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HomeMy WebLinkAboutSAFETY DATA SHEETr O Date: 10/22/2009 MSDS ID: 20509 Rev: 1.0.6 ._ Industrial Insulation Group., UC Replaces: 11/7/2008 A Calsit"Johns Manville Joint Venture Material Safety Data Sheet Material Name: Fire Resistant Mineral Wool Insulation Section 1— Chemical Product and Company Identification SCANNED BY St. Lucie Countv Product Name(s): MinWool-1200— Board, Flex, Blanket, Pipe, Pipe and Tank, MinWool Sound Attenuation Fire Batts, Safing, Curtainwall, MPT Field Pre -Formed Pipe, Pre -Formed Pipe, Metal Mesh Blanket, Pipe and Tank Wrap, Precision Cut Pipe, Mitered Fittings, Deck Plug. Manufacturer Information Industrial Insulation Group MinWool 908 John Bussey Drive Phenix City, AL 36869 Web site: www.iig-llc.com Phone number for Health and Safety Information: 970.858.6211 (M-F, 7:00 am to 4:00 pm, Mountain Time) Section 2 — Composition and Information on Ingredients CAS # Component 65997-17-3 Synthetic Vitreous Fiber 25104-55-6 Cured Urea k Formaldehyde/PhenolBinder OSHA ACGIH NIOSH Percent PEL TLV REL 95+ 15(T) 5(R) mgW Iflcc NE 0-5 NE NE NE ACGIH TLVs are 2006 values. OSHA PELs are those in effect on the date of preparation of this MSDS. The listed PELs, TVLs and RELs are time weighted average exposure limits. Component Related Regulatory Information This product may be regulated, have exposure limits or other information identified as the following: Nuisance Particulates, Rock Wool Fibers Section 3 — Hazards Identificatio Emergency Overview: Appearance and Odor: Commercial Board, Batt, and Pipe insulation is solid, green/yellow. This product is an article and under normal conditions of use, this product is not expected to create any unusual emergency hazards. However, cutting, sawing, or abrading may increase the risk of personnel exposure. Inhalation of excessive amounts of dust created when fabricating, cutting, or other mechanical alterations of the product may cause temporary upper respiratory irritation and/or congestion — remove affected individuals to fresh air. 1 Skin irritation may be treated by gently washing affected area with soap and warm water. Eye irritation may be treated by flushing eyes with large amounts of water. If irritation persists, contact a physician. Prolonged contact with dust from this product may cause Dermatitis. Acrid smoke may be generated in a fire, use normal fire fighting procedures to prevent inhalation of smoke and gases. HMIS Rating: Health: 1, Fire: 0, Reactivity: 0, Other: 0 NFPARating: Health: 1, Flammability: 0, Reactivity:0 WHMIS Class: IIG MinWool-1200 products are not controlled products Copyright 2009 110 20509 1 of 6 Potential Health Effects Summary Breathing dust from this product may cause a scratchy throat, congestion, and slight coughing. Getting dust or fibers on the skin, or in the eyes may cause itching, rash, or redness. Breathing large amounts of dust or fibers from this product may lead to chronic health effects as discussed in Section I 1 of this material safety data sheet. Inhalation: If inhaled, remove the affected person to fresh air. If irritation persists, seek medical attention. Skin Contact: Dusts and fibers from this product may cause temporary mechanical irritation to the skin. Eye Contact: ` Dusts and fibers from this product may cause temporary mechanical irritation to the eyes. Ingestion: This product is not intended to be ingested or eaten under normal conditions of use. If ingested, it may cause temporary irritation to the gastrointestinal (GI) tract, especially the stomach. Target Organs Upper respiratory passages, skin, and eyes. Primary Routes of Entry (Exposure) Inhalation (breathing dust), skin, and eye contact. Medical Conditions Aggravated by Exposure: Chronic respiratory or skin conditions may temporarily worsen from exposure to this product. Section 4— First Aid Measure First Aid: Inhalation Remove to fresh au. Drink water to clear throat, and blow nose to remove dust. If irritation persists, get medical attention. First Aid: Skin Wash gently with soap and warm Water to remove dust. Use a wash cloth to help remove fibers. To avoid further irritation, do not rob or scratch affected areas. Rubbing or scratching may force fibers into the skin. If irritation persists get medical attention. Never use compressed air to remove fibers from the skin. Wash hands before eating or using the restroom. First Aid: Ingestion Product is not intended to be ingested or eaten. If this product is ingested, irritation of the gastrointestinal (GI) tract may occur, and should be treated symptomatically. Watch the person for several days to make 'sure that partial or complete intestinal obstruction does not occur. Do not induce vomiting unless directed to do so by medical personnel. Rinse mouth with water to remove fibers, and drink plenty of water to help reduce the irritation. No chronic effects are expected following ingestion. First Aid: Eyes Do not rub or scratch your eyes. Fibers may cause the eye to be scratched. Flush eyes with large amounts of water for at least 15 minutes. If irritation persists, contact a medical professional. First Aid: Notes to Physician This product is a mechanical irritant, and is not expected to produce any chronic health effects from acute exposures. Treatment should be directed toward removing the source of irritation with symptomatic treatment as necessary. Section 5 — Fire Fighting Measures Flash Point: Not applicable Upper Flammable Limit (UFL): Not applicable Auto Ignition: Not determined Rate of Burning: `Not applicable General Fire Hazard Method Used: Not applicable Lower Flammable Limit (LFL): Not applicable Flammability Classification: Non combustible There is no potential for fire or explosion. Extinguishing Media Use any extinguishing media appropriate for the surrounding fires Fire Fighting Equipment/Instructions No special procedures are expected to be necessary for this product. Normal fire fighting procedures should be followed to avoid inhalation of smoke and gases produced by other materials. Hazardous Combustion Products: Primary combustion products are carbon monoxide, carbon dioxide, ammonia, and water. Other undetermined compounds could be released in small quantities. Copyright 2009 IIG 20509 2 of 6 Section 6 — Accidental Release Measures Containment Procedures Pick up large pieces. Vacuum dusts. If sweeping is necessary, use a dust suppressant such as water. Do not dry sweep dust accumulation or use compressed air for clean-up. These procedures will help to minimize potential exposures. This material will sink and disperse along the bottom of waterways and ponds. It can not easily be removed after it is waterbome; however, the material is non -hazardous in water. Clean -Up Procedures Wastes are not hazardous as defined by the RCRA (40 CFR 261). Comply with state and local regulations for disposal of these products. If you are unsure of the regulations, contact your local Public Health Department, or the local office of the EPA. Section 7 — Handling and Storage Handling Procedures Use protective equipment as described in Section 8 of this material safety data sheet when handling uncontained material. Keep product in its packaging, as long as practicable to minimize potential dust generation. Keep work areas clean. Avoid unnecessary handling of scrap materials by placing them in waste disposal containers and equipment, kept as to close working areas as possible, to prevent release of fibers and dust. Good housekeeping practices should be used to prevent generation and accumulation of dusts. After handling product, wash face and hands before eating, drinking, or smoking. Storage Procedures Warehouse storage should be in accordance with package directions, if any. Material should be kept dry, and protected from the elements. Section 8 — ExBosure Control and Personal Protection General Product Information Follow all applicable exposure limits and use OSHA -recommended equipment and work practices. A complete copy of these practices can be obtained from IIG MinWool LLC (see Section 1 of this Material Safety Data Sheet), and is also available on the OSHA website (http://www.osha.gov/SLTC/syntheticmineralfbers). Personal Protective Equipment Personal Protective Equipment: Eyes/Face Safety glasses with side shields are recommended to keep dust out of the eyes. Personal Protective Equipment: Skin Leather or cotton gloves should be worn to prevent skin contact and irritation. Barrier creams may also be used to reduce skin contact and irritation caused by mineral wool fibers. ' Normal work clothing (long sleeved shirts and long pants) is recommended. Skin irritation is known to occur chiefly at the pressure points such as around the neck, wrists, waist and between the fingers. Personal Protective Equipment: Respiratory A respirator should be used if ventilation is unavailable, or is inadequate for keeping dust and fiber levels below the applicable exposure limits. In those cases, use a NIOSHcertified disposable or reusable particulate respirator with an efficiency rating of N95 or higher (under 42 CFR 84) when working with this product. For exposures up to five times the established exposure limits use a quarter -mask respirator, rated N95 or higher; and for exposures rip to ten times the established exposure limits use a half -mask respirator (e.g., MSA s DM-11, Racal's Delta N95, 3M's 8210), rated N95 or higher. For exposure limits up to 50 times the established exposure limits use a full -face respirator, rated N99 or higher. Operations such as sawing, blowing, tear out, and spraying may generate airborne fiber concentrations requiring a higher level of respiratory protection. Ventilation In fixed manufacturing settings, local exhaust ventilation should be provided at areas of cutting to remove airborne dust and fibers. General dilution ventilation should be provided as necessary to keep airborne dust and fibers below the applicable exposure limits and guidelines. The need for ventilation systems should be evaluated by a professional industrial hygienist, while the design of specific ventilation systems should be conducted by a professional engineer. Personal Protective Equipment: General _ Loose -fitting, long-sleeved clothing should be worn to protect the skin from irritation. Exposed skin areas should be washed with soap and warm water after handling. Copyright 2009 IIG 20509 3 of 6 Section 9 — Physical & Chemical Properties Appearance: Fibrous semi -circle, blanket, or board insulation Odor: Organic pH: 8 Physical State: Solid Vapor Density: Not applicable Vapor Pressure: Not applicable Melting Point: >2100'F Boiling Point: Not applicable Specific Gravity: Not determined Solubility (H2O): Nil Freezing Point: Not applicable Viscosity: Not applicable Evaporation Rate: Not applicable VOC: 0 Percent Volatile: 0 Section 10 — Chemical Stability & Reactivity Information Chemical Stability This is a stable material. This product is not reactive. Hazardous Decomposition None. Hazardous Polymerization Will not occur. Incompatible Materials: This product reacts with hydrofluoric acid. Hazardous Decomposition Products: Primary combustion products are carbon monoxide, carbon dioxide, ammonia, and water. Other undetermined compounds could be released in small quantities. Section 11 — ToxicolonicalInformation Acute Toxicity A: General Product Information Dusts may cause mechanical irritation to eyes and skin. Ingestion may cause transient irritation of throat, stomach and gastrointestinal tract. Inhalation may cause coughing, nose and throat irritation, and sneezing. Higher exposures may cause difficulty breathing, congestion, and chest tightness. B: Component Analysis - LD50/LC50 No LD50%L.C50's are available for this product in its entirety. Cured Urea/formaldehyde/phenol binder (25104-55-6) Oral LD50 Rat: 7 gm/kg Oral LD50 Mouse: 7 gm/kg Carcinogenicity A: General Product Information OSHA, NTP, IARC, and ACGIH have not classified this product in its entirety as a carcinogen. In October 2001 the IARC concluded its re-evaluation of the carcinogenic risk of mineral wool fibers. The result was a reclassification of the fibers from Group 2B (possibly carcinogenic to humans) to Group 3 (not classifiable as to the carcinogenicity to humans). Epidemiological studies published during the 15 years prior to the 2001 IARC review provide no evidence of increased risk of cancer from occupational exposure during manufacture or use of mineral wool fiber. Reference IARC Volume 81, 2002. B: Component Carcinogenicity ACGIH, IARC, OSHA, and NTP carcinogen lists have been checked for those components with CAS registry numbers. Synthetic Vitreous Fiber(65997-17-3) ACGIH: A3 - animal carcinogen (related to rock wool fibers) with unknown relevance to humans IARC: Group 3; Volume 81, 2002 Man -Made Vitreous Fibers, Not Classifiable Section 12 — Ecological Information Ecotoxicity A: General Product Information No data available for this product. B: Component Analysis - Ecotoxicity - Aquatic Toxicity No ecotoxicity data are available for this product's components. Copyright 2009 IIG 20509 4 of 6 Section 13 — Disposal Considerations US EPA Waste Number & Descriptions A: General Product Information This product, as supplied, is not regulated as a hazardous waste by the U.S. EPA under RCRA regulations. Comply with state and local regulations for disposal. If you are unsure of the regulations, contact your local Public Health Department, or the local office of the EPA. B: Component Waste Numbers No EPA Waste Numbers are applicable for this product's components. Disposal Instructions - Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations. Section 14 — Transport Information US DOT Information Shipping Name: This product is not classified a hazardous material for transport. Section 15 — Regulatory Information US Federal Regulations A: General Product Information No information on this product as it whole. Formaldehyde content is below the SARA 313 0.1 % `de minimis concentration. B: Component Analysis This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4). Synthetic Vitreous Fiber (65997-17-3) CERCLA: Includes mineral fiber emissions from facilities manufacturing or processing glass rock or slag fibers (or other mineral derived fibers) of average diameter I micrometer or less; Statutory RQ = I pound (.454 kg); no final RQ is being assigned to the generic or broad class (related to Fine mineral fibers) State Regulations A: General Product Information The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): WARNING! This product contains a chemical known to the state of California to cause cancer. Other Regulatory Information A: General Product Information No information available for the product. B: TSCA Status All ingredients of this product are included in the US EPA Chemical Substance Inventory or are not required to be listed. C: CERCLA Includes mineral fiber emissions from facilities manufacturing or processing glass rock or slag fibers (or other mineral derived fibers) of average diameter 1 micrometer or less; Statutory RQ = I pound (.454 kg); no final RQ is being assigned to the generic or broad class (related to Fine mineral fibers). D: Clean Air Act Mineral wool fiber appears on the Clean Air Act-1990 Hazardous Air Pollutants List. International Regulations A: General Product Information Canada Workplace Hazardous Materials Information System (WHMIS) WHMIS Classification: D2B—Irritant Product classified as a manufactured article as defined in Hazardous Product Act (HPA), Section 11(1). Section 12(I) exempts it from the WHMIS supplier label and MSDS requirements of the Act. B: Component Analysis - WHMIS IDL No components are listed in the WHMIS IDL. Section 16 — Other Information Information about "Health and Safety Research on Rock- and Slag -wool" can be obtained from the North American Insulation Manufacturers Association (NAIMA), 44 Canal Center Plaza, Suite 310, Alexandria, VA 22314, or on the web at http://www.naima. org Ws product has been classified according to the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. Copyright 2009 IIG 20509 5 of 6 Key/Legend: EPA= Environmental Protection Agency; TSCA= Toxic Substance Control Act; ACGIH =American Conference of Governmental Industrial Hygienists; IARC = International Agency for Research on Cancer; NIOSH = National Institute for Occupational Safety and Health; NTP = National Toxicology Program; OSHA= Occupational Safety and Health Administration; NFPA= National Fire Protection Association; HMIS = Hazardous Material Identification System; RCRA= Resource Conservation and Recovery Act; CERCLA= Comprehensive Environmental Response, Compensation and Liability Act; SARA= Superfund Amendments and Reauthorization Act; DSL = Canadian Domestic Substance List; EINECS = European Inventory of New and Existing Chemical Substances; WHMIS = Workplace Hazardous Materials Information System; CAA= Clean Air Act; CHPA=Canadian Hazardous Product Act; IDL=Canadian Hazardous Disclosure List Revision Summary: This is a revised MSDS which replaces Revision 1.0.4 with a new date. Get this and other MSDS forms electronically via Internet: http://www.iig4lc.com or by calling 800-866-3234. As of the date of preparation of this document, the foregoing information is believed to be accurate and is provided in good faith to comply with applicable federal and state law(s). However, no warranty or representation with respect to such information is intended or given. Prepared by IIG Technical Service IMPORTANT SAFETY NOTICE: The information in this MSDS relates only to the specific material described herein and does not relate to use in combination with any other material or substance or in any process. Because of the use of this information and the conditions of use of this product are not within the control of Industrial Insulation Group, it is the users obligation to determine the conditions of safe use of this product. Users of this product should study this MSDS and become aware of the product hazards and safety information before using this product. Users should also notify their employees, agents, and contractors regarding information contained in this MSDS and any product hazards and safety information in order to provide for safe use of this product. IIG 20509 6 of 6 SAFETY DATA SHEET THE DOW CHEMICAL COMPANY Product name: GREAT STUFFTm Fireblock Insulating Foam Issue Date: 04/14/2015 Sealant 12oz HC ES 12ct V=O A' Print Date: 07/08/2015 THE DOW CHEMICAL COMPANY encc�ragjsjW%*ect?Wu t ro ead and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions. 1. IDENTIFICATION Product name: GREAT STUFFTM Fireblock Insulating Foam Sealant 12oz HC ES 12ct Recommended use of the chemical and restrictions on use Identified uses: Polyurethane foam. SCANNED COMPANY IDENTIFICATION BY THE DOW CHEMICAL COMPANY St. Lucie County 2030 WILLARD H DOW CENTER MIDLAND MI 48674-0000 UNITED STATES Customer Information Number: 800-258-2436 i SDSQuestion@dow.com EMERGENCY TELEPHONE NUMBER 24-Hour Emergency Contact: 800-424-9300 Local Emergency Contact: 800-424-9300 2. HAZARDS IDENTIFICATION Hazard classification This material is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29CFR 1910.1200. Flammable aerosols - Category 2 Skin irritation - Category 2 Eye irritation - Category 2B Respiratory sensitisation - Category 1 Skin sensitisation - Category 1 Carcinogenicity - Category 2 Effects on or via lactation Specific target organ toxicity - single exposure - Category 3 Specific target organ toxicity - repeated exposure - Category 2 - Inhalation Label elements Hazard pictograms ® Tm Trademark of The Dow Chemical Company ("Dow") or an affiliated Page 1 of 19 company of Dow Product name: GREAT STUFF*^ Fireblock Insulating Foam Issue Date: 04/14/2015 Sealant 12oz HC ES 12ct p4A Signal word: DANGER! Hazards Flammable aerosol. Causes skin and eye irritation. May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. Suspected of causing cancer. May cause harm to breast-fed children. May cause damage to organs (Respiratory system) through prolonged or repeated exposure if inhaled. i Precautionary statements Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heattsparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. Avoid contact during pregnancy/ while nursing. Wash skin thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well -ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves. Use personal protective equipment as required. In case of inadequate ventilation wear respiratory protection. Response IF ON SKIN: Wash,with plenty of soap and water. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/ attention. If skin irritation or rash occurs: Get medical advice/ attention. If eye irritation persists: Get medical advice/ attention. Take off contaminated clothing and wash before reuse. Storage Store in a well -ventilated place. Keep container tightly closed. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 OF. Page 2 of 19 Product name: GREAT STUFFTM Fireblock Insulating Foam Issue Date: 04/14/2015 Sealant 12oz HC ES 12ct Disposal Dispose of contents/ container to an approved waste disposal plant. Other hazards no data available 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical nature: Mixture This product is a mixture. Component CASRN Concentration Diphenylmethane Diisocyanate, isomers and 9016-87-9 >= 10.0 - <= 30.0 % homologues '. 4,4'-Methylenediphenyl diisocyanate 101-68-8 >= 10.0 - <= 30.0 % Polymethylenepolyphenyiisocyanate, 57029-46-6 >= 10.0 - <= 30.0 % propoxylated glycerin polymer Polymethylenepolyphenyl polyisocyanate, 53862-89-8 >= 10.0 - <= 30.0 % polypropyleneglycol copolymer Tris(1-chloro-2-propyl) phosphate 13674-84-5 >= 5.0 - <= 10.0 % Paraffin waxes and Hydrocarbon waxes, 63449-39-8 >= 5.0 - <= 10.0 % chlorinated Isobutane 75-28-5 >= 7.0 - <= 13.0 % Methyl ether 115-10-6 >= 1.0 - <= 5.0 % Propane 74-98-6 >= 1.0 - <= 5.0 % 4. FIRST AID MEASURES Description of first aid measures General advice: First Aid responders should pay attention to self-protection and use the recommended protective clothing (chemical resistant gloves, splash protection). If potential for exposure exists refer to Section 8 for specific personal protective equipment. Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by qualified personnel. Call a physician or transport.to a medical facility. Page 3 of 19 Product name: GREAT STUFFTm Fireblock Insulating Foam Issue Date: 04/14/2015 Sealant 12oz HC ES 12ct Skin contact: Remove material from skin immediately by washing with soap and plenty of water. Remove contaminated clothing and shoes while washing. Seek medical attention if irritation persists Wash clothing before reuse. An MDI skin decontamination study demonstrated that cleaning very soon after exposure is important, and that a polyglycol-based skin cleanser or corn oil may be more effective than soap and water. Discard items which cannot be decontaminated, including leather articles such as shoes, belts and watchbands. Suitable emergency safety shower facility should be available in work area. Eye contact: Immediately flush eyes with water; remove contact lenses, if present, after the first 5 minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention without delay, preferably from an ophthalmologist. Suitable emergency eye wash facility should be immediately available. Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by medical personnel. Most important symptoms and effects, both acute and delayed: Aside from the information found under Description of first aid measures (above) and Indication of immediate medical attention and special treatment needed (below), any additional important symptoms and effects are described in Section 11: Toxicology Information. Indication of any immediate medical attention and special treatment needed Notes to physician: Excessive exposure may aggravate preexisting asthma and other respiratory disorders (e.g. emphysema, bronchitis, reactive airways dysfunction syndrome). Repeated excessive exposure may aggravate preexisting lung disease. Maintain adequate ventilation and oxygenation of the patient. May cause respiratory sensitization or asthma -like symptoms. Bronchodilators, expectorants and antitussives may be of help. Treat bronchospasm with inhaled beta2 agonist and oral or parenteral corticosteroids. Respiratory symptoms, including pulmonary edema, may be delayed. Persons receiving significant exposure should be observed 24-48 hours for signs of respiratory distress. Exposure may increase "myocardial irritability". Do not administer sympathomimetic drugs such as epinephrine unless absolutely necessary. If you are sensitized to diisocyanates, consult your physician regarding working with other respiratory irritants or sensitizers. Although cholinesterase depression has been reported with this material, it is not of benefit in determining exposure and need not be considered in the.treatment of persons exposed to the material. Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient. 5. FIREFIGHTING MEASURES Suitable extinguishing media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam. Alcohol resistant: foams (ATC type) are preferred. General purpose synthetic foams (including AFFF) or protein foams may function, but will be less effective. Unsuitable extinguishing media: Do not use direct water stream. Straight or direct water streams may not be effective to extinguish fire. Special hazards arising from the substance or mixture Hazardous combustion products: During a fire, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include and are not limited to: Nitrogen oxides. Isocyanates. Hydrogen chloride. Carbon monoxide. Carbon dioxide. Hydrogen cyanide. Page 4 of 19 Product name: GREAT STUFFTm Fireblock Insulating Foam Issue Date: 04/14/2015 Sealant 12oz HC ES 12ct Unusual Fire and Explosion Hazards: Contains flammable propellant. Aerosol cans exposed to fire can rupture and become flaming projectiles. Propellant release may result in a fireball. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Dense smoke is produced when product burns. Advice for firefighters Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Stay upwind. Keep out of low areas where gases (fumes) can accumulate. Water may not be effective in extinguishing fire. Do not use direct water stream. May spread fire. Fight fire from protected location or safe distance. Consider the use of unmanned hose holders or monitor nozzles. Eliminate ignition sources. Move container from fire area if this is possible without hazard. Use water spray to cool fire - exposed containers and fire -affected zone until fire is out. Special protective equipment for firefighters: Wear positive -pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely, change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight fire from a remote location. For protective equipment in post -fire or non -fire clean-up situations, refer to the relevant sections. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures: Evacuate area. Only trained and properly protected personnel must be involved in clean-up operations. Keep personnel out of low areas. Keep personnel out of confined or poorly ventilated areas. Keep upwind of spill. Ventilate area of leak or spill. No smoking in area. For large spills, warn public of downwind explosion hazard. Check area with combustible gas detector before reentering area. Ground and bond all containers and handling equipment. Eliminate all sources of ignition in vicinity of spill or released vapor to avoid fire or explosion. Vapor explosion hazard. Keep out of sewers. See Section 10 for more specific information. Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection. Refer to section 7, Handling, for additional precautionary measures. Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. Methods and materials for containment and cleaning up: Contain spilled material if possible. Ground and bond all containers and handling equipment. Isolate area until gas has dispersed. Use non -sparking tools in cleanup operations. Eliminate all sources of ignition in vicinity of spill or released vapor to avoid fire or explosion. Check area with combustible gas detector before reentering area. Ground and bond all containers and handling equipment. Collect in suitable and properly labeled containers. Absorb with materials such as: Clay. Dirt. Milsorb®. Sand. Sawdust. Vermiculite. See Section 10 for more specific information. See Section 13, Disposal Considerations, for additional information. 7. HANDLING AND STORAGE Precautions for safe handling: Keep away from heat, sparks and flame. Avoid contact with eyes. Avoid contact with skin and clothing. Avoid prolonged or repeated contact with skin. Avoid breathing Page 5 of 19 Product name: GREAT STUFFTM Fireblock Insulating Foam Issue Date: 04/14/2015 Sealant 12oz HC ES 12ct vapor. Wash thoroughly after handling. Keep container closed. Use only with adequate ventilation. Keep out of reach of children. No smoking, open flames or sources of ignition in handling and storage area. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Contents under pressure. Do not puncture or incinerate container. Containers, even those that have been emptied, can contain vapors. Do not cut, drill, grind, weld, or perform similar operations on or near empty containers. Do not enter confined spaces unless adequately ventilated. Never use air pressure for transferring product. Use of non -sparking or explosion -proof equipment may be necessary, depending upon the type of operation. See Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION. Conditions for safe storage: Minimize sources of ignition, such as static build-up, heat, spark or flame. Store in a dry place. See Section 10 for more specific information. Storage stability Storage temperature: Shelf life: Use within 49 °C (120 °F) 12 Month 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters 4,4'-Methylenediphenyl ACGIH TWA 0.005 ppm diisocyanate OSHA Z-1 C 0.2 mg/m3 0.02 ppm Isobutane ACGIH STEL 1,000 ppm Methyl ether US WEEL TWA 1,000 ppm Propane ACGIH OSHAZ-1 TWA 1,800mg/m3 1,000 ppm Exposure controls Engineering controls: Use only with adequate ventilation. Local exhaust ventilation may be necessary for some operations. Provide general and/or local exhaust ventilationto control airborne levels below the exposure guidelines. Exhaust systems should be designed to move the air away from the source of vapor/aerosol generation and people working at this point. The odor and irritancy of this material are inadequate to warn of excessive exposure. Lethal concentrations may exist in areas with poor ventilation. Individual protection measures Eye/face protection: Use safety glasses (with side shields). Skin protection Hand protection: Use gloves chemically resistant to this material. Examples of preferred glove barrier materials include: Butyl rubber. Chlorinated polyethylene. Polyethylene. Ethyl vinyl alcohol laminate ("EVAL"). Examples of acceptable glove barrier materials include: Neoprene. Nitrile/butadiene rubber ("nitrile" or "NBR"). Viton. Polyvinyl chloride ("PVC" or "vinyl"). NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier. Page 6 of 19 Product name: GREAT STUFFTm Fireblock Insulating Foam Issue Date: 04/14/2015 Sealant 12oz HC ES 12ct Other protection: Use protective clothing chemically resistant to this material. Selection of specific items such as face shield, boots, apron, or full body suit will depend on the task. Respiratory protection: Atmospheric levels should be maintained below the exposure guideline. When atmospheric levels may exceed the exposure guideline, use an approved air - purifying respirator equipped with an organic vapor sorbent and a particle filter. For situations where the atmospheric levels may exceed the level for which an air -purifying respirator is effective, use a positive -pressure air -supplying respirator (air line or self-contained breathing apparatus). For emergency response or for situations where the atmospheric level is unknown, use an approved positive -pressure self-contained breathing apparatus or positive - pressure air line with auxiliary self-contained air supply. In confined or poorly ventilated areas, use an approved self-contained breathing apparatus or positive pressure air line with auxiliary self-contained air supply. The following should be effective types of air -purifying respirators: Organic vapor cartridge with a particulate pre -filter. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical state Color Odor Odor Threshold pH Melting point/range Freezing point Boiling point (760 mmHg)° Flash point Foam Orange mild No test data available Not applicable No test data available No test data available Not applicable closed cup -104 "C (-155 `F) Estimated. Evaporation Rate (Butyl Acetate No test data available =1) Flammability (solid, gas) Not Applicable Lower explosion limit No test data available Upper explosion limit No test data available Vapor Pressure 1,151 hPa at 55 'C (131 OF) Not reported Container is under Relative Vapor Density (air =1) Relative Density (water = 1) Water solubility Partition coefficient: n- octanoUwater Auto -ignition temperature Decomposition temperature Kinematic Viscosity pressure. No test data available 1.069 at 25 -C (77 OF) / 25 °C Estimated. no data available no data available No test data available No test data available Not applicable Page 7 of 19 Product name: GREAT STUFFTm Fireblock Insulating Foam Issue Date: 04/14/2015 Sealant 12oz HC ES 12ct Explosive properties Not explosive Oxidizing properties No Molecular weight no data available NOTE: The physical data presented above are typical values and should not be construed as a specification. 10. STABILITY AND REACTIVITY Reactivity: no data available Chemical stability: Stable under recommended storage conditions. See Storage, Section 7. Unstable at elevated temperatures. Possibility of hazardous reactions: Can occur. Exposure to elevated temperatures can cause product to decompose and generate gas. This can cause pressure build-up and/or rupturing of closed containers. Acids. Conditions to avoid: Avoid temperatures above,50 'C Elevated temperatures can cause container to vent and/or rupture. Exposure to elevated temperatures can cause product to decompose. Incompatible materials: Avoid contact with: Acids. Alcohols. Amines. Ammonia. Bases. Metal compounds. Strong oxidizers. Products based on diisocyanates like TDI and MDI react with many materials to release heat. The reaction rate increases with temperature as well as with increased contact; these reactions can become violent. Contact is increased by stirring or if the other material acts as a solvent. Products, based on diisocyanates such as TDI and MDI are not soluble in water and will sink to the bottom, but react slowly at the interface. The reaction forms carbon dioxide gas and a layer of solid polyurea. Reaction with water will generate carbon dioxide and heat. Hazardous decomposition products: Decomposition products depend upon temperature, air supply and the presence of other materials. Toxic gases are released during decomposition. 11. TOXICOLOGICAL INFORMATION Toxicological information on this product or its components appear in this section when such data is available. Acute toxicity Acute oral toxicity Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling operations are not likely to cause injury; however, swallowing larger amounts may cause injury. Observations in animals include: Gastrointestinal irritation. As product: Singlel,dose oral LD50 has not been determined. LD50, Rat, > 2,000 mg/kg Estimated. Page 8 of 19 Product name: GREAT STUFFTM Fireblock Insulating Foam Issue Date: 04/14/2015 Sealant 12oz HC ES 12ct Acute dermal toxicity Prolonged skin contact is unlikely to result in absorption of harmful amounts. As product: The dermal LD50 has not been determined. LD50, Rabbit, > 2,000 mg/kg Estimated Acute Inhalation toxicity In confined or poorly ventilated areas, vapor can easily accumulate and can cause unconsciousness and death due to displacement of oxygen. Excessive exposure may cause irritation to upper respiratory tract (nose and throat) and lungs. May cause pulmonary edema (fluid in the lungs.) Effects may be delayed. May cause central nervous system depression. Symptoms of excessive exposure may be anesthetic or narcotic effects; dizziness and drowsiness may be observed. Excessive exposure may increase sensitivity to epinephrine and increase myocardial irritability (irregular heartbeats). Decreased lung function has been associated with overexposure to isocyanates. As product: The LC50 has not been determined. Skin corrosion/irritation Prolonged contact may cause moderate skin irritation with local redness. Material may stick to skin causing irritation upon removal. May stain skin. Serious eye damage/eye irritation May cause eye irritation. May cause slight temporar�, corneal injury. Sensitization Skin contact may cause an allergic skin reaction. Animal studies have shown that skin contact with isocyanates may play a role in respiratory sensitization. May cause allergic respiratory reaction. MDI concentrations below the exposure guidelines may cause allergic respiratory reactions in individuals already sensitized. Asthma -like symptoms may include coughing, difficult breathing and a feeling of tightness in the chest Occasionally, breathing difficulties may be life threatening. Specific Target Organ Systemic Toxicity (Single Exposure) May cause respiratory irritation. Route of Exposure: Inhalation Specific Target Organ Systemic Toxicity (Repeated Exposure) Tissue injury in the upper respiratory tract and lungs has been observed in laboratory animals after repeated excessive exposures to MDI/polymeric MIDI aerosols. Contains component(s) which have been reported to cause effects on the following organs in animals: kidney i Liver. Carcinogenicity -- -- Lung tumors have been observed in laboratory animals exposed to respirable aerosol droplets of MDI/Polymeric MIDI (6 mg/m3) for their lifetime. Tumors occurred concurrently with respiratory Page 9 of 19 Product name: GREAT STUFFTM Fireblock Insulating Foam Issue Date: 04/14/2015 Sealant 12oz HC ES 12ct irritation and lung injury. Current exposure guidelines are expected to protect against these effects reported for MDI. Teratogenicity In laboratory animals, MDI/polymeric MDI did not cause birth defects; other fetal effects occurred only at high doses which were toxic to the mother. Reproductive toxicity Based on information for component(s): May cause harm to breastfed babies. Mutagenicity In vitro genetic toxicity studies were negative for component(s) tested. Genetic toxicity data on MDI are inconclusive. MDI was weakly positive in some in vitro studies; other in vitro studies were negative. Animal mutagenicity studies were predominantly negative. Aspiration Hazard Based on physical properties, not likely to be an aspiration hazard. COMPONENTS INFLUENCING TOXICOLOGY: Diohenvlmethane Diisocvanate. Isomers and homologues Acute inhalation toxicity LC50, Rat, 4 Hour, dust1mist, 0.49 mg/I For similar material(s): 2,4'-Diphenylmethane diisocyanate (CAS 5873-54-1). LC50, Rat, 4 Hour, Aerosol, 0.31 mg/I For similar material(s): 4,4'-Methylenediphenyl diisocyanate (CAS 101-68-8). LC50, Rat, 1 Hour, Aerosol, 2.24 mg/I 4.4' -Methylenediphenyl dilsocvanate Acute Inhalation toxicity LC50, Rat, 1 Hour, dust/mist, 2.24 mg/l Polymethylenepolvphenvlisocvanate, propoxvlated glycerin polymer Acute inhalation toxicity The LC50 has not been determined. The LC50 has not been Trisfl-chloro-2-Dropvll ohosphate Acute Inhalation toxicity LC50, Rat, 4 Hour, dust/mist, > 7 mg/I ( Paraffin waxes and Hvdrocarbon waxes, chlorinated Acute Inhalation toxicity As product: The LC50 has not been determined Isobutane Acute inhalation toxicity LC50, Mouse, 1 Hour, 52 mg/I Page 10 of 19 Product name: GREAT STUFFTM Fireblock Insulating Foam Issue Date: 04/14/2015 Sealant 12oz HC ES 12ct Methyl ether Acute inhalation toxicity LC50, Rat, 4 Hour, gas, 164000 ppm Propane Acute inhalation toxicity LC50, Rat, male and female, 4 Hour, vapour, > 425000 ppm 12. ECOLOGICAL INFORMATION Ecotoxicological information on this product or its components appear in this section when such data is available. Toxicity Diphenvlmethane Diisocvanate, isomers and homologues Acute toxicity to fish The measured ecotoxicity is that of the hydrolyzed product, generally under conditions maximizing production of soluble species. Material is practically non -toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested). Based on information for a similar material: LC50, Danio rerio (zebra fish), static test, 96 Hour, > 1,000 mg/I, OECD Test Guideline 203 or Equivalent , Acute toxicity to aquatic invertebrates Based on information for a similar material: EC50, Daphnia magna (Water flea), static test, 24 Hour, > 1,000 mg/l, OECD Test Guideline 202 or Equivalent Acute toxicity to algae/aquatic plants Based on information for a similar material: NOEC, Desmodesmus subspicatus (green algae), static test, 72 Hour, Growth rate inhibition, 1,640 mg1l, OECD Test Guideline 201 or Equivalent Toxicity to bacteria Based on information for a similar material: EC50, activated sludge, static test, 3 Hour, Respiration rates., > 100 mg/I Toxicity to soil -dwelling organisms EC50, Eisenia fetida (earthworms), Based on information for a similar material:, 14 d, > 1,000 mg/kg Toxicity to terrestrial plants EC50, Avena sativa (oats), Growth inhibition, 1,000 mg/I EC50, Lactuca sativa (lettuce), Growth inhibition, 1,000 mg/I 4X-Methvlenediphenvl diisocyanate Acute toxicity to fish Page 11 of 19 Product name: GREAT STUFFTM Fireblock Insulating Foam Issue Date: 04/14/2015 Sealant 12oz HC ES 12ct The measured ecotoxicity is that of the hydrolyzed product, generally under conditions maximizing production of soluble species. Material is practically non -toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested). Based on information for a similar material: LC50, Danio rerio (zebra fish), static test, 96 Hour, > 1,000 mg/I, OECD Test Guideline 203 or Equivalent Acute toxicity to aquatic invertebrates Based on information for a similar material: EC50, Daphnia magna (Water flea), static test, 24 Hour, > 1,000 mg/I, OECD Test Guideline 202 or Equivalent Acute toxicity to algae/aquatic plants Based on information for a similar material: NOEC, Desmodesmus subspicatus (green algae), static test, 72 Hour, Growth rate inhibition, 1,640 mg/I, OECD Test Guideline 201 or Equivalent Toxicity to bacteria Based on information for a similar material: EC50, activated sludge, static test, 3 Hour, Respiration rates., > 100 mg/I Toxicity to soil -dwelling organisms EC50, Eisenia fetida (earthworms), Based on information for a similar material:, 14 d, > 1,000 mg/kg t Toxicity to terrestrial plants EC50, Avena sativa (oats), Growth inhibition, 1,000 mg/I EC50, Lactuca sativa (lettuce), Growth inhibition, 1,000 mgA Polvmethvlenenolvohenvlisocvanate, or000xviated alvicerin oolvmer Acute toxicity to fish For this family of materials: Material is practically non -toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested). Polymethvlenepolyphenyl polyisocyanate, polvpropvlenealycol copolymer Acute toxicity to fish Not expected to be acutely toxic to aquatic organisms. Tris(1-chloro-2-propvil phosphate Acute toxicity to fish Material is slightly toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and 100 mg/L in the most sensitive species tested). LC50, Lepomis macrochirus (Bluegill sunfish), static test, 96 Hour, 84 mg/I, OECD Test Guideline 203 or Equivalent Acute toxicity to aquatic invertebrates EC50, Daphnia magna (Water flea), 48 Hour, 131 mgA Acute toxicity to algae/aquatic plants -`--- - ErC50, Pseudokirchneriella subcapitata (green algae), static test, 96 Hour, Growth rate inhibition, 82 mgA, OECD Test Guideline 201 or Equivalent Page 12 of 19 Product name: GREAT STUFFTm Fireblock Insulating Foam Issue Date: 04/14/2015 Sealant 12oz HC ES 12ct Toxicity to bacteria EC50, activated sludge, Respiration inhibition, 3 Hour, 784 mgA, OECD 209 Test Chronic toxicity to aquatic invertebrates NOEC, Daphnia magna (Water flea), semi -static test, 21 d, number of offspring, 32 mg/I LOEC, Daphnia magna (Water flea), semi -static test, 21 d, number of offspring, > 32 mg/I Paraffin waxes and Hydrocarbon waxes, chlorinated Acute toxicity to fish Material is highly toxic to aquatic organisms on an acute basis (LC50/EC50 between 0.1 and 1 mg/L in the most sensitive species tested). LC50, Oncorhynchus mykiss (rainbow trout), 96 Hour, > 0.1 mg/I Isobutane Acute toxicity to fish No relevant data found. Methyl ether Acute toxicity to fish Material is practically non -toxic to aquatic organisms on an acute basis (LC501EC50/EL50/LL50 >100 mg/L in the most sensitive species tested). LC50, Poecilia reticl ulata (guppy), semi -static test, 96 Hour, > 4,000 mg/I Acute toxicity to aquatic invertebrates LC50, Daphnia magna (Water flea), 48 Hour, > 4,000 mgA, OECD Test Guideline 202 or Equivalent Propane Acute toxicity to fish No relevant data found. Persistence and degradability Diphenylmethane Diisocvanate. Isomers and homolocues Biodegradability: In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the atmospheric environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates. 10-day Window: Not applicable Biodegradation: 0 % Exposure time: 28 d Method: OECD Test Guideline 302C or Equivalent 4,4'-Methvlenediphenvl dilsocvanate Biodegradability: In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the atmospheric environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates. 10-day Window: Not applicable Biodegradation: 0 % Exposure time: 28 d Method: OECD Test Guideline 302C or Equivalent Page 13 of 19 Product name: GREAT STUFFTM Fireblock Insulating Foam Issue Date: 04/14/2015 Sealant 12oz HC ES 12ct Passes OECD test(s) for ready biodegradability. Polvmethvlenepolvphenvl polvisocvanate, polvpropvleneplvcol copolymer Biodegradability: Expected to degrade slowly in the environment. Tris(1-chloro-2-propvll phosphate Biodegradability: Material is expected to biodegrade very slowly (in the environment). Fails to pass OECD/EEC tests for ready biodegradability. 10-day Window: Fail Biodegradation: 14 % Exposure time: 28 d Method: OECD Test Guideline 301 E or Equivalent 10-day Window: Not applicable Biodegradation: 95 % Exposure time: 64 d Method: OECD Test Guideline 302A or Equivalent Theoretical Oxygen Demand: 1.17 mg/mg t Photodegradatiod, Test Type: Half-life (indirect photolysis)` Sensitizer: OH radicals Atmospheric half-life: 0.24 d Method: Estimated. Paraffin waxes and Hydrocarbon waxes. chlorinated Biodegradability: Expected to degrade slowly in the environment. Theoretical Oxygen Demand: 2.89 mg/mg Isobutane Biodegradability: Biodegradation may occur under aerobic conditions (in the presence of oxygen). Theoretical Oxygen Demand: 3.58 mg/mg Photodegradation Test Type: Half-life (indirect photolysis) Sensitizer: OH radicals Atmospheric half-life: 4.4 d Method: Estimated. Methyl ether Biodegradability: Material is expected to biodegrade very slowly (in the environment). to pass OECD/EEC tests for ready biodegradability. 10-day Window: Fail Biodegradation: 5 % Exposure time: 28 d — — -- Method: OECD Test Guideline 301A or Equivalent Fails Page 14 of 19 Product name: GREAT STUFFrm Fireblock Insulating Foam Issue Date: 04/14/2015 Sealant 12oz HC ES 12ct Theoretical Oxygen Demand: 2.08 mg/mg Photodegradation Test Type: Half-life (indirect photolysis) Sensitizer: OH radicals Atmospheric half-life: 6.4 d Method: Estimated. Propane Biodegradability: No relevant data found. Theoretical Oxygen Demand: 3.64 mg/mg Photodegradation Test Type: Half-life (indirect photolysis) Sensitizer: OH radicals Atmospheric half-life: 8.4 d Method: Estimated. Bloaccumulative potential ) Diphenvlmethane Diisocyanate, isomers and homologues Bloaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Reacts with water. In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Bloconcentration factor (BCF): 92 Cyprinus carpio (Carp) 28 d 4.4'-Methvlenediphenyl dilsocvanate Bloaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Reacts with water. In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Bioconcentration factor (BCF): 92 Cyprinus carpio (Carp) 28 d Polymethylenepolyphenvlisocyanate, propoxylated glycerin polymer Bioaccumulation: No relevant data found. Polymethvlenepolyohenvlyolyisocyanate,yolypronvieneglycol copolymer Bioaccumulation: In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Trls(1-chloro-2-propyl) phosphate Bloaccumulation:'Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Partition coefficient: n-octanol/water(log Pow): 2.59 Measured Bloconcentration factor (BCF): 0.8 - 4.6 Cyprinus carpio (Carp) 42 d Measured Paraffin waxes and Hydrocarbon waxes. chlorinated Bioaccumulation: Bioconcentration potential is low (BCF less than 100 or log Pow greater than 7). Partition coefficient: n-octanol/water(log Pow): 7.4 Estimated. Isobutane Page 15 of 19 Product name: GREAT STUFFTm Fireblock Insulating Foam Issue Date: 04/14/2015 Sealant 12oz HC ES 12ct Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Partition coefficient: n-octanol/water(log Pow): 2.76 Measured Methyl ether Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Partition coefficient: n-octanol/water(log Pow): 0.10 Measured Propane Bloaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Partition coefficient: n-octanol/water(log Pow): 2.36 Measured Mobility in soil Diphenvlmethane Diisocvanate. Isomers and homologues In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. 4.4'-Methvlenediphenvl dllsocvanate In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Polvmethvlenepolvohenvllsocvanate, propoxylated glycerin polymer No relevant data found. In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Tris(1-chloro-2-propyl) phosphate Potential for mobility in soil is slight (Koc between 2000 and 5000). Partition coefficient(Koc): 1300 Estimated. Paraffin waxes and Hydrocarbon waxes, chlorinated Expected to be relatively immobile in soil (Koc > 5000). Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is not expected to be an important fate process. Partition coefficient(Koc): > 5000 Estimated. Isobutane Potential for mobility in soil is very high (Koc between 0 and 50). Partition coefficient(Koc): 35 Estimated. Methyl ether Potential for mobility in soil is very high (Koc between 0 and 50). Partition coefficient(Koc): 1.29 - 14 Estimated. Propane Potential for mobility in soil is very high (Koc between 0 and 50). Partition coefficient(Koc): 24 - 460 Estimated. Page 16 of 19 Product name: GREAT STUFFTM Fireblock Insulating Foam Issue Date: 04/14/2015 Sealant 12oz HC ES 12ct 13. DISPOSAL CONSIDERATIONS Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local laws and regulations. Regulations may vary in different locations. Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed, permitted: Incinerator or other thermal destruction device. 14. TRANSPORT INFORMATION DOT Proper shipping name Aerosols UN number UN 1950 Class 2.1 Packing group Classification for SEA transport (IMO-IMDG): Proper shipping name AEROSOLS UN number UN 1950 Class 2.1 Packing group Marine pollutant Paraffin waxes and Hydrocarbon waxes, chlorinated Transport in bulk Consult IMO regulations before transporting ocean bulk according to Annex I or II of MARPOL 73/78 and the IBC or IGC Code Classification for AIR transport (IATA/ICAO): Proper shipping name Aerosols, flammable UN number UN 1950 Class 2.1 Packing group This information is not intended to convey all specific regulatory or operational requirements/information relating to this product. Transportation classifications may vary by container volume and may be influenced by regional or country variations in regulations. Additional transportation system information can be obtained through an authorized sales or customer service representative. It is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the material. Page 17 of 19 Product name: GREAT STUFF"" Fireblock Insulating Foam Issue Date: 04/14/2015 Sealant 12oz HC ES 12ct 15. REGULATORY INFORMATION OSHA Hazard Communication Standard This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right -to -Know Act of 1986) Sections 311 and 312 Acute Health Hazard Chronic Health Hazard Fire Hazard Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right -to -Know Act of 1986) Section 313 This product contains the following substances which are subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and which are listed in 40 CFR 372. Components CASRN Diphenylmethane Diisocyanate, isomers and homologues 9016-87-9 4,4'-Methylenediphenyl diisocyanate 101-68-8 Pennsylvania Worker and Community Right -To -Know Act: The following chemicals are listed because of the additional requirements of Pennsylvania law: Components CASRN Isobutane 75-28-5 Propane Methyl ether 74-98-6 115-10-6 California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986) This product contains no listed substances knownto the State of California to cause cancer, birth defects or other reproductive harm, at levels which would require a warning under the statute. United States TSCA Inventory (TSCA) All components of this product are in compliance with the inventory listing requirements of the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. 16. OTHER INFORMATION Revision Identification Number: 101222505 / A001 / Issue Date: 04/14/2015 / Version: 5.0 Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this document. Page 18 of 19 Product name: GREAT STUFFTM Fireblock Insulating Foam Issue Date: 04/14/2015 Sealant 12oz HC ES 12ct Legend ACGIH USA. ACGIH Threshold Limit Values (TLV) C Ceiling OSHA Z-1 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air Contaminants STEL Short-term exposure limit TWA 8-hour, time -weighted average US WEEL USA. Workplace Environmental Exposure Levels (WEEL) Information Source and References This SIDS is prepared by Product Regulatory Services and Hazard Communications Groups from information supplied by internal references within our company. THE DOW CHEMICAL COMPANY urges each customer or recipient of this (M)SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this (M)SDS and any hazards associated with the product. The information herein is provided in good faith and believed to be accurate as of the effective date shown above. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ between various locations. It is the buyer's/user's responsibility to ensure that his activities comply with all federal, state, provincial or local laws. The information presented here pertains only to the product'as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the safe use of this product. Due to the proliferation of sources for information such as manufacturer - specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current, please contact us for the most current version. Page 19 of 19