier if guidance is required. Contaminated packaging Dispose of container and unused contents in accordance with federal, state and local requirements. 14.Transport Information The data provided in this section is for information only and may not be specific to your package size or mode of transport. You will need to apply the appropriate regulations to properly classify your shipment for transportation. International Transport Regulations Regulatory UN/NA number Proper Shipping Name Classes/'PG Additional information Information DOT Non -regulated TOG Non -regulated IMO/IMDG UN3082 Environmentally Hazardous Substance, Class 9 III Liquid, N.O.S. (Bisphenol-A Epichlorohydrin Resin) IATA (Cargo) UN3082 Environmentally Hazardous Substance, Class 9 III Liquid, N.O.S. (Bisphenol-A Epichlorohydrin Resin) *PG: Packing group Special precautions for user: Transport within users premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. 15. Regulatory Information UNITED STATES U.S. Federal Regulations United States —TSCA 12(b) — Chemical export notification: None Required. United States —TSCA 5(a)2 — Final significant new use rules: Not Listed. United States —TSCA 5(a)2 — Proposed significant new use rules: Not Listed. United States —TSCA S(e) —Substance consent order: Not listed. California Prop. 65 WARNING: This product contains less than 0.1% of a chemical known to the State of California to cause cancer. WARNING: This product contains less than 1%of a chemical known to the State of California to cause birth defects or other reproductive harm. Ingredient Name Cancer Reproductive No significant risk level Maximum acceptable dosagelevel Oxirane, 2-(phenoxymethyl)- Yes No 5 jig/clay No Oxirane, 2-(chloromethyl)- Yes Yes 9 jig/day No EPA SARA 302 Extremely None. Hazardous Substances EPA SARA 302/304/311/312 Acute Health Hazard Hazardous Chemicals United States inventory (TSCA 8b) All components are listed or exempted. CANADA WHMIS (Canada) Class D-2B: Material causing other toxic effects (Toxic). Canadian NPRI None required. CEPAToxic substances None required. INTERNATIONAL REGULATIONS International Lists Australia inventory (AILS): All components are listed or exempted. Canada inventory: All components are listed or exempted. Korea inventory: All components are listed or exempted. Japan inventory: All components are listed or exempted. China inventory (IECSC): All components are listed or exempted. New Zealand inventory (NZIoC): All components are listed or exempted. Philippines inventory (PICCS): All components are listed or exempted. Taiwan inventory (CSNN): All components are listed or exempted. 16.Other Information, Including Date of Preparation or Last Revision HMIS Rating Date of Preparation Date of Last Revision Revision # More Information Prepared by February 10, 2017 1.0 1-253-333-8118 N. Kim, System Three Resins Inc. The information contained herein is based on the data available to us and is believed to be correct. However, System Three Resins, Inc. makes no warranty, expressed or implied, regarding the accuracy of these data or the results to be obtained from the use thereof. System Three assumes no responsibility for injury from the use of the product described herein. 1. Product Identification Product name SIDS Number Product type Manufacturer/Supplier information Company name Address Telephone Website Email Emergency Contact 2. Hazard(s) Identification Classification of substance or mixture/Signal Word GHS Label Elements Hazard Pictograms Hazard Statements/Classification of substance or mixture Precautionary statements Precautionary Statements Prevention SAFETY DATA SHEET GelMagic Hardener, Part B 1230B00 Amine/Butadiene mixture Directed at, but not limited to, the adhesive bonding of similar and dissimilar substrates. SYSTEM THREE RESINS, INC. 3500 W. Valley Hwy, Suite Suite 105 Auburn, WA 98001-2436 United States 1-253-333-8118 www.systemthree.com support-08@systemthree.com CHEMTREC (U.S. and CANADA) CHEMTREC (Outside the U.S.) DANGER 1-800-424-9300 1-703-527-0585 SKIN CORROSION/IRRITATION — Category 2 SERIOUS EYE DAMAGE/EYE IRRITATION — Category 1 SKIN SENSITIZATION — Category 1 ACUTE AQUATIC HAZARD — Category 2 LONG-TERM AQUATIC HAZARD — Category 2 H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H401 Toxic to aquatic life. H411 Toxic to aquatic life with long lasting effects. P261 Avoid breathing vapors. P264 Wash hands thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P281 Use personal protective equipment as required. P285 In case of inadequate ventilation wear respiratory protection. Response P313 Call a POISON CENTER or doctor/physician if you feel unwell. P308 + P313 If exposed or concerned: Get medical attention. P302+352+363 IF ON SKIN: Wash with soap and water. Takeoff contaminated clothing and wash before reuse. P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P333+13313 If skin irritation or rash occurs: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. P391 Collect spillage. Storage P401 Store at room temperature in a well -ventilated area. Disposal P501 Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified (HNOC) None Available. 3. Composition/Information On Ingredients Chemical Name CAS Number Content (%) Modified Polyamines Trade Secret 60-70% ATBN Polymer 68683-29-4 20-30% Nonyl Phenol 25154-52-3 0-5% There are no additional ingredients presentwhich, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. 4. First -Aid Measures Skin contact Remove contaminated clothing and shoes and wipe, excess off skin. Flush skin with water. Follow by washing in soap and water. If irritation occurs, seek medical attention. Do not reuse clothing until cleaned. Contaminated leather articles (shoes) cannot be decontaminated and should be destroyed. Eye contact Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove contact lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. Ingestion Do not induce vomiting unless directed to do so by medical personnel. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Inhalation Remove victim to fresh air and provide oxygen if breathing is difficult. Give artificial respiration if not breathing. Get medical attention. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments No specific treatment. S. Fire -Fighting Measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Hazardous decomposition products Special protective actions for fire-fighters Special protective equipment for fire- fighters Further information 6. Accidental Release Measures Alcohol -resistant foam, carbon dioxide (CO2), dry chemical, water fog. None known. In a fire or if heated, a pressure increase will occur and the container may burst. This material is toxic to aquatic life with long lasting effects. Fire water contaminated must be contained and prevented from being discharged to any waterway, sewer or drain. Decomposition products may include the following materials: Carbon dioxide, carbon monoxide, nitrogen oxides Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face -piece operated in positive pressure mode. Do not allow run-off from firefighting to enter drains or water courses. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Personal precautions No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Do not breathe vapor or mist. Provide adequate ventilation. Wear proper protective clothing, gloves and eye/face protection. Use self-contained breathing apparatus and chemically protective clothing. Emergency procedures If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. Methods and materials for Stop leak if without risk. Move containers from spill area. Approach release containment/cleanup from upwind. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage. 7. Handling and Storage Precautions for safe handling Avoid contact with skin and eyes. Emergency showers and eye wash stations should be readily accessible. Adhere to work practice rules established by government regulations. Use personal protective equipment. When using, do not eat, drink or smoke. Precautions/Recommendations for Store epoxy products in temperature stable environment, out of the reach of safe/proper storage pets or children. Securely fasten container lids and tops, and prevent products from sitting and below freezing temperatures. 8. Exposure Controls/Personal Protection Permissible exposure limit (OSHA) None established. Threshold limit value (ACGIH) None established. Appropriate engineering controls Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Environmental exposure controls Use appropriate containment to avoid environmental contamination. Do not allow spill to enter sewers or waterways. Individual protection measures/Personal protective equipment Eye/face protection Splash -proof goggles or safety spectacles with side shields are recommended. Always wear eye protection when sanding cured epoxy resins to avoid dust in eyes. Hand protection Always wear impervious gloves: butyl rubber, nitrile rubber, Neoprene, PVC disposable gloves, Skin protection Wear clean, body -covering clothing to avoid skin contact. Respiratory protection Use a properly fitted, air -purifying or air -fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Special instructions for protection and Wear gloves at all times when handling product, avoid direct contact with skin. hygiene When finished using product, dispose of gloves properly and wash hands with warm, soapy water. 9. Physical and Chemical Properties Chemical family Appearance Physical State Form Color Odor Density (Specific Gravity) Viscosity pH Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Polyamine Amber colored paste Amine/Butadiene mixture Paste Amber Mild 8.40lb/gal (1.01) 60,000 cps at 77 °F (25 °C) N/A N/A N/A >250°F, Pensky-Martens Closed Cup Slower than ether Data not available Upper/lower flammability limit (by volume) N/A Material VOC None Vapor density Heavier than air Relative density Not determined Solubility in water Partition coefficient: n-octanol/water 1O.Stability and Reactivity Negligible N/A Reactivity No specific test data related to reactivity available for this product. Chemical Stability Stable under normal conditions. Possibility of hazardous reactions Hazardous polymerization will not occur. Conditions to avoid Epoxy resins and epoxy resin hardeners react with each other producing heat. They should not be mixed with each other under uncontrolled conditions or in large mass as the ensuing exotherm may result in heat and smoke, resulting in hazardous decomposition products. Incompatible materials Strong oxidizing and reducing agents. Lewis and mineral acids. Hazardous decomposition products Oxides of carbon and nitrogen. 11. Toxicological Information Acute Toxicity No comprehensive data is available on the product itself. Irritation/Corrosion (components) Classifies as non -corrosive to skin per negative Corrositex Dermal Testing. Classifies as Serious Eye Damage Category 1 per GHS calculations of additivity. Component Test Species Result Modified Polyamines OECD 404 Acute Dermal Rabbit Skin — Corrosive Irritation/Corrosion OECD 405 Acute Eye Rabbit Eyes - Corrosive Irritation/Corrosion Sensitization No information on product itself. Component Species Result ATBN Polymer Guinea Pig Strong Sensitizer Mutageniciri Carcinogenicity Reproductive Toxicity Teratogenicity Specific target organ toxicity (sinele exposure) Specific target orean toxicity (repeated exposure) Aspiration hazard Potential acute health effects Eye Contact Inhalation Skin Contact Ingestion Symptoms related to the Physical, chemical and toxicological characteristics No information on product itself. No information on product itself. No information on product itself. No information on product itself. No information on product itself. No information on product itself. No information on product itself. Causes serious eye damage. May give off vapor that is irritating to the respiratory system. Causes skin irritation. May cause an allergic skin reaction. Harmful if swallowed. Eye Contact Adverse symptoms may include the following: Pain Watering Redness Inhalation No data available. Skin Contact Adverse symptoms may include the following: Pain or irritation Ingestion No data available. Delayed and immediate effects and also No data available. chronic effects from short and long term exposure Potential chronic health effects General Carcinogenicity Mutagenicity Teratogenicity Developmental effects Fertility effects Numerical measures of toxiciri Acute toxicity estimates (ATE.,.) Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. Route ATE value Oral 2344.2 mg/kg Dermal 2054.1 mg/kg Inhalation (vapors) N/A 12. Ecological Information Ecotoxicity No information on product itself. Component Test Endpoint Exposure Species Result ATBN Polymer OECD 202 Invertebrates Acute EC50 48 h Invertebrates >1000 mg/I OECD 201 Algae, Growth Inhibition Test Acute EC50 72 h Algae >1000 mg/I Nonyl Phenol OECD 209 Activated Sludge, Respiration Inhibition Test Acute EC50 3 h Static Bacteria 950 mg/I ASTM Acute EC50 48 h Static Daphnia 0.085 mg/I ASTM Acute LC50 96 h Static Fish 0.05 mg/I Persistence and degradabiliri No information on product itself. Component Test Period Result Nonyl phenol OECD 301E Ready Biodegradability— CO2 Evolution Test 35 days 48.2% Bioaccumulative Potential No information on product itself. Component LogPow, BCF Potential Nonyl Phenol 5.4 740 High Mobility in Soil Soil/water partition coefficient (KOC) Other adverse effects 13. Disposal Considerations Waste from residues/ unused products Contaminated packaging 14.Transport Information No information on product itself. No known significant effects or critical hazards. The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Product should not be allowed to enter drains, water courses or the soil; dispose of this material and its containers in a safe way. Contact supplier if guidance is required. Dispose of container and unused contents in accordance with federal, state and local requirements. The data provided in this section is for information only and may not be specific to your package size or mode of transport. You will need to apply the appropriate regulations to properly classify your shipment for transportation. International Transport Regulations Regulatory UN/NA number information DOT TOG IMO/IMDG UN3082 IATA (Cargo) UN3082 Proper Shipping Name Non -regulated Non -regulated Environmentally hazardous substance, liquid, n.o.s. (Nonyl Phenol) Environmentally hazardous substance, liquid, n.o.s. (Nonyl Phenol) Classes/*PG Class 9 III Class III Additional Information Marine pollutant *PG: Packing group Special precautions for user: Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. 15. Regulatory Information UNITED STATES U.S. Federal Regulations Clean Air Act — Ozone Depleting Substances (ODS) Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs) Pennsylvania — RTK United States —TSCA 12(b) — Chemical export notification: None Required. United States —TSCA 5(a)2—Final significant new use rules: Not Listed. United. States —TSCA 12(b)— Proposed significant new use rules: None Required. United States —TSCA 5(e) —Substance consent order: Not listed. This product does not contain nor is it manufactured with ozone depleting substances. Product Name Concentration % Phenol 0-1% Diethanolamine Phenol. California Prop. 65 EPA SARA 302/304/311/312 Substances EPA SARA 313 Form R — Reporting requirements CERCLA Hazardous Substances United States inventory (TSCA 8b) CANADA WHMIS (Canada) Canadian NPRI CEPA Toxic substances INTERNATIONAL REGULATIONS International Lists This product contains no listed substances known to the State of California to cause cancer, birth defects or other reproductive harm, at levels which would require a warning under the statute. Acute Health Hazard Product Name Concentration % Phenol 0-1% Diethanolamine 1% Component % Section 304 CERCLA Hazardous Substance CERCLA Reportable Quantity (Lbs) Product Reportable Quantity (Lbs) Phenol 1 Listed Diethanolamine 1 100 All components are listed or exempted. Class D-213: Material causing other toxic effects (Toxic). Class E: Corrosive material. None Required None Required Australia inventory (AICS): All components are listed or exempted. Canada inventory: All components are listed or exempted. Korea inventory: All components are listed or exempted. Japan inventory: All components are listed or exempted. China inventory (IECSC): All components are listed or exempted. New Zealand inventory (NZIoC): All components are listed or exempted. Philippines inventory (PICCS): All components are listed or exempted. Taiwan inventory (CSNN): All components are listed or exempted. 16. Other Information, Including Date of HMIS Rating Date of Preparation Date of Last Revision Revision # More Information Prepared by ration or Last Revision April 20, 2017 July 25, 2016 2.0 1-253-333-8118 N. Kim, System Three Resins Inc. The information contained herein is based on the data available to us and is believed to be correct. However, System Three Resins, Inc. makes no warranty, expressed or implied, regarding the accuracy of these data or the results to be obtained from the use thereof. System Three assumes no responsibility for injury from the use of the product described herein. SYSTEMTHAEF 1. Product Identification SAFETY DATA SHEET Product name GelMagic Resin, Part A SDS Number 1230A00 Product type Epoxy polymer mixture. Manufacturer/Supplier information Directed at, but not limited to, the adhesive of similar and dissimilar substrates. Company name SYSTEM THREE RESINS, INC Address 3500 W. Valley Hwy, Suite Suite 105 Auburn, WA 98001-2436 United States Telephone 1-253-333-8118 Website www.systemthree.com Email support-08@systemthree.com Emergency Contact CHEMTREC (U.S. and CANADA) 1-800-424-9300 CHEMTREC (Outside the U.S.) 1-703-527-0585 2. Hazard(s) Identification Classification of substance or WARNING mixture/Signal Word Skin Corrosion/Irritation - Category 2 Serious Eye Damage/Eye Irritation - Category 2 Skin Sensitization - Category 1 Specific Target Organ Toxicity (Single Exposure) [Respiratory tract irritation] — Category 3 GHS Label Elements Hazard Pictograms , • Hazard Statements/Classification of H315 Causes skin irritation. substance or mixture H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H335 May cause respiratory irritation. Precautionary statements Precautionary Statements Prevention P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P264 Wash hands thoroughly after handling. P271 Use only outdoors or in a well -ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/protective clothing/eye protection/face protection. Response P304 +340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P313 Call a POISON CENTER or doctor/physician if you feel unwell. P302+352+363 IF ON SKIN: Wash with soap and water. Takeoff contaminated clothing and wash before reuse. P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P308 + P313 If exposed or concerned: Get medical attention. Storage P401 Store at room temperature in a well -ventilated area. Disposal P501 Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified (HNOC) None Available. 3. Composition/Information On Ingredients Chemical Name CAS Number Content (%) Digl cidyl Ether of Bis henol A 25068-38-6 70-80 % Benzyl Alcohol 100-51-6 5-10 % Alkyl Glycidyl Ether 17557-23-2 5 —10 % There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. 4. First -Aid Measures Skin contact Remove contaminated clothing and shoes and wipe excess off skin. Flush skin with water. Follow by washing in soap and water. If irritation occurs, seek medical attention. Do not reuse clothing until cleaned. Contaminated leather articles (shoes) cannot be decontaminated and should be destroyed. Eye contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Ingestion Do not induce vomiting unless directed to do so by medical personnel. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Inhalation Remove victim to fresh air and provide oxygen if breathing is difficult. Give artificial respiration if not breathing. Get medical attention. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments No specific treatment. 5. Fire -Fighting Measures Suitable extinguishing media Alcohol -resistant foam, carbon dioxide (CO2), dry chemical, water fog. Unsuitable extinguishing media None known. Specific hazards arising from the chemical In a fire or if heated, a pressure increase will occur and the container may burst. This material is toxic to aquatic life with long lasting effects. Fire water contaminated must be contained and prevented from being discharged to any waterway, sewer or drain. Hazardous decomposition products Decomposition products may include the following materials: Carbon dioxide Carbon monoxide Special protective actions for fire-fighters Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective equipment for fire- Fire-fighters should wear appropriate protective equipment and self-contained fighters breathing apparatus (SCBA) with a full face -piece operated in positive pressure mode. Further information Do not allow run-off from firefighting to enter drains or water courses. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. 6. Accidental Release Measures Personal precautions Wear proper personal protective equipment (PPE). Avoid direct contact with material. Proper PPE includes: disposable gloves, eye protection and skin protection. Emergency procedures If materials is spilled, avoid contact with material. Persons not wearing appropriate protective equipment should leave the area of the spill until cleanup is complete. Methods and materials for Stop leak if without risk. Move containers from spill area. Approach release containment/cleanup from upwind. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage. 7. Handling and Storage Precautions for safe handling Avoid contact with skin and eyes. Emergency showers and eye wash stations should be readily accessible. Adhere to work practice rules established by government regulations. Use personal protective equipment. When using, do not eat, drink or smoke. Precautions/Recommendations for Store epoxy products in temperature stable environment, out of the reach of safe/proper storage pets or children. Securely fasten container lids and tops, and prevent products from sitting and below freezing temperatures. 8. Exposure Controls/Personal Protection Permissible exposure limit (OSHA) None established. Threshold limit value (ACGIH) None established. Appropriate engineering controls Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Environmental exposure controls Use appropriate containment to avoid environmental contamination. Do not allow spill to enter sewers or waterways. Individual protection measures/Personal protective equipment Eye/face protection Hand protection Skin protection Respiratory protection Special instructions for protection and hygiene Splash -proof goggles or safety spectacles with side shields are recommended. Always wear eye protection when sanding cured epoxy resins to avoid dust in eyes. Always wear impervious gloves: butyl rubber, nitrile rubber, Neoprene, PVC disposable gloves, Wear clean, body -covering clothing to avoid skin contact Use a properly fitted, air -purifying or air -fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Wear gloves at all times when handling product, avoid direct contact with skin. When finished using product, dispose of gloves properly and wash hands with warm, soapy water. 9. Physical and Chemical Properties Chemical family Epoxy Resin Appearance Blue paste Physical State Epoxy polymer mixture Form Paste Color Blue Odor Mild Density (Specific Gravity) 9.78 lb/gal (1.17) Viscosity 90,000 cps at 77'F (25 °C) pH N/A Melting point/freezing point N/A Initial boiling point and boiling range N/A Flash point >300°F, Pensky-Martens Closed Cup Evaporation rate Slower than ether Flammability (solid, gas) Data not available Upper/lower flammability limit (by volume) N/A Upper flammability limit (by volume) N/A Lower flammability limit (by volume) N/A Material VOC None Vapor density Heavier than air Relative density Not determined Solubility in water Negligible Partition coefficient: n-octanol/water 3 Auto -ignition temperature 300°C (572.00-F) Decomposition temperature N/A 10.Stability and Reactivity Reactivity No specific test data related to reactivity available for this product. Chemical Stability Stable under normal conditions. Possibility of hazardous reactions Hazardous polymerization will not occur. Conditions to avoid Epoxy resins and epoxy resin hardeners react with each other producing heat. They should not be mixed with each other under uncontrolled conditions or in large mass as the ensuing exotherm may result in heat and smoke, resulting in hazardous decomposition products. Incompatible materials Strong oxidizing and reducing agents. Lewis and mineral acids. Hazardous decomposition products Oxides of carbon, aldehydes, and acids. 11. Toxicological Information Acute Toxicity No comprehensive data is available on the product itself. Component Result Species Dose Exposure Diglycidyl Ether of Bisphenol A LD50 Oral Rat 11,400 mg/kg LD50 Dermal Rat 2,000 mg/kg - Alkyl Glycidyl Ether LD50 Oral Rat 4,500 mg/kg - LD50 Dermal Rabbit >2,000 mg/kg - Benzyl Alcohol LD50 Oral Rat 1620 mg/kg - LC50Inhalation Rat >4178 mg/m3 4 h, aerosol Irritation/Corrosion (components) No information on product itself. Component Result Species Test Exposure Diglycidyl Ether of Bisphenol A Moderate to severe irritation Rabbit Skin 4 h Mild irritation Rabbit Eye 24 h Benzyl Alcohol Irritant Rabbit Eye - Sensitization Mutagenicity Carcinogenicity Reproductive Toxicitv Teratogenicity Specific target organ toxicity (single exnosurel No information on product itself. No information on product itself. No information on product itself. No information on product itself. No information on product itself. No information on product itself. Component Category Route of exposure Target organs Diglycidyl Ether of Bisphenol A Category 3 Respiratory tract irritation Alkyl Glycidyl Ether Category 3 Respiratory tract irritation Specific target organ toxicity (repeated No information on product itself. exposure) Aspiration hazard No information on product itself. Potential acute health effects Eye Contact Causes serious eye irritation. Inhalation May cause respiratory irritation. Skin Contact Causes skin irritation. May cause an allergic skin reaction. Ingestion Irritating to mouth, throat and stomach. Symptoms related to the physical, chemical and toxicological characteristics Eye Contact Adverse symptoms may include the following: Pain Watering Redness Inhalation Adverse symptoms may include the following: Respiratory tract irritation Coughing Skin Contact Adverse symptoms may include the following: Irritation Redness Ingestion No specific data. Delayed and immediate effects and also Not available. chronic effects from short and'long term exposure Potential chronic health effects General Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. Carcinogenicity No known significant effects or critical hazards. Mutagenicity No known significant effects or critical hazards. Teratogenicity No known significant effects or critical hazards. Developmental effects No known significant effects or critical hazards. Fertility effects No known significant effects or critical hazards. Numerical measures of toxiciri Acute toxicity estimates (ATEmi,l No specific data. 12. Ecological Information Ecotoxicity No information on product itself. Component Result Species Exposure Diglycidyl Ether of Bisphenol A Acute LC50 1.3 mg/I Fish 96 h Acute LC50 2.1 mg/I Daphnia 48 h Benzyl Alcohol Acute LC50 460 mg/I Fish 96 h Acute EC50 230 mg/I Invertebrates 48 h Chronic NOEC 310 mg/I Algae 72 h Persistence and degradability No information on product itself. Bioaccumulative Potential No information on product itself. Component LogPow BCF Potential Diglycidyl Ether of Bisphenol A 2.64 —3.78 3—3131.00 Low Benzyl Alcohol 1.05 1.37 (calculated) Mobility in Soil Soil/water partition coefficient (KOC) Other adverse effects 13. Disposal Considerations Waste from residues/ unused products Contaminated packaging 14.Transport Information No information on product itself. No known significant effects or critical hazards. The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Product should not be allowed to enter drains, water courses or the soil; dispose of this material and its containers in a safe way. Contact supplier if guidance is required. Dispose of container and unused contents in accordance with federal, state and local requirements. The data provided in this section is for information only and may not be specific to your package size or mode of transport. You will need to apply the appropriate regulations to properly classify your shipment for transportation. International Transport Regulations Regulatory UN/NA number Proper Shipping Name Classes/*PG information DOT Non -regulated TDG Non -regulated IMO/IMDG UN3077 ENVIRONMENTALLY HAZARDOUS Class 9111 SUBSTANCE, SOLID, N.O.S. (BISPHENOL- A EPICHLOROHYDRIN RESIN) IATA (Cargo) UN3077 ENVIRONMENTALLY HAZARDOUS Class 9 111 SUBSTANCE, SOLID, N.O.S. (BISPHENOL- A EPICHLOROHYDRIN RESIN) *PG: Packing group Special precautions for user: 15. UNITED STATES Information Additional Information Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. U.S. Federal Regulations United States —TSCA 12(b) — Chemical export notification: None Required. United States —TSCA 5(a)2— Final significant new use rules: Not Listed. United States — TSCA 12(b) — Proposed significant new use rules: None Required. United States — TSCA 5(e) — Substance consent order: Not listed. Clean Air Act — Ozone Depleting This product does not contain nor is it manufactured with ozone depleting Substances(ODS) substances. California Prop. 65 WARNING: This product contains less than 0.1%of a chemical known to the State of California to cause cancer. WARNING: This product contains less than 1% of a chemical known to the State of California to cause birth defects or other reproductive harm. Ingredient Name Cancer Reproductive No significant risk level Maximum acceptable dosagelevel Oxirane, 2-(phenoxymethyl)- Yes No 5 µg/day No Oxirane, 2-(chloromethyl)- Yes Yes 9 µg/day No EPA SARA 302/304/3111312 Acute Health Hazard Substances EPA SARA 313 None Required United States inventory (TSCA 8b) All components are listed or exempted. CANADA WHMIS (Canada) Class D-28: Material. causing other toxic effects (Toxic). Canadian NPRI None Required CEPA Toxic substances None Required INTERNATIONAL REGULATIONS International Lists Australia inventory (AILS): All components are listed or exempted. Canada inventory: All components are listed or exempted. Korea inventory: All components are listed or exempted. Japan inventory: All components are listed or exempted. China inventory (IECSC): All components are listed or exempted. New Zealand inventory (NZIoQ: All components are listed or exempted. Philippines inventory (PICCS): All components are listed or exempted. Taiwan inventory (CSNN): All components are listed or exempted. 16. Other Information, Including Date of Preparation or Last Revision HMIS Rating Date of Preparation Date of Last Revision Revision # More Information Prepared by February 13, 2017 December 8, 2016 3.0 1-253-333-8118 N. Kim, System Three Resins Inc. The information contained herein is based on the data available to us and is believed to be correct. However, System Three Resins, Inc. makes no warranty, expressed or implied, regarding the accuracy of these data or the results to be obtained from the use thereof. System Three assumes no responsibility for injury from the use of the product described herein. SAFETY DATA SHEET 1. Product Identification Product name QUIkFalr Hardener Part B SIDS Number 1400B00 Product type Amine/Pigment Mixture Recommended use of the chemical and Putty Hardener Component. restrictions on use Restrictions Manufacturer/Supplier information Company name Address Telephone Website Email Emergency Contact 2. Hazard(s) Identification None known. SYSTEM THREE RESINS, INC. 3500 W. Valley Hwy, Suite Suite 105 Auburn, WA 98001-2436 United States 1-253-333-8118 www.systemthree.com support-08@systemthree.com CHEMTREC (U.S. and CANADA) 1-800-424-9300 CHEMTREC (Outside the U.S.) 1-703-527-0585 Classification of substance or DANGER mixture/Signal Word ACUTE TOXICITY: ORAL — Category 4 SK{N CORROSION/IRRITATION — Category 2 SERIOUS EYE DAMAGE/EYE IRRITATION — Category 1 SKIN SENSITIZER — Category 1 REPRODUCTIVE TOXICITY [Fertility] — Category 2 REPRODUCTIVE TOXICITY [Unborn Child] — Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) —Category 3 AQUATIC HAZARD (ACUTE) — Category 1 AQUATIC HAZARD (CHRONIC) —Category 1 GHS Label Elements Hazard Pictograms < >O<t< > Hazard Statements/Classification of H302 Harmful if swallowed. substance or mixture H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H335 May cause respiratory irritation. H361 Suspected of damaging fertility or the unborn child. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. Precautionary statements Precautionary Statements Prevention P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P261 Avoid breathing fumes/vapors. P264 Wash hands and exposed skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well -ventilated area. P272 Contaminated clothing should not be allowed out of the workplace. P272 Avoid release to the environment. P280 Wear eye protection/face protection. Wear protective gloves. Response P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/attention. P312 Call a POISON CENTER/doctor if you feel unwell. P330 Rinse mouth. P362+P364 Take off contaminated clothing and wash it before reuse. P391 Collect spillage. Storage P403+P233 Store in a well -ventilated place. Keep container tightly closed. P405 Store locked up. Disposal P501 Disposal of contents/container to be specified in accordance with regulations. Hazards not otherwise classified (HNOC) None known. 3. Composition/Information On Ingredients Chemical Name CAS Number Content (%) Modified Aliphatic Amines Trade Secret 50 — 60% Nonyl Phenol 84852-15-3 20-30% Para-tertiary-butylphenol 98-54-4 20 — 30% There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. 4. First -Aid Measures Skin contact Get medical attention immediately. Remove material from skin immediately by washing with soap and plenty of water. Remove contaminated clothing and shoes while washing. Seek medical attention if irritation persists or if open sores or blisters develop. Wash clothing before reuse. Discard items which cannot be decontaminated, including leather articles such as shoes, belts and watchbands. Safety shower should be located in immediate work area. Eye contact Get medical attention immediately. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 15 minutes. Suitable emergency eye wash facility should be available in work area. Ingestion Get medical attention immediately. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waist band. Inhalation Get medical attention immediately. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled or if extended exposure to eye and skin tissues have occurred. Specific treatments No specific treatment. 5. Fire -Fighting Measures Suitable extinguishing media Alcohol -resistant foam, carbon dioxide (CO2), dry chemical, water fog. Unsuitable extinguishing media None known. Specific hazards arising from the chemical In a fire or if heated, a pressure increase will occur and the container may burst. This material is toxic to aquatic life with long lasting effects. Fire water contaminated must be contained and prevented from being discharged to any waterway, sewer or drain. Fire may produce irritating, corrosive and/or toxic gases. Hazardous decomposition products Decomposition products may include the following materials: Carbon dioxide Carbon monoxide Nitrogen oxides Special protective actions for fire-fighters Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective equipment for fire- Fire-fighters should wear appropriate protective equipment and self-contained fighters breathing apparatus (SCBA) with a full face -piece operated in positive pressure mode. Further information Do not allow run-off from firefighting to enter drains or water courses. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. 6. Accidental Release Measures Personal precautions No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Wear proper protective clothing, gloves and eye/face protection. Emergency procedures If material is spilled, avoid contact with material. Persons not wearing appropriate protective equipment should leave the area of the spill until cleanup is complete. Methods and materials for Stop leak if without risk. Move containers from spill area. Approach release containment/cleanup from upwind. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). 7. Handling and Precautions for safe handling Put on appropriate personal protective equipment (see Section 8). Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Avoid breathing vapor or mist. Do not swallow. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Precautions/Recommendations for Store in accordance with local regulations. Store in original container protected safe/proper storage from direct sunlight in a dry, cool and well -ventilated area, away from incompatible materials and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. 8. Exposure Controls/Personal Protection Occupational Exposure Limits None established. Appropriate engineering controls Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Environmental exposure controls Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Do not allow spill to enter sewers or waterways. Individual protection measures/Personal protective equipment Eye/face protection Splash -proof goggles or safety spectacles with side shields are recommended. Always wear eye protection when sanding cured epoxy resins to avoid dust in eyes. Hand protection Always wear impervious gloves: butyl rubber, nitrile rubber, Neoprene, PVC disposable gloves, Skin protection Wear clean, body -covering clothing to avoid skin contact. Respiratory protection Use a properly fitted, air -purifying or air -fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Special instructions for protection and Wear gloves at all times when handling product, avoid direct contact with skin. hygiene When finished using product, dispose of gloves properly and wash hands with warm, soapy water. 9. Physical and Chemical Properties Chemical family Appearance Physical State Form Color Odor Density (Specific Gravity) Viscosity pH Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability limit (by volume) Upper flammability limit (by volume) Lower flammability limit (by volume) Material VOC Vapor density Relative density Solubility in water Partition coefficient: n-octanol/water Auto -ignition temperature Decomposition temperature 10.Stability and Reactivity Amine curing agent Epoxy paste Solid paste Off-white Ammonia -like odor 0.7 — 0.8 60,000 CPS @77°F N/A N/A N/A >250°F(Pensky-Martins Closed Cup) Slower than ether N/A N/A N/A N/A None Heavier than air N/A Negligible N/A N/A N/A Reactivity Stable under normal conditions Chemical Stability Stable. Possibility of hazardous reactions Under normal conditions of storage and use, hazardous reactions will not occur. Conditions to avoid Epoxy resins and epoxy resin hardeners react with each other producing heat. They should not be mixed with each other under uncontrolled conditions or in a large mass as the ensuing exothermic reaction may result in heat and smoke. Incompatible materials Strong oxidizing agents, strong acids and reducing agents, and mineral acids. Hazardous decomposition products Irritating and/or toxic fumes and gases may be emitted upon the product's decomposition. Decomposition of this product may emit oxides of carbon and nitrogen. Other hazards None known. 11. Toxicological Information Acute Health Hazard (components► No comprehensive data (ingestion, inhalation, dermal) on mixture (product). Component Result Species Dose Exposure Modified Aliphatic Amines LD50 Dermal Rabbit, 2,000 mg/kg - LD50 Oral Rat 930 mg/kg - LD50 Dermal Rabbit 1,870 mg/kg - LD50 Oral Rat 1,170 mg/kg - LC50Inhalation Rat 4.9 mg/1 1 h Nonyl Phenol LD50 Dermal Rabbit 2,031 mg/kg LD50 Oral Rat 1,412 mg/kg - Para-tertiary-butylphenol LD50 Dermal Rabbit 2,520 mg/kg LD50 Oral Rat 5,660 mg/kg Irritation/Corrosion (components) Classifies as non -corrosive per negative Corrositex Dermal Testing. Classifies as Serious eye damage Category 1 per GHS calculations of additivity. Component Result Species Test Exposure Modified Aliphatic Amines Corrosive - Skin - Severe eye irritation - Eye - Para-tertiary-butylphenol Irritation - Skin - Serious eye irritation - Eye - Sensitization No data is available for this product. Component Test Species Result Exposure Modified Aliphatic Amines Buehler skin Guinea Pig No evidence of sensitization sensitization (guinea pig) Magnusson & Guinea Pig Evidence of sensitization in 7 of Kilgman 10 animals (intradermal induction maximization — 0.1%; topical induction -10%; study challenge — 2% & 1%). Mutagenicity No data is available for this product. Carcinogenicity No data is available for this product. Reproductive Toxicity A component has been shown to cause reproductive/teratogenic effects in laboratory animals (Phenol). Teratogenicity A component has been shown to cause reproductive/teratogenic effects in laboratory animals (Phenol). Specific target organ toxicity (single No data is available for this product. exposure) Component Category Route of exposure Target organs Modified Aliphatic Amines Category 3 Respiratory tract irritation Specific target organ toxicity (repeated No data is available for this product. exposure) Aspiration hazard No data is available for this product. Potential acute health effects Eye Contact Causes serious eye damage. Inhalation May cause respiratory irritation. Skin Contact Causes severe skin irritation. May cause a severe allergic reaction. Ingestion Harmful if swallowed. May cause burns to mouth, throat, and stomach. Symptoms related to the Dhvsical, chemical and toxicoloeical characteristics Eye Contact Adverse symptoms may include the following: Pain Watering Redness Inhalation Adverse symptoms may include the following: Reduced fetal weight Increase in fetal deaths Skin Contact Adverse symptoms may include the following: Pain or irritation Redness Blistering may occur Reduced fetal weight Increase in fetal deaths Ingestion Adverse symptoms may include the following: Stomach pains Reduced fetal weight Increase in fetal deaths Delayed and immediate effects and also No data is available for this product. chronic effects from short and long term exposure Potential chronic health effects General Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. Carcinogenicity No significant effects or critical hazards. Mutagenicity No significant effects or critical hazards. Teratogenicity Suspected of damaging the unborn child. Developmental effects No significant effects or critical hazards. Fertility effects Suspected of damaging fertility. Numerical measures of toxicity, Acute toxicity estimates (ATEmix) Route ATE value Oral 1861.4 mg/kg Dermal 2690.3 mg/kg Inhalation (vapors) 30.26 mg/I 12. Ecological Information Ecotoxicity No data is available on the product itself. Component Test Exposure Species Result Modified Aliphatic Amines LC50 OECD 203 96 h Fish 87.6 mg/I EC50 OECD 202 48 h Daphnia magna 15.2 mg/I NOEC OECD 211 21 d Daphnia magna 4.7 mg/I EC50 72 h Algae >100 mg/I EC50 48 h Daphnia magna 19.8 mg/I Fish 1825 mg/I Nonyl Phenol LC50 96 h Fish 0.209 mg/I EC50 48 h Daphnia magna 0.0844 mg/I Para-tertiary-butylphenol LC50 96 h Fish 5.14 mg/I EC50 48 h Daphnia magna 4.8 mg/I Persistence and degradability No data is available on the product itself. Component Test Period Result Modified Aliphatic Amines OECD 301E 28 d 49% Nonyl Phenol OECD 301E 35 d 48.2% Bioaccumulative Potential No data is available on the product itself. Component LogPow BCF Potential Modified Aliphatic Amines - 3.161/kg (calculated) Nonyl Phenol 5.4 740 high Para -tertiary -butyl phenol 3.31 - Mobility in Soil No data is available on the product itself. Soil/water partition coefficient (KOC) No data is available on the product itself. Other adverse effects No known significant effects or critical hazards. 13. Disposal Considerations Waste from residues/ unused products The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non -recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Contaminated packaging Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. 14.Transport Information The data provided in this section is for information only and may not be specific to your package size or mode of transport. You will need to apply the appropriate regulations to properly classify your shipment for transportation. International Transport Regulations Regulatory UN/NA number information DOT TDG IMO/IMDG UN3077 IATA(Cargo) UN3077 *PG: Packing group Special precautions for user: 15. Regulatory Information Proper Shipping Name Classes/*PG Additional Information Non -regulated Non -regulated ENVIRONMENTALLY HAZARDOUS Class 9 III Marine pollutant SUBSTANCE, SOLID, N.O.S. (Nonyl Phenol) ENVIRONMENTALLY HAZARDOUS Class 9111 SUBSTANCE, SOLID, N.O.S. (Nonyl Phenol) Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. UNITED STATES U.S. Federal Regulations United States —TSCA 12(b) — Chemical export notification: None Required. United States — TSCA 5(a)2 — Final significant new use rules: Not Listed. United States —TSCA 5(a)2— Proposed significant new use rules: Not Listed. United States —TSCA 5(e) — Substance consent order: Not listed. Clean Air Act— Ozone Depleting This product does not contain nor is it manufactured with ozone depleting Substances(ODS) substances. Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs) Pennsylvania — RTK California Prop. 65 EPA SARA 302 Extremely Hazardous Substances Product Name Concentration % Phenol 0-1 vnenoi This product contains no listed substances known to the State of California to cause cancer, birth defects or other reproductive harm, at levels which would require a warning under the statute. None EPA SARA 302/304/311/312 Hazardous Acute Health Hazard, Chronic Health Hazard Chemicals SARA 313 Form R — Reporting requirements CERCLA Hazardous substances Product Name Concentration % Phenol 0-1 Component % Section 304 CERCLA Product CERCLA Reportable Reportable Hazardous Quantity Quantity Substance (Lbs) (Lbs) Phenol 1 Listed United States inventory (TSCA 8b) All components are listed or exempted. CANADA WHMIS (Canada) Class D-28: Material causing other toxic effects (Toxic). Canadian NPRI None required. CEPA Toxic substances None required. INTERNATIONAL REGULATIONS International Lists Australia inventory (AICS): All components are listed or exempted. Canada inventory: All components are listed or exempted. Korea inventory: All components are listed or exempted. Japan inventory: All components are listed or exempted. China inventory (IECSC): All components are listed or exempted. New Zealand inventory (NZIoC): All components are listed or exempted. Philippines inventory (PICCS): All components are listed or exempted. Taiwan inventory (CSNN): All components are listed or exempted. 16. Other Information, Including Date of Preparation or Last Revision HMIS Rating Date of Preparation Date of Last Revision Revision p More Information Prepared by February 13, 2017 December 29, 2015 2.0 1-253-333-8118 N. Kim, System Three Resins Inc. The information contained herein is based on the data available to us and is believed to be correct. However, System Three Resins, Inc. makes no warranty, expressed or implied, regarding the accuracy of these data or the results to be obtained from the use thereof. System Three assumes no responsibility for injury from the use of the product described herein. SAFETY DATA SHEET 1. Product Identification Product name QuikFair Resin Part A SIDS Number 1400A00 Product type Epoxy Resin Mixture Recommended use of the chemical and Putty resin component. restrictions on use Restrictions None known. Manufacturer/Supplier information Company name Address Telephone Website Email Emergency Contact 2. Hazard(s) Identification SYSTEM THREE RESINS, INC. 3500 W. Valley Hwy, Suite Suite 105 Auburn, WA 98001-2436 United States 1-253-333-8118 www.systemthree.com support-08@systemthree.com CHEMTREC (U.S. and CANADA) 1-800-424-9300 CHEMTREC (Outside the U.S.) 1-703-527-0585 Classification of substance or WARNING mixture/Signal Word Skin Corrosion/Irritation —Category 2 Serious Eye Damage/Eye Irritation — Category 2 Skin Sensitization — Category 1 Specific Target Organ Toxicity (Single Exposure) [Respiratory tract irritation] — Category 3 GHS Label Elements Hazard Pictograms • < > Hazard Statements/Classification of H315 Causes skin irritation. substance or mixture H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H335 May cause respiratory irritation. Precautionary statements Precautionary Statements Prevention P280 Wear protective gloves. Wear eye or face protection. P201 Obtain special instructions before use. P271 Use only outdoors or in a well -ventilated area. P261 Avoid breathing vapor. P264 Wash hands thoroughly after handling. Response Storage Disposal Hazards not otherwise classified (HNOC) 3. Composition/information on P272 Contaminated work clothing should not be allowed out of the workplace. P304 +340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P313 Call a POISON CENTER or doctor/physician if you feel unwell. P302+352+363 IF ON SKIN: Wash with soap and water. Takeoff contaminated clothing and wash before reuse. P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P401 Store at room temperature in a well -ventilated area. P501 Dispose of contents and container in accordance with all local, regional, national and international regulations. None Available. Chemical Name CAS Number Content (°a) Diglycidyl Ether of Bisphenol A 25068-38-6 50-60% Alkyl Glycidyl Ether 17557-23-2 15-20% Diglycidyl Ether of Bisphenol F 28064-14-4 3-8% There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. 4. First -Aid Measures Skin contact Remove material from skin immediately by washing with soap and plenty of water. Remove contaminated clothing and shoes while washing. Seek medical attention if irritation persists. Wash clothing before reuse. Discard items which cannot be decontaminated, including leather articles such as shoes, belts and watch bands. Eye contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 15 minutes. Suitable emergency eye wash facility should be available in work area. Get medical attention immediately if irritation persists. Ingestion Get medical attention immediately. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt orwaistband. Inhalation Get medical attention immediately. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. if unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments No specific treatment. 5. Fire -Fighting Measures Suitable extinguishing media Alcohol -resistant foam, dry chemical, water fog or carbon dioxide (CO2). Unsuitable extinguishing media None known. Specific hazards arising from the chemical In a fire or if heated, a pressure increase will occur and the container may burst. This material is toxic to aquatic life with long lasting effects. Fire water contaminated must be contained and prevented from being discharged to any waterway, sewer or drain. Hazardous decomposition products Decomposition products may include the following materials: Carbon dioxide Carbon monoxide Special protective actions for fire-fighters Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective equipment for fire- Fire-fighters should wear appropriate protective equipment, and self-contained fighters breathing apparatus (SCBA) with a full face -piece operated in positive pressure mode. Further information Do not allow run-off from firefighting to enter drains or water courses. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. 6. Accidental Release Measures Personal precautions No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Wear proper protective clothing, gloves and eye/face protection. Emergency procedures If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. Methods and materials for Stop leak if without risk. Move containers from spill area. Approach release containment/cleanup from upwind. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). 7. Handling and Storage Precautions for safe handling Put on appropriate personal protective equipment. Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid contact with skin and eyes. Do not ingest. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. When using, do not eat, drink or smoke. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Precautions/Recommendations for Store in accordance with local regulations. Store in original container protected safe/proper storage from direct sunlight in a dry, cool and well -ventilated area, away from incompatible materials and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. 8. Exposure Controls/Personal Protection Occupational Exposure Limits None established. Appropriate engineering controls Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Environmental exposure controls Use appropriate containment to avoid environmental contamination. Do not allow spill to enter sewers or waterways. Individual protection measures/Personal protective equipment Eye/face protection Splash -proof goggles or safety spectacles with side shields are recommended. Always wear eye protection when sanding cured epoxy resins to avoid dust in eyes. Hand protection Always wear impervious gloves: butyl rubber, nitrile rubber, Neoprene, PVC disposable gloves, Skin protection Wear clean, body -covering clothing to avoid skin contact. Respiratory protection Use a properly fitted, air -purifying or air -fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Special instructions for protection and Discard contaminated leather articles. Remove contaminated clothing. Wash at hygiene the end of each work shift and before eating smoking or using the toilet. Provide readily accessible eye wash stations and safety showers. 9. Physical and Chemical Properties Chemical family Epoxy Resin Appearance Colored paste Physical State Epoxy polymer mixture Form Paste Color Tan Odor Characteristic odor Density (Specific Gravity) 0.8 — 0.9 Viscosity 130,000 CPS @ 25C pH N/A Melting point/freezing point N/A Initial boiling point and boiling range N/A Flash point >300°F (Pensky-Martens Closed Cup) Evaporation rate Slower than ether Flammability (solid, gas) Data not available Upper/lower flammability limit (by volume) N/A Upper flammability limit (by volume) N/A Lower flammability limit (by volume) N/A Material VOC None Vapor density Heavier than air Relative density Not determined Solubility in water Negligible Partition coefficient: n-octanol/water N/A Auto -ignition temperature N/A Decomposition temperature N/A 1O.Stability and Reactivity No specific test data related to reactivity available for this product or its ingredients. Chemical Stability Stable under normal conditions. Possibility of hazardous reactions Under normal conditions of storage and use, hazardous reactions will not occur. Conditions to avoid Extremes of temperature and direct sunlight. Incompatible materials Reactive or incompatible with the following materials: Strong oxidizing agents Strong acids Aliphatic amines Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. Other hazards Reacts with considerable heat release with some curing agents. 11. Toxicological Information Acute Health Hazard (components) No comprehensive data is available on the product itself. Component Result Species Dose Exposure Diglycidyl Ether of Bisphenol A LD50 Oral Rat 11,400 mg/kg - LD50 Dermal Rat 2,000 mg/kg - Alkyl Glycidyl Ether LD50 Oral Rat 4,500 mg/kg - Diglycidyl Ether of Bisphenol F LD50 Oral Rat >2,000 mg/kg - LD50 Dermal Rat >2,000 mg/kg - Irritation/Corrosion (components) No data is available for this product. Component Result Species Test Exposure Diglycidyl Ether of Bisphenol A Moderate to severe irritation Rabbit Skin 4 h Mild irritation Rabbit Eye 24 h Diglycidyl Ether of Bisphenol F Mild irritant Rabbit Skin - Mild irritant Rabbit Eye Sensitization Mutagenicity Carcinogenicity Reproductive Toxicity Teratogenicity Specific target organ toxicity (single exposure) No data is available for this product. No data is available for this product. No data is available for this product. No data is available for this product. No data is available for this product. No data is available for this product. Component Category Route of exposure Target organs Diglycidyl Ether of Bisphenol A Category 3 Respiratory tract irritation Diglycidyl Ether of Bisphenol F Category 3 Respiratory tract irritation Specific target organ toxicity (repeated No data is available for this product. exposure) Aspiration hazard No data is available for this product. Potential acute health effects Eye Contact Causes serious eye irritation. Inhalation May cause respiratory irritation. Skin Contact Causes severe skin irritation. May cause an allergic skin reaction. Ingestion Irritating to mouth, throat, and stomach. Symptoms related to the physical, chemical and toxicological characteristics Eye Contact Adverse symptoms may include the following: Pain or irritation Watering Redness Inhalation Adverse symptoms may include the following: _ Respiratory tract irritation Coughing Skin Contact Adverse symptoms may include the following: Irritation Pain Redness Ingestion No specific data Delayed and immediate effects and also Not available. chronic effects from short and long term exposure Potential chronic health effects General Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. Carcinogenicity No known significant effects or critical hazards. Mutagenicity No known significant effects or critical hazards. Teratogenicity No known significant effects or critical hazards. Developmental effects No known significant effects or critical hazards. Fertility effects No known significant effects or critical hazards. Numerical measures of toxicity Acute toxicity estimates (ATEmix) 12. Ecological Information Ecotoxicity Not available. No information on the product itself. Component Test Species Result Exposure Diglycidyl Ether of Bisphenol A LC50 Fish 1.3 mg/I 96 h LC50 Daphnia 2.1 mg/I 48 h Diglycidyl Ether of Bisphenol F LC50 Fish 1.5 mg/I 96 h LC50 Daphnia 1.7 mg/I 48 h Chronic NOEC Daphnia 0.3 mg/I 21 d Persistence and degradability No information on the product itself. Component Test Period Result Diglycidyl Ether of Bisphenol A OECD 302E 28 d 12% Diglycidyl Ether of Bisphenol F OECD 301F Derived 28 d 5% Bioaccumulative Potential No information on the product itself. Component LogPow BCF Potential Diglycidyl Ether of Bisphenol A 2.64-3.78 3 — 31 Low Diglycidyl Ether of Bisphenol F 3.242 31 Low Alkyl glycidyl Ether 0.23 - Low Mobility in Soil Soil/water partition coefficient (KOC) Other adverse effects 13. Disoosal Considerations Waste from residues/ unused products Contaminated packaging 14.Transport Information No information on the product itself. No know significant effects or critical hazards. The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Product should not be allowed to enter drains, water courses or the soil; dispose of this material and its containers in a safe way. Contact supplier if guidance is required. Dispose of container and unused contents in accordance with federal, state and local requirements. The data provided in this section is for information only and may not be specific to your package size or mode of transport. You will need to apply the appropriate regulations to properly classify your shipment for transportation. International Transport Regulations Regulatory UN/NA number Proper Shipping Name Classes/*PG information DOT Non -regulated TDG Non -regulated IMO/IMDG UN3082 Environmentally Hazardous Substance, Class 9 III Liquid, N.O.S. (Bisphenol-A Epichlorohydrin Resin) IATA (Cargo) UN3082 Environmentally Hazardous Substance, Class 9 III Liquid, N.O.S. (Bisphenol-A Epichlorohydrin Resin) *PG: Packing group Special precautions for user: 15. Regulatory Information UNITED STATES Additional Information Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. U.S. Federal Regulations United States—TSCA 12(b) — Chemical export notification: None Required. United States — TSCA S(a)2 — Final significant new use rules: Not Listed. United States — TSCA 5(a)2 — Proposed significant new use rules: Not Listed. United States — TSCA 5(e) — Substance consent order: Not listed. California Prop. 65 WARNING: This product contains less than 0.1% of a chemical known to the State of California to cause cancer. WARNING: This product contains less than 1% of a chemical known to the State of California to cause birth defects or other reproductive harm. Ingredient Name Cancer Reproductive No significant risk level Maximum acceptable dosagelevel Oxirane, 2-(phenoxymethyl)- Yes No 5 µg/day No Oxirane, 2-(chloromethyl)- Yes Yes 9 µg/day No EPA SARA 302 Extremely Hazardous Substances EPA SARA 302/304/311/312 Hazardous Chemicals United States inventory (TSCA 8b) CANADA WHMIS (Canada) Canadian NPRI CEPA Toxic substances INTERNATIONAL REGULATIONS None required. Acute Health Hazard. All components are listed or exempted. Class D-26: Material causing other toxic effects (Toxic). None required. None required. International Lists Australia inventory (AILS): All components are listed or exempted. Canada inventory: All components are listed or exempted. Korea inventory: All components are listed or exempted. Japan inventory: All components are listed or exempted. China inventory (IECSC): All components are listed or exempted. New Zealand inventory (NZIoQ: All components are listed or exempted. Philippines inventory (PICCS): All components are listed or exempted. Taiwan inventory (CSNN): All components are listed or exempted. 16. Other Information, Includ Date of Preparation or Last Revision HMIs Rating Date of Preparation Date of Last Revision Revision # More Information Prepared by February 3, 2017 December 24, 2015 2.0 1-253-333-8118 N. Kim The information contained herein is based on the data available to us and is believed to be correct. However, System Three Resins, Inc. makes no warranty, expressed or implied, regarding the accuracy of these data or the results to be obtained from the use thereof. System Three assumes no responsibility for injury from the use of the product described herein. SYSTEMTHREEO 1. Product Identification SAFETY DATA SHEET Product name SilverTip® Coating and Laminating Resin SIDS Number 0900A Product type Epoxy polymer mixture. Recommended use of the chemical and Directed at, but not limited to, the laminating and coating of fiber restrictions on use composite and wood. Restrictions Manufacturer/Supplier information 2. Company name Address Telephone Website Email Emergency Contact Identification None known. SYSTEM THREE RESINS, INC. 3500 W. Valley Hwy, Suite Suite 105 Auburn, WA 98001-2436 United States 1-253-333-8118 www.systemthree.com support@systemthree.com CHEMTREC (U.S. and CANADA) 1-800-424-9300 CHEMTREC (Outside the U.S.) 1-703-527-0585 Classification of substance or WARNING mixture/Signal Word Skin Corrosion/Irritation - Category 2 Serious Eye Damage/Eye Irritation - Category 2 Skin Sensitization - Category 1 Specific Target Organ Toxicity (Single Exposure) [Respiratory tract irritation] — Category 3 GHS Label Elements Hazard Pictograms • Hazard Statements/Classification of H315 Causes skin irritation. substance or mixture H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H335 May cause respiratory irritation. Precautionary statements Precautionary Statements P201 Obtain special instructions before use. Prevention P202 Do not handle until all safety precautions have been read and understood. P264 Wash hands thoroughly after handling. P271 Use only outdoors or in a well -ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/protective clothing/eye protection/face protection. Response P304+340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P313 Call a POISON CENTER or doctor/physician if you feel unwell. P302+352+363 IF ON SKIN: Wash with soap and water. Take off contaminated clothing and wash before reuse. P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P308+ P313 If exposed or concerned: Get medical attention. Storage P401 Store at room temperature in a well -ventilated area. Disposal P501 Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified (HNOC) None Available. 3. Composition/Information On Ingredients Chemical Name CAS Number Content (%) Diglycidyl Ether of Bisphenol A 25068-38-6 70 — 80 Diglycidyl Ether of Bisphenol F 28064-14-4 5 —10% Benzyl Alcohol 100-51-6 5 —10 Alkyl Glycidyl Ether 17557-23-2 5 —10 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. 4. First -Aid Measures Skin contact Remove contaminated clothing and shoes and wipe excess off skin. Flush skin with water. Follow by washing in soap and water. If irritation occurs, seek medical attention. Do not reuse clothing until cleaned. Contaminated leather articles (shoes) cannot be decontaminated and should be destroyed. Eye contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Ingestion Do not induce vomiting unless directed to do so by medical personnel. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Inhalation Remove victim to fresh air and provide oxygen if breathing is difficult. Give artificial respiration if not breathing. Get medical attention. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments No specific treatment. -5. Fire -Fighting Measures Suitable extinguishing media Alcohol -resistant foam, carbon dioxide (CO2), dry chemical, water fog. Unsuitable extinguishing media None known. Specific hazards arising from the chemical In a fire or if heated, a pressure increase will occur and the container may burst. This material is toxic to aquatic life with long lasting effects. Fire water contaminated must be contained and prevented from being discharged to any waterway, sewer or drain. Hazardous decomposition products Decomposition products may include the following materials: Carbon dioxide Carbon monoxide Special protective actions for fire-fighters Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective equipment for fire- Fire-fighters should wear appropriate protective equipment and self-contained fighters breathing apparatus (SCBA) with a full face -piece operated in positive pressure mode. Further information Do not allow run-off from firefighting to enter drains or water courses. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. 6. Accidental Release Measures Personal precautions Wear proper personal protective equipment (PPE). Avoid direct contact with material.Proper PPE includes: disposable gloves, eye protection and skin protection. Emergency procedures If material is spilled, avoid contact with material. Persons not wearing appropriate protective equipment should leave the area of the spill until cleanup is complete. Methods and materials for Stop leak if without risk. Move containers from spill area. Approach release containment/cleanup from upwind. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage. 7. Handling and Storage Precautions for safe handling Avoid contact with skin and eyes. Emergency showers and eye wash stations should be readily accessible. Adhere to work practice rules established by government regulations. Use personal protective equipment. When using, do not eat, drink or smoke. Precautions/Recommendations for Store epoxy products in temperature stable environment, out of the reach of safe/proper storage pets or children. Securely fasten container lids and tops, and prevent products from sitting and below freezing temperatures. 8. Exposure Controls/Personal Protection Occupational Exposure Limits Not established. Appropriate engineering controls Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Environmental exposure controls Use appropriate containment to avoid environmental contamination. Do not allow spill to enter sewers or waterways. Individual protection measures/Personal protective equipment Eye/face protection Splash -proof goggles or safety spectacles with side shields are recommended. Always wear eye protection when sanding cured epoxy resins to avoid dust in eyes. Hand protection Always wear impervious gloves: butyl rubber, nitrile rubber, Neoprene, PVC disposable gloves, Skin protection Wear clean, body -covering clothing to avoid skin contact. Respiratory protection Use a properly fitted, air -purifying or air -fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Special instructions for protection and Wear gloves at all times when handling product, avoid direct contact with skin. hygiene When finished using product, dispose of gloves properly and wash hands with warm, soapy water. 9. Physical and Chemical Chemical family Appearance Physical State Form Color Odor Density (Specific Gravity) Viscosity PH Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Epoxy Resin Clear liquid Epoxy polymer mixture Liquid Water clear Mild 9.47 Ib/gal(1.1-1.3) 700 cps @ 25°C Not available Not available Not available >300'F, Pensky-Martens Closed Cup Slower than ether Flammability (solid, gas) Not available Upper/lower flammability limit (by volume) Not available Material VOC Vapor density None Heavier than air Relative density Not determined Solubility in water Negligible, in water Partition coefficient: n-octanol/water 3 Auto -ignition temperature 300°C (572.00°F) Decomposition temperature Not available and Reactivity Reactivity No specific test data related to reactivity available for this product. Chemical Stability Stable under normal conditions. Possibility of hazardous reactions Hazardous polymerization will not occur. Conditions to avoid Epoxy resins and epoxy resin hardeners react with each other producing heat. They should not be mixed with each other under uncontrolled conditions or in large mass as the ensuing exotherm may result in heat and smoke, resulting in hazardous decomposition products. Incompatible materials Strong oxidizing and reducing agents. Lewis and mineral acids. Hazardous decomposition products Oxides of carbon, aldehydes, and acids. Other hazards None known. 11. Toxicological Information Acute Health Hazard (components) No comprehensive data (ingestion, inhalation, dermal) on mixture (product). Component Result Species Dose Exposure Diglycidyl Ether of Bisphenol A LD50 Oral Rat 11,400 mg/kg - LD50 Dermal Rat 2,000 mg/kg - Diglycidyl Ether of Bisphenol F LD50 Oral Rat >2,000 mg/kg - LD50 Dermal Rat >2,000 mg/kg - Alkyl Glycidyl Ether LD50 Oral Rat 4,500 mg/kg - LD50 Dermal Rabbit >2,000 mg/kg - Benzyl Alcohol LD50 Oral Rat 1620 mg/kg - LC50 Inhalation Rat >4178 mg/m3 4 h, aerosol Irritation/Corrosion (components) No information on product itself. Component Result Species Test Exposure Diglycidyl Ether of Bisphenol A Moderate to severe irritation Rabbit Skin 4 h Mild irritation Rabbit Eye 24 h Diglycidyl Ether of Bisphenol F Mild irritant Rabbit Skin - Mild irritant Rabbit Eye - Benzyl Alcohol Irritant Rabbit Eye Sensitization Mutagenicity No information on product itself. No information on product itself. Carcinogenicity No information on product itself. Reproductive Toxicity No information on product itself. Teratogenicity Specific target organ toxicity (single exposure) No information on product itself. No information on product itself. Component Category Route of exposure Target organs Diglycidyl Ether of Bisphenol A Category 3 Respiratory tract irritation Diglycidyl Ether of Bisphenol F Category 3 Respiratory tract irritation Alkyl Glycidyl Ether Category 3 Respiratory tract irritation Specific target organ toxicity (repeated No information on product itself. exposure) Aspiration hazard No information on product itself. Potential acute health effects Eye Contact Causes serious eye irritation. Inhalation May cause respiratory irritation. Skin Contact Causes skin irritation. May cause an allergic skin reaction. Ingestion Irritating to mouth, throat and stomach. Symptoms related to the physical, chemical and toxicological characteristics Eye Contact Adverse symptoms may include the following: Pain Watering Redness Inhalation Adverse symptoms may include the following: Respiratory tract irritation Coughing Skin Contact Adverse symptoms may include the following: Irritation Redness Ingestion No specific data. Delayed and immediate effects and also chronic effects from short and long term exposure Potential chronic health effects General Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. Carcinogenicity No known significant effects or critical hazards. Mutagenicity No known significant effects or critical hazards. Teratogenicity No known significant effects or critical hazards. Developmental effects No known significant effects or critical hazards. Fertility effects No known significant effects or critical hazards. Numerical measures of toxicity Acute toxicity estimates(ATEmix) Not available 12. I Information Ecotoxicity No information on product itself. Component Result Species Exposure Diglycidyl Ether of Bisphenol A Acute LC50 1.3 mg/I Fish 96 h Acute LC50 2.1 mg/I Daphnia 48 h Diglycidyl Ether of Bisphenol F Acute LC50 1.5 mg/I Fish 96 h Acute LC50 1.7 mg/I Daphnia 48 h Chronic NOEC 0.3 mg/I Daphnia 21 d Benzyl Alcohol Acute LC50 460 mg/I Fish 96 h Acute EC50 230 mg/I Invertebrates 48 h Chronic NOEL 310 mg/I Algae 72 h Persistence and degradability eioaccumulative Potential No information on product itself. No information on product itself. Component LogPow BCF Potential Diglycidyl Ether of Bisphenol A 2.64 — 3.78 3 — 3131.00 low Diglycidyl Ether of Bisphenol F 3 - low Benzyl Alcohol 1.05 1.37 (calculated) Mobility in Soil Soil/water partition coefficient (KOC) No information on product itself. Other adverse effects No known significant effects or critical hazards. 13. Disposal Considerations Waste from residues/ unused products The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Product should not be allowed to enter drains, water courses or the soil; dispose of this material and its containers in a safe way. Contact supplier if guidance is required. Contaminated packaging Dispose of container and unused contents in accordance with federal, state and local requirements. 14.Transport Information The data provided in this section is for information only and may not be specific to your package size or mode of transport. You will need to apply the appropriate regulations to properly classify your shipment for transportation. International Transport Regulations Regulatory UN/NA number Proper Shipping Name Classes/'PG Additional information Information DOT Non -regulated TDG Non -regulated IMO/IMDG UN3082 Environmentally hazardous substance, Class 9 III liquid, n.c.s. (Bisphenol-A Epichlorohydrin Resin) IATA (Cargo) UN3082 Environmentally hazardous substance, Class 9 111 liquid, n.o.s. (Bisphenol-A Epichlorohydrin Resin) *PG: Packing group Special precautions for user: Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. 15. Regulatory Information UNITED STATES U.S. Federal Regulations United States—TSCA 12(b) — Chemical export notification: None Required. United States — TSCA 5(a)2 — Final significant new use rules: Not Listed. United States — TSCA 5(a)2 — Proposed significant new use rules: Not Listed. United States—TSCA 5(e) —Substance consent order: Not listed. Clean Air Act— Ozone Depleting This product does not contain nor is it manufactured with ozone depleting Substances (ODS) substances. . Clean Air Act Section 112(b) Hazardous None Air Pollutants (HAPs) California Prop. 65 WARNING: This product contains less than 0.1%of a chemical known to the State of California to cause cancer. WARNING: This product contains less than 1% of a chemical known to the State of California to cause birth defects or other reproductive harm. Ingredient Name Cancer Reproductive No significant risk level Maximum acceptable dosagelevel Oxirane, 2-(phenoxymethyl)- Yes No 5 jig/day No Oxirane, 2-(chloromethyl)- Yes Yes 9 µg/day No EPA SARA 302 Extremely Hazardous Substances EPA SARA 302/304/311/312 Hazardous Chemicals SARA 313 Form R — Reporting requirements United States inventory (TSCA 8b) CANADA WHMIS (Canada) Canadian NPRI CEPA Toxic substances INTERNATIONAL REGULATIONS None required Acute Health Hazard None required All components are listed or exempted. Class D-213: Material causing other toxic effects (Toxic). None required None required International Lists Australia inventory (AILS): All components are listed or exempted. Canada inventory: All components are listed or exempted. Korea inventory: All components are listed or exempted. Japan inventory: All components are listed or exempted. China inventory (IECSC): All components are listed or exempted. New Zealand inventory (NZIoC): All components are listed or exempted. Philippines inventory (PICCS): All components are listed or exempted. Taiwan inventory (CSNN): All components are listed or exempted. 16. Other Information, Including Date of Preparation or Last Revision HMIS Rating Date of Preparation Date of Last Revision Revision # More Information Prepared by May 18, 2018 June 12, 2017 3.0 1-253-333-8118 N. Kim, System Three Resins Inc. The information contained herein is based on the data available to us and is believed to be correct. However, System Three Resins, Inc. makes no warranty, expressed or implied, regarding the accuracy of these data or the results to be obtained from the use thereof. System Three assumes no responsibility for injury from the use of the product described herein. SAFETY DATA SHEET 1. Product Identification Product name SilverTip Fast Hardener, Part B SIDS Number 0900B Product type Amine curing agent. Recommended use of the chemical and Directed at, but not limited to, the laminating and coating of composite restrictions on use materials, wood, and inorganic substrates. Restrictions Manufacturer/Supplier information Company name Address Telephone Website Email Emergency Contact 2. Hazard(s) Identification None known. SYSTEM THREE RESINS, INC. 3500 W. Valley Hwy, Suite Suite 105 Auburn, WA 98001-2436 United States 1-253-333-8118 www.systemthree.com support-08@systemthree.com CHEMTREC (U.S. and CANADA) 1-800-424-9300 CHEMTREC (Outside the U.S.) 1-703-527-0585 Classification of substance or DANGER mixture/Signal Word Acute Toxicity: Oral — Category 4 Acute Toxicity: Inhalation — Category 4 Skin Corrosion/Irritation — Category 1 Serious Eye Damage/Eye Irritation —Category 1 Skin Sensitization — Category 1 Reproductive Toxicity— Category 1 Specific Target Organ Toxicity (Single Exposure) [Respiratory tract irritation] — Category 3' Aquatic Hazard (Acute) —Category 1 Aquatic Hazard (Long-term) —Category 1 GHS Label Elements Hazard Pictograms <p� Hazard Statements/Classification of H302 Harmful if swallowed. substance or mixture H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H332 Harmful if inhaled. H335 May cause respiratory irritation. H360 May damage fertility or the unborn child. H400 Very toxic to aquatic life H410 Very toxic to aquatic life with long lasting effects. Precautionary statements Precautionary Statements Prevention P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P261 Avoid breathing vapor. P264 Wash hands thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well -ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves. Wear eye or face protection. Response P301+ P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361+ 13353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+ P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P362+ P364 Take off contaminated clothing and wash it before reuse. Storage P405 Store locked up. Disposal P501 Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified (HNOC) None known. 3. Composition/Information On Ingredients Chemical Name CAS Number Content (%) Isophorone Diamine 2855-13-2 60 — 70% p-tert-Butylphenol 98-54-4 5 —10% Benzyl Alcohol 100-51-6 15 — 20% 1,3-benzenedi methana mine 1477-55-0 5 —10% Nonyl Phenol 84852-15-3 5 —10% There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. 4. First -Aid Measures Skin contact Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. Chemical burns must be treated promptly by a physician. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Eye contact Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove contact lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. Ingestion Do not induce vomiting without medical advice. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Prevent aspiration of vomit. Never give anything by mouth to an unconscious person. Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored for at least 48 hours. Specific treatments No specific treatment. S. Fire -Fighting Measures. Suitable extinguishing media Alcohol -resistant foam, carbon dioxide (COz), dry chemical, water fog. Unsuitable extinguishing media None known. Specific hazards arising from the chemical In a fire or if heated, a pressure increase will occur and the container may burst. This material is toxic to aquatic life with long lasting effects. Fire water contaminated must be contained and prevented from being discharged to any waterway, sewer or drain. Hazardous decomposition products Decomposition products may include the following materials: Carbon dioxide Carbon monoxide Special protective actions for fire-fighters Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective equipment for fire- Fire-fighters should wear appropriate protective equipment and self-contained fighters breathing apparatus (SCBA) with a full face -piece operated in positive pressure mode. Further information Do not allow run-off from firefighting to enter drains or water courses. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. 6. Accidental Release Measures Personal precautions No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Wear proper protective clothing, gloves and eye/face protection. Emergency procedures If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. Methods and materials for Stop leak if without risk. Move containers from spill area. Approach release containment/cleanup from upwind. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). 7. Handling and Storage Precautions for safe handling Put on appropriate personal protective equipment. Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid contact with skin and eyes. Emergency showers and eye wash stations should be readily accessible. When using, do not eat, drink or smoke. Precautions/Recommendations for Store in accordance with local regulations. Store in original container protected safe/proper storage from direct sunlight in a dry, cool and well -ventilated area, away from incompatible materials and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. 8. Exposure Controls/Personal Protection Occupational Exposure Limits None established. Appropriate engineering controls Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Environmental exposure controls Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Do not allow spill to enter sewers or waterways. Individual protection measures/Personal protective equipment Eye/face protection Splash -proof goggles or safety spectacles with side shields are recommended. Always wear eye protection when sanding cured epoxy resins to avoid dust in eyes. Hand protection Always wear impervious gloves: butyl rubber, nitrile rubber, Neoprene, PVC disposable gloves. Skin protection Wear clean, body -covering clothing to avoid skin contact. Respiratory protection Use a properly fitted, air -purifying or air -fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Special instructions for protection and Discard contaminated leather articles. Remove contaminated clothing. Wash at hygiene the end of each work shift and before eating smoking or using the toilet. Provide readily accessible eye wash stations and safety showers. 9. Physical and Chemical Properties Chemical family Amine curing agent Appearance Clear liquid Physical State Amine mixture Form Liquid Color Colorless Odor Ammoniacal Density (Specific Gravity) 0.9 —1.0 Viscosity 525 CPS @77°F (25°C) pH N/A Melting point/freezing point N/A Initial boiling point and boiling range N/A Flash point N/A Evaporation rate Slower than ether Flammability (solid, gas) N/A Upper/lower flammability limit (by volume) N/A Material VOC None Vapor density Heavier than air Relative density N/A Solubility in water Negligible Partition coefficient: n-octanol/water N/A Auto -ignition temperature N/A Decomposition temperature N/A and Reactivity Reactivity None. Chemical Stability Stable under normal conditions. Possibility of hazardous reactions Under normal conditions of storage and use, hazardous reactions will not occur. Conditions to avoid Do not freeze. Avoid exposure to air, moisture, ignition sources and elevated temperatures. Incompatible materials Reactive or incompatible with the following materials: Organic acids Mineral acids Sodium hypochlorite Oxidizing agents Hazardous decomposition products Carbon monoxide Carbon dioxide Nitrogen oxides Other hazards None known. 11. Toxicological Information Acute Health Hazard (components) No comprehensive data (ingestion, inhalation, dermal) on mixture (product). Component Result Species Dose Exposure Isophorone Diamine LD50 Oral Rat 1,030 mg/kg - LD50 Dermal Rat >2,000 mg/kg - LC50 Inhalation Rat >5.01 mg/I 4 h Nonyl Phenol LD50 Dermal Rabbit 2,031 mg/kg - LD50 Oral Rat 1,412 mg/kg Benzyl Alcohol LD50 Oral Rat 1,620 mg/kg - LC50Inhalation Rat >4,178 mg/kg 4 h, aerosol 2-Methyl-1,5- pentamethylenediamine LD50 Dermal Rabbit 1870 mg/kg - LD50 Oral Rat 1170 mg/kg - LC50Inhalation Rat 4.9 mg/I/1h - Para- tertiary-butylphenol LD50 Dermal Rabbit 2,520 mg/kg - LD50 Oral Rat 5,660 mg/kg - 1,3-Benzenedimethanamine LD50 Dermal Rabbit 2,000 mg/kg - LD50 Oral Rat 930 mg/kg - Irritation/Corrosion (components) Classifies as corrosive per positive GHS calculation on additivity. Component Result Species Test Exposure Isophorone Diamine Skin — Corrosive Rabbit OECD 404 Acute Dermal Irritation/Corrosion - Eyes — Corrosive Rabbit OECD 405 Acute Eye Irritation/Corrosion - Benzyl Alcohol Eye — Irritant Rabbit OECD 405 Acute Eye Irritation/Corrosion - Para-tertiary-butylphenol Irritation Skin Serious eye irritation Eye Sensitization Mutagenicity Carcinogenicity Reproductive ToxicitV Teratogenicity Specific target organ toxicity (single exposure) No data is available on the product itself. No data is available on the product itself. No data is available on the product itself. No data is available on the product itself. No data is available on the product itself. No data is available on the product itself. Component Category Route of exposure Target organs 2-Methyl-1,5- pentamethylenediami ne Category 3 Respiratory tract irritation Specific target organ toxicity (repeated exposure) Aspiration hazard No data is available on the product itself. No data is available on the product itself. Potential acute health effects Eye Contact Causes serious eye damage. Inhalation May cause respiratory irritation. Skin Contact Causes severe burns. Harmful in contact with skin. May cause an allergic skin reaction. Ingestion Harmful if swallowed. May cause burns to mouth, throat and stomach. Symptoms related to the physical, chemical and toxicological characteristics Eye Contact Adverse symptoms may include the following: Pain or irritation Watering Redness Inhalation Adverse symptoms may include the following: Respiratory tract irritation Coughing Skin Contact Adverse symptoms may include the following: Pain or irritation Redness Blistering may occur Ingestion Adverse symptoms may include the following: Stomach pains Delaved and immediate effects and also chronic effects from short and long term exposure Potential chronic health effects General Carcinogenicity Mutagenicity Teratogenicity Developmental effects Fertility effects Numericalmeasures of toxicity Acute toxicity estimates (ATEmix) No data is available on the product itself. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. Route ATE value Oral 1614.6 mg/kg Dermal 3194.6 mg/kg Inhalation (vapors) 13.75 mg/I 12. Ecological Information Ecotoxicity No data is available on the product itself. Component Endpoint Exposure Species Result Isophorone Diamine Acute LC50 96 h Fish 110 mg/I Acute EC50 48 h Daphnia magna 23 mg/I Acute EC50 72 h Scenedesmus subspicatus >50 mg/I Nonyl Phenol Acute EC50 3 h Static Bacteria 950 mg/I Acute EC50 48 h Static Daphnia 0.085 mg/I Acute LC50 96 h Static Fish 0.05 mg/I Benzyl Alcohol Acute LC50 96 h Fish 460 mg/I Acute EC50 48 h Invertebrates 230 mg/l Chronic NOEC 21 d Invertebrates 51 mg/I Acute EC50 72 h Algae 770 mg/I Chronic NOEC 72 h Algae 310 mg/I 2-Methyl-1,5- penta methylenediamine Acute EC50 72 h Algae >100 mg/I Acute EC50 48 h Daphnia 19.8 mg/I - Fish 1825 mg/I Para-tertiary-butylphenol LC50 96 h Fish 5.14 mg/I EC50 48 h Daphnia magna 4.8 mg/I 1,3-Benzenedimethanamine LC50 OECD 203 96 h Fish 87.6 mg/I EC50 OECD 202 48 h Daphnia magna 15.2 mg/I NOEC OECD 211 21 d Daphnia magna 4.7 mg/I Persistence and deeradability No data is available on the product itself. Component Test Period Result Nonyl Phenol OECD 301E Ready Biodegradability—CO2 Evolution Test 35 days 48.2% Benzyl Alcohol - Readily biodegradable 1,3-Benzenedimethanamine OECD 301B 28 d 49% Bioaccumulative Potential No data is available on the product itself. Component LogPow BCF Potential Nonyl Phenol 5.4 740 High Benzyl Alcohol 1.05 1.37 (calculated) - Para-tertiary-butylphenol 3.31 - - 1,3-Benzenedimethanamine - 3.161/kg (calculated) Mobility in Soil Soil/water partition coefficient (KOC) Other adverse effects 13. Disposal Considerations Waste from residues/ unused products No data is available on the product itself. No data is available on the product itself. No known significant effects or critical hazards. The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Product should not be allowed to enter drains, water courses or the soil; dispose of this material and its containers in a safe way. Contact supplier if guidance is required. Contaminated packaging Dispose of container and unused contents in accordance with federal, state and local requirements. 14.Transvort Information The data provided in this section is for information only and may not be specific to your package size or mode of transport. You will need to apply the appropriate regulations to properly classify your shipment for transportation. International Transport Regulations Regulatory UN/NA number Proper Shipping Name Classes/*PG Additional information Information DOT UN2735 Amines, liquid, corrosive, n.o.s. Class 8 III Marine pollutant (Isophorone diamine, para-tert- butylphenol) TDG UN2735 Amines, liquid, corrosive, n.o.s. Class 811I Marine pollutant (Isophorone diamine, para-tert- butylphenol) IMO/IMDG UN2735 Amines, liquid, corrosive, n.o.s. Class 8111 Marine pollutant (Isophorone diamine, para-tert- butylphenol) IATA (Cargo) UN2735 Amines, liquid, corrosive, n.o.s. Class 8111 (Isophorone diamine, para-tert- butylphenol) *PG: Packing group Special precautions for user: Transport within users premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. 15. Regulatory Information UNITED STATES U.S. Federal Regulations United States—TSCA 12(b) —Chemical export notification: None Required. United States —TSCA 5(a)2 — Final significant new use rules: Not Listed. United States —TSCA 5(a)2 — Proposed significant new use rules: Not Listed. United States —TSCA 5(e) — Substance consent order: Not listed. Clean Air Act —Ozone Depleting This product does not contain nor is it manufactured with ozone depleting Substances (ODS) substances. Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs) Pennsylvania — RTK California Prop. 65 EPA SARA 302 Extremely Hazardous Product Name Concentration % Phenol 0 —1% Phenol, 4-tert-Butylphenol This product does not contain any chemicals known to the state of California to cause cancer, birth defects or any other harm. None required. Substances EPA SARA 302/304/311/312 Hazardous Acute Health Hazard, Chronic Health Hazard Chemicals SARA 313 Form R — Reporting requirements CERCLA Hazardous substances Product Name Concentration Phenol 0-1% Component % Section 304 CERCLA 1 CERCLA Reportable Product Reportable United States inventory (TSCA 8b) CANADA WHMIS (Canada) Canadian NPRI CEPA Toxic substances INTERNATIONAL REGULATIONS International Lists Hazardous Substance Quantity (Lbs) Quantity (Lbs) Phenol 1 Listed All components are listed or exempted. Class D-28: Material causing other toxic effects (Toxic). Class E: Corrosive material. None required. None required. Australia inventory (AILS): All components are listed or exempted. Canada inventory: All components are listed or exempted. Korea inventory: All components are listed or exempted. Japan inventory: All components are listed or exempted. China inventory (IECSC): All components are listed or exempted. New Zealand inventory (NZIoC): All components are listed or exempted. Philippines inventory (PICCS): All components are listed or exempted. Taiwan inventory (CSNN): All components are listed or exempted. 16. Other Information, Including Date of Preparation or Last Revision HMIS Rating Date of Preparation Date of Last Revision Revision # More Information Prepared by June 13, 2017 January 13, 2016 2.0 1-253-333-8118 N. Kim, System Three Resins Inc. The information contained herein is based on the data available to us and is believed to be correct. However, System Three Resins, Inc. makes no warranty, expressed or implied, regarding the accuracy of these data or the results to be obtained from the use thereof. System Three assumes no responsibility for injury from the use of the product described herein. MTEMTHREF 1. Product Identification SAFETY DATA SHEET Product name SilverTip Slow Hardener, Part B SDS Number 0901B00 Producttype Amine curing agent. Recommended use of the chemical and Directed at, but not limited to, the laminating and coating of composite restrictions on use materials, wood, and inorganic substrates. Restrictions Manufacturer/Supplier information 2. Company name Address Telephone Website Email Emergency Contact Identification None known. SYSTEM THREE RESINS, INC. 3500 W. Valley Hwy, Suite Suite 105 Auburn, WA98001-2436 United States 1-253-333-8118 www.systemthree.com support-08@systemthree.com CHEMTREC (U.S. and CANADA) 1-800-424-9300 CHEMTREC (Outside the U.S.) 1-703-527-0585 Classification of substance or DANGER mixture/Signal Word Acute Toxicity: Oral — Category 4 Skin Corrosion/I rritation —Category 1 Serious Eye Damage/Eye Irritation —Category 1 Skin Sensitization —Category 1 Specific Target Organ Toxicity (Single Exposure) — Category 3 Aquatic Hazard (Acute) —Category 3 Aquatic Hazard (Long-term) — Category 3 GHS Label Elements Hazard Pictograms • Hazard Statements/Classification of H302 Harmful if swallowed. substance or mixture H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H335 May cause respiratory irritation. H402 Harmful to aquatic life. H412 Harmful to aquatic life with long lasting effects. Precautionary statements Precautionary Statements Prevention P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P261 Avoid breathing Vapor. P264 Wash hands thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well -ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves. Wear eye or face protection. Response P301+ P330 +P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+ P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician. P362 + P364 Take off contaminated clothing and wash it before reuse. Storage P405 Store locked up. Disposal P501 Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified (HNOC) None known. 3. Composition/Information On Ingredients Chemical Name CAS Number Content (%) Aliphatic Amine Mixture Trade Secret 70-80% Alkyl Phenol Mixture Trade Secret 15-20% Benzyl Alcohol 100-51-6 15 —15 % There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. 4. First -Aid Measures Skin contact Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. Chemical burns must be treated promptly by a physician. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Eye contact Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove contact lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. Ingestion Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting without medical advice. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain open airway. Loosed tight clothing such as a collar, tie, belt, or waistband. Inhalation Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain open airway. Loosen tight clothing such as a collar, tie, belt, or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored for at least 48 hours. Specific treatments No specific treatment. 5. Fire -Fighting Measures Suitable extinguishing media Alcohol -resistant foam, carbon dioxide (CO2), dry chemical, water fog. Unsuitable extinguishing media None known. Specific hazards arising from the chemical In a fire or if heated, a pressure increase will occur and the container may burst. This material is toxic to aquatic life with long lasting effects. Fire water contaminated must be contained and prevented from being discharged to any waterway, sewer or drain. Hazardous decomposition products Decomposition products may include the following materials: Carbon dioxide Carbon monoxide Special protective actions for fire-fighters Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective equipment for fire- Fire-fighters should wear appropriate protective equipment and self-contained fighters breathing apparatus (SCBA) with a full face -piece operated in positive pressure mode. Further information Do not allow run-off from firefighting to enter drains or water courses. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. 6. Accidental Release Measures Personal precautions No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Wear proper protective clothing, gloves and eye/face protection. Emergency procedures If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. Methods and materials for Stop leak if without risk. Move containers from spill area. Approach release containment/cleanup from upwind. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with non-combustible, absorbent material e.g, sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). 7. Handling and Storage Precautions for safe handling Put on appropriate personal protective equipment. Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid contact with skin and eyes. Do not ingest. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. When using, do not eat, drink or smoke. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Precautions/Recommendations for Store in accordance with local regulations. Store in original container protected safe/proper storage from direct sunlight in a dry, cool and well -ventilated area, away from incompatible materials and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. 8. Exposure Controls/Personal Protection Occupational Exposure Limits None established. Appropriate engineering controls Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Environmental exposure controls Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Do not allow spill to enter sewers or waterways. Individual protection measures/Personal protective equipment Eye/face protection Splash -proof goggles or safety spectacles with side shields are recommended. Always wear eye protection when sanding cured epoxy resins to avoid dust in eyes. Hand protection Always wear impervious gloves: butyl rubber, nitrile rubber, Neoprene, PVC disposable gloves. Skin protection Wear clean, body -covering clothing to avoid skin contact. Respiratory protection Use a properly fitted, air -purifying or air -fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Special instructions for protection and Discard contaminated leather articles. Remove contaminated clothing. Wash at hygiene the end of each work shift and before eating smoking or using the toilet. Provide readily accessible eye wash stations and safety showers. 9. Physical and Chemical Properties Chemical family Amine curing agent Appearance Clear liquid Physical State Amine mixture Form Liquid Color Colorless Odor Ammoniacal Density (Specific Gravity) 0.9 —1.0 Viscosity 525 CPS @77-F (25-C) PH N/A Melting point/freezing point N/A Initial boiling point and boiling range N/A Flash point N/A Evaporation rate Slower than ether Flammability (solid, gas) N/A Upper/lower flammability limit (by volume) N/A Upper flammability limit (by volume) N/A Lower flammability limit (by volume) N/A Material VOC None Vapor density Heavier than air Relative density N/A Solubility in water Negligible Partition coefficient: n-octanol/water N/A Auto -ignition temperature N/A Decomposition temperature N/A 10.Stability and Reactivity Reactivity None. Chemical Stability Stable under normal conditions Possibility of hazardous reactions Under normal conditions of storage and use, hazardous reactions will not occur. Conditions to avoid Do not freeze. Avoid exposure to air, moisture, ignition sources and elevated temperatures. Incompatible materials Reactive or incompatible with the following materials: Organic acids Strong acids Halogenated compounds Hazardous decomposition products Carbon monoxide Carbon dioxide Nitrogen oxides Other hazards None known. 11. Toxicological Information Acute Health Hazard (components) No comprehensive data (ingestion, inhalation, dermal) on mixture (product). Component Result Species Dose Exposure Benzyl Alcohol LD50 Oral Rat 1,620 mg/kg - LC50 Inhalation Rat >4,178 mg/kg 4 h, aerosol Irritation/Corrosion (components) Classifies as corrosive per positive GHS calculation on additivity. Component Result Species Test Exposure Benzyl Alcohol Eye— Irritant Rabbit OECD 405 Acute Eye Irritation/Corrosion Aliphatic Amine Mixture Corrosive Calculated Sensitization No data is available on the product itself. Mutagenicity No data is available on the product itself. Carcinogenicity No data is available on the product itself. Reproductive Toxicity No data is available on the product itself. Teratooenicity No data is available on the product itself. Specific target organ toxicity (single No data is available on the product itself. exposure) Specific target organ toxicity (repeated No data is available on the product itself. exposure) Aspiration hazard No data is available on the product itself. Potential acute health effects Eye Contact Causes serious eye damage. Inhalation May cause respiratory irritation. Skin Contact Causes severe burns. Harmful in contact with skin. May cause an allergic skin reaction. Ingestion Harmful if swallowed. May cause burns to mouth, throat and stomach. Svmotoms related to the ohvs(cal. chemical and toxicological characteristics Eye Contact Adverse symptoms may include the following: Pain or irritation Watering Redness Inhalation Adverse symptoms may include the following: Respiratory tract irritation Coughing Skin Contact Adverse symptoms may include the following: Pain or irritation Redness Blistering may occur Ingestion Delayed and immediate effects and also chronic effects from short and lone term exposure Potential chronic health effects General Carcinogenicity Mutagenicity Teratogenicity Developmental effects Fertility effects Numerical measures of toxicity Acute toxicity estimates (ATEmix) Adverse symptoms may include the following: Stomach pains No data is available on the product itself. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. Route ATE value Oral 1918.8 mg/kg Dermal 3211.1 mg/kg Inhalation (vapors) N/A 12. Ecological Information Ecotoxicity No data is available on the product itself. Component Endpoint Exposure Species Result Benzyl Alcohol Acute LC50 96 h Fish 460 mg/I Acute EC50 48 h Invertebrates 230 mg/I Chronic NOEC 21 d Invertebrates 51 mg/I Acute EC50 72 h Algae 770 mg/I Chronic NOEC 72 h Algae 310 mg/I Persistence and degradability No data is available on the product itself. Component Test Period Result Benzyl Alcohol Readily biodegradable Bioaccumulative Potential No data is available on the product itself. Component LogPow BCF Potential Benzyl Alcohol 1.05 1.37 (calculated) Mobility in Soil Soil/water partition coefficient (KOC) Other adverse effects No data is available on the product itself. No data is available on the product itself. No known significant effects or critical hazards. 13. Disposal Considerations Waste from residues/ unused products The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Product should not be allowed to enter drains, water courses or the soil; dispose of this material and its containers in a safe way. Contact supplier if guidance is required. Contaminated packaging Dispose of container and unused contents in accordance with federal, state and local requirements. 14.Transport Information The data provided in this section is for information only and may not be specific to your package size or mode of transport. You will need to apply the appropriate regulations to properly classify your shipment for transportation. International Transport Regulations Regulatory - UN/NA number Proper Shipping Name Classes/*PG Additional information Information DOT UN2735 Amines, liquid, corrosive, n.o.s. Class 8 III Marine pollutant (Isophorone diamine, para-tert- butylphenol) TOG UN2735 Amines, liquid, corrosive, n.o.s. Class 8 III Marine pollutant (Isophorone diamine, para-tert- butylphenol) IMO/IMDG UN2735 Amines, liquid, corrosive, n.o.s. Class 8 III Marine pollutant (Isophorone diamine, para-tert- butylphenol) IATA (Cargo) UN2735 Amines, liquid, corrosive, n.o.s. Class 8 III (Isophorone diamine, para-tert- butylphenol) *PG: Packing group Special precautions for user: Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. 15. Regulatory Information UNITED STATES U.S. Federal Regulations United States —TSCA 12(b) —Chemical export notification: None Required. United States —TSCA 5(a)2 — Final significant new use rules: Not Listed. United States —TSCA 5(a)2 — Proposed significant new use rules: Not Listed. United States — TSCA 5(e) — Substance consent order: Not listed. Clean Air Act —Ozone Depleting This product does not contain nor is it manufactured with ozone depleting Substances (ODS) substances. Clean Air Act Section 112(b) Hazardous None known. Air Pollutants (HAPs) California Prop. 65 This product does not contain any chemicals known to the state of California to cause cancer, birth defects or any other harm. EPA SARA 302 Extremely Hazardous None known. Substances EPA SARA 302/304/311/312 Hazardous Acute Health Hazard Chemicals United States inventory (TSCA 8b) All components are listed or exempted. CANADA WHMIS (Canada) Class D-28: Material causing other toxic effects (Toxic). Class E: Corrosive material. Canadian NPRI None required. CEPA Toxic substances None required. INTERNATIONAL REGULATIONS International Lists Australia inventory (AICS): All components are listed or exempted. Canada inventory: All components are listed or exempted. Korea inventory: All components are listed or exempted. Japan inventory: All components are listed or exempted. China inventory (IECSC): All components are listed or exempted. New Zealand inventory (NZIoC): All components are listed or exempted. Philippines inventory (PICCS): All components are listed or exempted. Taiwan inventory (CSNN): All components are listed or exempted. 16. Other Information, Including Date of Preparation or Last Revision HMIS Rating Date of Preparation Date of Last Revision Revision # More Information Prepared by February 17, 2017 March 26, 2015 2.0 1-253-333-8118 N. Kim, System Three Resins Inc. The information contained herein is based on the data available to us and is believed to be correct. However, System Three Resins, Inc. makes no warranty, expressed or implied, regarding the accuracy of these data or the results to be obtained from the use thereof. System Three assumes no responsibility for injury from the use of the product described herein. SAFETY DATA SHEET 1. Product Identification Product name SilverTip Yacht Primer, Part A SDS Number 1710A00 Producttype Epoxy Resin Mixture Recommended use of the chemical and Paint primer for marine use. restrictions on use Restrictions None known. Manufacturer/Supplier information Company name SYSTEM THREE RESINS, INC. Address 3500 W. Valley Hwy, Suite Suite 105 Auburn, WA 98001-2436 United States Telephone 1-253-333-8118 Website www.systemthree.com Email support@systemthree.com Emergency Contact CHEMTREC (U.S. and CANADA) 1-800-424-9300 CHEMTREC (Outside the U.S.) 1-703-527-0585 2. Hazard(s) Identification Classification of substance or WARNING mixture/Signal Word Skin Corrosion/Irritation - Category 2 Serious Eye Damage/Eye Irritation -Category 2 Skin Sensitization - Category 1 Specific Target Organ Toxicity (Single Exposure) [Respiratory tract irritation] — Category 3 GHS Label Elements Hazard Pictograms , • Hazard Statements/Classification of H315 Causes skin irritation. substance or mixture H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H335 May cause respiratory irritation. Precautionary statements Precautionary Statements Prevention P261 Avoid breathing vapors. P264 Wash hands thoroughly after handling. P271 Use only outdoors or in a well -ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/protective clothing/eye protection/face protection. Response P304+ 340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P313 Call a POISON CENTER or doctor/physician if you feel unwell. P302+352+363 IF ON SKIN: Wash with soap and water. Take off contaminated clothing and wash before reuse. P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P308 + P313 If exposed or concerned: Get medical attention. Storage P401 Store at room temperature in a well -ventilated area. Disposal P501 Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified (HNOC) None Available. 3. Composition/Information On Ingredients Chemical Name CAS Number Content (%) Diglycidyl Ether of Bisphenol A 25068-38-6 50— 60% Dipropylene glycol n-butyl ether 29911-28-2 25 —30% Dipropylene glycol dimethyl ether 111109-77-4 15-20% There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. 4. First -Aid Measures Skin contact Remove contaminated clothing and shoes and wipe excess off skin. Flush skin with water. Follow by washing in soap and water. If irritation occurs, seek medical attention. Do not reuse clothing until cleaned. Contaminated leather articles (shoes) cannot be decontaminated and should be destroyed. Eye contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Ingestion Do not induce vomiting unless directed to do so by medical personnel. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Inhalation Remove victim to fresh air and provide oxygen if breathing is difficult. Give artificial respiration if not breathing. Get medical attention. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Treat symptomatically.'Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments No specific treatment. 5. Fire -Fighting Measures Suitable extinguishing media Alcohol -resistant foam, carbon dioxide (CO2), dry chemical, water fog. Unsuitable extinguishing media None known. Specific hazards arising from the chemical In a fire or if heated, a pressure increase will occur and the container may burst. This material is toxic to aquatic life with long lasting effects. Fire water contaminated must be contained and prevented from being discharged to any waterway, sewer or drain Hazardous decomposition products Decomposition products may include the following materials: Carbon dioxide Carbon monoxide Special protective actions for fire-fighters Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective equipment for fire- Fire-fighters should wear appropriate protective equipment and self-contained fighters breathing apparatus (SCBA) with a full face -piece operated in positive pressure mode. Further information Do not allow run-off from firefighting to enter drains or water courses. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. 6. Accidental Release Measures Personal precautions Wear proper personal protective equipment (PPE). Avoid direct contact with material. Proper PPE includes: disposable gloves, eye protection and skin protection. Emergency procedures If materials is spilled, avoid contact with material. Persons not wearing appropriate protective equipment should leave the area of the spill until cleanup is complete. Methods and materials for Stop leak if without risk. Move containers from spill area. Approach release containment/cleanup from upwind. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage. 7. Handling and Storage Precautions for safe handling Avoid contact with skin and eyes. Emergency showers and eye wash stations should be readily accessible. Adhere to work practice rules established by government regulations. Use personalprotective equipment. When using, do not eat, drink or smoke. Precautions/Recommendations for Store epoxy products in temperature stable environment, out of the reach of safe/proper storage pets or children. Securely fasten container lids and tops, and prevent products from sitting and below freezing temperatures. 8. Exposure Controls/Personal Protection Occupational Exposure Limits None established. Appropriate engineering controls Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Environmental exposure controls Use appropriate containment to avoid environmental contamination. Do not allow spill to enter sewers or waterways. Individual protection measures/Personal protective equipment Eye/face protection Splash -proof goggles or safety spectacles with side shields are recommended. Always wear eye protection when sanding cured epoxy resins to avoid dust in eyes. Hand protection Always wear impervious gloves: butyl rubber, nitrile rubber, Neoprene, PVC disposable gloves, Skin protection Wear clean, body -covering clothing to avoid skin contact. Respiratory protection Use a properly fitted, air -purifying or air -fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Special instructions for protection and Wear gloves at all times when handling product, avoid direct contact with skin. hygiene When finished using product, dispose of gloves properly and wash hands with warm, soapy water. 9. Physical and Chemical Properties Chemical family Appearance Physical State Form Color Odor Density (Specific Gravity) Viscosity PH Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Epoxy Resin Clear liquid Epoxy resin mixture Liquid Water clear Low odor 5.9-9.2 lbs./gal (1.07-1.1 g/cm') 50 cps @ 25°C Data not available Not applicable Not applicable 175°F, Pensky-Martens Closed Cup Slower than ether Data not available Upper/lower flammability limit (by volume) Data not available Material VOC 400-450 grams/liter Vapor density Relative density Solubility in water Partition coefficient: n-octanol/water Auto -ignition temperature Decomposition temperature Heavier than air Not determined Negligible, in water Data not available Data not available Data not available 10.Stability and Reactivity Reactivity No specific test data related to reactivity available for this product. Chemical Stability Stable under normal conditions. Possibility of hazardous reactions Hazardous polymerization will not occur. Conditions to avoid Epoxy resins and epoxy resin hardeners react with each other producing heat. They should not be mixed with each other under uncontrolled conditions or in large mass as the ensuing exotherm may result in heat and smoke, resulting in hazardous decomposition products. Incompatible materials Strong oxidizing and reducing agents. Lewis and mineral acids. Hazardous decomposition products Oxides of carbon, aldehydes, and acids. Other hazards None known. 11. Toxicological Information Acute Health Hazard (components► No comprehensive data (ingestion, inhalation, dermal) on mixture (product). Component Result Species Dose Exposure Diglycidyl Ether of Bisphenol A LD50 Oral Rat 11,400 mg/kg - LD50 Dermal Rat 2,000 mg/kg - Dipropylene glycol n-butyl ether LD50 Oral Rat 3,700 mg/kg - LDSO Dermal Rat >2,000 mg/kg LC50Inhalation Rat >2.04 mg/I 4 h Dipropylene glycol dimethyl ether LD50 Oral Rat 3,300 mg/kg - LD50 Dermal Rat >2,000 mg/kg - LC50Inhalation Rat >5.25 mg/I 4 h Irritation/Corrosion (components) No information on the product itself. Component Result Species Test Exposure Diglycidyl Ether of Bisphenol A Moderate to severe irritation Rabbit Skin 4 h Mild irritation Rabbit Eye 24 h Dipropylene glycol n-butyl ether Slight irritation Rat Skin - Dipropylene glycol dimethyl ether Slight irritation Eye Sensitization Mutagenicity Carcinogenicity Reproductive Toxicity Teratoeenicity Specific target organ toxicity (single exposure) No information on the product itself. No information on the product itself. No information on the product itself. No information on the product itself. No information on the product itself. No information on the product itself. Component Category Route of exposure Target organs I Diglycidyl Ether of Bisphenol A I Category 3 I I Respiratory tract irritation Specific target organ toxicity (repeated No information on the product itself. exposure) Aspiration hazard Potential acute health effects Eye Contact Inhalation Skin Contact Ingestion Symptoms related to the physical, chemical and toxicological characteristics Eye Contact Inhalation Skin Contact Ingestion Delayed and immediate effects and also chronic effects from short and long term exposure Potential chronic health effects General Carcinogenicity Mutagenicity Teratogenicity Developmental effects Fertility effects Numerical measures of toxiciri Acute toxicity estimates (ATEmix) 12. Ecological Information Ecotoxiciri No information on the product itself. Causes serious eye irritation. May cause respiratory irritation. Causes skin irritation. May cause an allergic skin reaction. Irritating to mouth, throat and stomach. Adverse symptoms may include the following: Pain Watering Redness Adverse symptoms may include the following: Respiratory tract irritation Coughing Adverse symptoms may include the following: Irritation Redness No specific data. Not available. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No specific data. No information on product itself. Component Result Species Exposure Diglycidyl Ether of Bisphenol A Acute LC501.3 mg/I Fish 96 h Acute LC50 2.1 mg/I Daphnia 48 h Dipropylene glycol n-butyl ether Acute LC50 >1,000 mg/I Daphnia 48 h Acute LC50 841 mg/I Guppy 96 h Dipropylene glycol dimethyl ether Acute LC50 >1,000 mg/I Guppy 96 h Acute LC50 >1,000 mg/I Daphnia 24 h Persistence and degradability Bioaccumulative Potential No information on product itself. No information on product itself. Component LogPow BCF Potential Diglycidyl Ether of Bisphenol A 3 - Low Dipropylene glycol n-butyl ether <3 <100 Low Dipropylene glycol dimethyl ether <3 <100 Low Mobility in Soil_ Soil/water partition coefficient (KOC) Other adverse effects 13. Disposal Considerations Waste from residues/ unused products Contaminated packaging 14.Transport Information No information on product itself. No known significant effects or critical hazards. The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Product should not be allowed to enter drains, water courses or the soil; dispose of this material and its containers in a safe way. Contact supplier if guidance is required. Dispose of container and unused contents in accordance with federal, state and local requirements. The data provided in this section is for information only and may not be specific to your package size or mode of transport. You will need to apply the appropriate regulations to properly classify your shipment for transportation. International Transport Regulations Regulatory UN/NA number information DOT TDG IMO/IMDG UN3082 IATA(Cargo) UN3082 'PG: Packing group Special precautions for user: 15. Regulatory Information UNITED STATES Proper Shipping Name Classes/•PG Additional Information Non -regulated Non -regulated Environmentally hazardous substance, Class 9 III liquid, n.o.s. (Bisphenol-A Epichlorohydrin Resin) Environmentally hazardous substance, Class 9 III liquid, n.o.s. (Bisphenol-A Epichlorohydrin Resin) Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. U.S. Federal Regulations United States —TSCA 12(b) — Chemical export notification: None Required. United States —TSCA 5(a)2 —Final significant new use rules: Not Listed. United States — TSCA 5(a)2 — Proposed significant new use rules: Not Listed. United States — TSCA 5(e) — Substance consent order: Not listed. Clean Air Act— Ozone Depleting This product does not contain nor is it manufactured with ozone depleting Substances(ODS) substances. Clean Air Act Section 112(b) Hazardous None. Air Pollutants (HAPs) California Prop. 65 WARNING: This product contains less than 0.1% of a chemical known to the State of California to cause cancer. Ingredient Name Cancer Reproductive Oxirane, 2-(phenoxymethyl)- Yes No EPA SARA 302 Extremely Hazardous None required. Substances EPA SARA 302/304/311/312 Hazardous Acute Health Hazard Chemicals SARA 313 None required. Form R — Reporting requirements United States inventory (TSCA 8b) All components are listed or exempted. CANADA WHMIS (Canada) Class D-213: Material causing other toxic effects (Toxic). Canadian NPRI None required. CEPA Toxic substances None required. INTERNATIONAL REGULATIONS International Lists Australia inventory (AICS): All components are listed or exempted. Canada inventory: All components are listed or exempted. Korea inventory: All components are listed or exempted. Japan inventory: All components are listed or exempted. China inventory (IECSC): All components are listed or exempted. New Zealand inventory (NZIoC): All components are listed or exempted. Philippines inventory (PICCS): All components are listed or exempted. Taiwan inventory (CSNN): All components are listed or exempted. 16.Other Information, Including Date of Preparation or Last Revision HMIS Rating Date of Preparation July 28, 2017 Date of Last Revision June 1, 2015 Revision # 2.0 More Information 1-253-333-8118 Prepared by N. Kim, System Three Resins Inc. The information contained herein is based on the data available to us and is believed to be correct. However, System Three Resins, Inc. makes no warranty, expressed or implied, regarding the accuracy of these data or the results to be obtained from the use thereof. System Three assumes no responsibility for injury from the use of the product described herein. SAFETY DATA SHEET 1. Product Identification Product name SilverTip® Yacht Primer, Part B SIDS Number 1710B00 Producttype Polyamide Coating Hardener Recommended use of the chemical and Paint primer for marine use. restrictions on use Restrictions None known. Manufacturer/Supplier information Company name Address Telephone Website Email Emergency Contact 2. Hazard(s) Identification Classification of substance or mixture/Signal Word GHS Label Elements Hazard Pictograms Hazard Statements/Classification of substance or mixture Precautionary statements Precautionary Statements Prevention SYSTEM THREE RESINS, INC. 3500 W. Valley Hwy, Suite Suite 105 Auburn, WA 98001-2436 United States 1-253-333-8118 www.systemthree.com support@systemthree.com CHEMTREC (U.S. and CANADA) 1-800-424-9300 CHEMTREC (Outside the U.S.) 1-703-527-0585 WARNING Skin Corrosion/Irritation - Category 2 Serious Eye Damage/Eye Irritation - Category 1 Skin Sensitization - Category 1 O H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye damage. P261 Avoid breathing vapors. P264 Wash hands thoroughly after handling. P271 Use only outdoors or in a well -ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/protective clothing/eye protection/face protection. Response Storage Disposal Hazards not otherwise classified (HNOC) 3. Composition/information On I P304 +340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P313 Call a POISON CENTER or doctor/physician if you feel unwell. P302+352+363 IF ON SKIN: Wash with soap and water. Takeoff contaminated clothing and wash before reuse. P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P308+ P313 If exposed or concerned: Get medical attention. P401 Store at room temperature in a well -ventilated area. P501 Dispose of contents and container in accordance with all local, regional, national and international regulations. None Available. Chemical Name CAS Number Content (%) Polyamide Resin Trade Secret 15 — 25% Titanium Dioxide 13463-67-7 10-15% Isopropyl Alcohol 67-63-0 1— 2% There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. 4. First -Aid Measures Skin contact Remove contaminated clothing and shoes and wipe excess off skin. Flush skin with water. Follow by washing in soap and water. If irritation occurs, seek medical attention. Do not reuse clothing until cleaned. Contaminated leather articles (shoes) cannot be decontaminated and should be destroyed. Eye contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Ingestion Do not induce vomiting unless directed to do so by medical personnel. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Inhalation Remove victim to fresh air and provide oxygen if breathing is difficult. Give artificial respiration if not breathing..Get medical attention. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments No specific treatment. 5. Fire -Fighting Measures Suitable extinguishing media Alcohol -resistant foam, carbon dioxide (CO2), dry chemical, water fog. Unsuitable extinguishing media None known. Specific hazards arising from the chemical Potential skin irritation. Toxic fumes may be evolved when this substance is burned. Incomplete combustion may for carbon monoxide. Downwind personnel must be evacuated. Hazardous decomposition products Decomposition products may include the following materials: Carbon dioxide Carbon monoxide Special protective actions for fire-fighters Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective equipment for fire- Fire-fighters should wear appropriate protective equipment and self-contained fighters breathing apparatus (SCBA) with a full face -piece operated in positive pressure mode. Further information Do not allow run-off from firefighting to enter drains or water courses. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. 6. Accidental Release Measures Personal precautions Wear proper personal protective equipment (PPE). Avoid direct contact with material. Proper PPE includes: disposable gloves, eye protection and skin protection. Emergency procedures If materials is spilled, avoid contact with material. Persons not wearing appropriate protective equipment should leave the area of the spill until cleanup is complete. Methods and materials for Stop leak if without risk. Move containers from spill area. Approach release containment/cleanup from upwind. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage. 7. Handling and Precautions for safe handling Avoid contact with skin and eyes. Emergency showers and eye wash stations should be readily accessible. Adhere to work practice rules established by government regulations. Use personal protective equipment. When using, do not eat, drink or smoke. Precautions/Recommendations for Store epoxy products in temperature stable environment, out of the reach of safe/proper storage pets or children. Securely fasten container lids and tops, and prevent products from sitting and below freezing temperatures. 8. Exposure Controls/Personal Protection Occupational Exposure Limits None established. Appropriate engineering controls Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Environmental exposure controls Use appropriate containment to avoid environmental contamination. Do not allow spill to enter sewers or waterways. Individual protection measures/Personal protective equipment Eye/face protection Splash -proof goggles or safety spectacles with side shields are recommended. Always wear eye protection when sanding cured epoxy resins to avoid dust in eyes. Hand protection Always wear impervious gloves: butyl rubber, nitrile rubber, Neoprene, PVC disposable gloves, Skin protection Wear clean, body -covering clothing to avoid skin contact. Respiratory protection Use a properly fitted, air -purifying or air -fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Special instructions for protection and Wear gloves at all times when handling product, avoid direct contact with skin. hygiene When finished using product, dispose of gloves properly and wash hands with warm, soapy water. 9. Physical and Chemical Properties Chemical family Appearance Physical State Form Color Odor Density (Specific Gravity) Viscosity PH Melting point/freezing point Initial boiling point and boiling range Flash point Epoxy Hardener Gray liquid Polyamide/water mixture Liquid Gray Mild 11.5 —11.7 Ibs/gal (1.38 —1.40 g/cm3) 2,300-2,500 CPS @ 25°C 9.57 Not applicable Not applicable >2127 (>100°C), Pensky-Martens Closed Cup Evaporation rate Slower than ether Flammability (solid, gas) Data not available Upper/lower flammability limit (by volume) Data not available Material VOC Vapor density Heavier than air Relative density Not determined Solubility in water Negligible, in water Partition coefficient: n-octanol/water Data not available Auto -ignition temperature Data not available Decomposition temperature Data not available 10.Stability and Reactivity Reactivity No specific test data related to reactivity available for this product. Chemical Stability Stable under normal conditions. Possibility of hazardous reactions Hazardous polymerization will not occur. Conditions to avoid None known. Incompatible materials Strong oxidizing and reducing agents. Lewis and mineral acids. Hazardous decomposition products Oxides of carbon, aldehydes, and acids. Other hazards None known. 11. Toxicological Information Acute Health Hazard (components) No comprehensive data (ingestion, inhalation, dermal) on mixture (product). Component Result Species Dose Exposure Polyamide Resin LD50 Oral Rat 2,960 mg/kg - LD50 Dermal Rabbit >5,000 mg/kg Irritation/Corrosion (components) No information on the product itself. Component Result Species Test Exposure Polyamide Resin Moderate irritation Severe eye irritation - - - Sensitization No information on the product itself. Mutagenicity No information on the product itself. Carcinogenicity No information on the product itself. Reproductive Toxicity No information on the product itself. Teratogenicity No information on the product itself. Specific target organ toxicity (single No information on the product itself. exposure) Specific target organ toxicity (repeated No information on the product itself. exposure) Aspiration hazard No information on the product itself. Potential acute health effects Eye Contact Causes serious eye damage. Inhalation May cause nose, throat, and lung irritation. Inhalation of vapors and/or aerosols in high concentration may cause irritation of respiratory system. Skin Contact Causes skin irritation. May cause an allergic skin reaction. Ingestion No specific data. Symptoms related to the physical, chemical and toxicological characteristics Eye Contact Adverse symptoms may include the following: Pain Watering Redness Inhalation Adverse symptoms may include the following: Respiratory tract irritation Coughing Skin Contact Adverse symptoms may include the following: Irritation Redness Ingestion No specific data. Delayed and immediate effects and also Not available. chronic effects from short and lone term exposure Potential chronic health effects General Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. Carcinogenicity No known significant effects or critical hazards. Mutagenicity No known significant effects or critical hazards. Teratogenicity No known significant effects or critical hazards. Developmental effects No known significant effects or critical hazards. Fertility effects No known significant effects or critical hazards. Numerical measures of toxicity Acute toxicity estimates (ATEmix) No specific data. 12. Ecological Information Ecotoxicity No information on product itself. Component Result Species Exposure Isopropyl Alcohol Acute LC50: 10,000 mg/I Artemia salina 24 h Acute LC50:10,000 mg/I Daphnia magna 24 h Acute LC50: 900 — 1,950 gm/I Crangon crangon 48 h Acute LC50: 750-1,650 gm/I Crangon crangon 96 h Persistence and degradability Bioaccumulative Potential No information on product itself. No information on product itself. Component LogPow BCF Potential Isopropyl Alcohol 0.05 Mobility in Soil Soil/water partition coefficient (KOC) Other adverse effects 13. Disposal Considerations No information on product itself. No known significant effects or critical hazards. Waste from residues/ unused products The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Product should not be allowed to enter drains, water courses or the soil; dispose of this material and its containers in a safe way. Contact supplier if guidance is required. Contaminated packaging Dispose of container and unused contents in accordance with federal, state and local requirements. 14.Transport Information The data provided in this section is for information only and may not be specific to your package size or mode of transport. You will need to apply the appropriate regulations to properly classify your shipment for transportation. International Transport Regulations Regulatory UN/NA number information DOT TDG IMO/IMDG IATA (Cargo) *PG: Packing group Special precautions for user: 15. Regulatory Information UNITED STATES Proper Shipping Name Non -regulated Non -regulated Non -regulated Non -regulated Classes/*PG Additional Information Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. U.S. Federal Regulations United States —TSCA 12(b) — Chemical export notification: None Required. United States —TSCA 5(a)2 — Final significant new use rules: Not Listed. United States —TSCA 5(a)2 — Proposed significant new use rules: Not Listed. United States —TSCA 5(e) —Substance consent order: Not listed. Clean Air Act— Ozone Depleting This product does not contain nor is it manufactured with ozone depleting Substances(ODS) substances. Clean Air Act Section 112(b) Hazardous None. Air Pollutants (HAPs) California Prop. 65 This product does not contain any chemicals known to the State of California to cause cancer, birth defects or any other harm. EPA SARA 302 Extremely Hazardous None required. Substances EPA SARA 302/304/311/312 Hazardous None. Chemicals SARA 313 None required. Form R — Reporting requirements United States inventory (TSCA 8b) All components are listed or exempted. CANADA WHMIS (Canada) None. Canadian NPRI None required. CEPA Toxic substances None required. INTERNATIONAL REGULATIONS International Lists Australia inventory (AICS): All components are listed or exempted. Canada inventory: All components are listed or exempted. Korea inventory: All components are listed or exempted. Japan inventory: All components are listed or exempted. China inventory (IECSC): All components are listed or exempted. New Zealand inventory (NZIoC): All components are listed or exempted. Philippines inventory (PICCS): All components are listed or exempted. Taiwan inventory (CSNN): All components are listed or exempted. 16. Other Information, Including Date of Preparation or Last Revision HMIS Rating Date of Preparation Date of Last Revision Revision # More Information Prepared by July 31, 2017 June 1, 2015 2.0 1-253-333-8118 N. Kim, System Three Resins Inc. The information contained herein is based on the data available to us and is believed to be correct. However, System Three Resins, Inc. makes no warranty, expressed or implied, regarding the accuracy of these data or the results to be obtained from the use thereof. System Three assumes no responsibility for injury from the use of the product described herein.