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Page: 1
SAFETY DATA SHEET
Revision Date: 05123/2015
Print Date: 1/6/2016
SDS Number: 000000258834
AropolTM L 67307 T-50 B RESIN
TM Trademark, Ashland or its subsidiaries, registered
in various countries
863183
Version: 1.0
l� _/ d l _OZgo
RECEIVED
29 CFR 1910.1200 (OSHA HazCom 2012)
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION MAY 0 2 2018
Product Identifier ST. l.ucle county, Permitting
Trade name AropolTM L 67307 T-50 B
RESIN
TM Trademark, Ashland or its subsidiaries, registered in
various countries
M C
0
Recommended use of the chemical and restrictions on use F Lh PY'
sheet
Ashland
P.O. Box 2219
Columbus, OH 43216
United States of America
1-800-ASHLAND (1-800-274-5263)
Regulatory Information Number
1-800-325-3751
Product Information
614-790-3333
EHS Customer Requests@ashiand.com
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification
Flammable liquids
Combustible Dust
Skin irritation
Eye irritation
Specific target organ
systemic toxicity - single
exposure
Specific target organ
systemic toxicity - repeated
exposure (Inhalation)
GHS Label element
Hazard pictograms
Category 3
Category 2
Category 2A
Category 3 (Respiratory system)
Category 1 (Auditory system)
r SCANNED
BY
Lucie County
I
f ' \� /\''/
AS H LAN"o
Page: 2
SAFETY DATA SHEET
Revision Date: 05/23/2015
Print Date: 1/6/2016
SDS Number: 000000258834
AropolTe" L 67307 T-50 B RESIN
TM Trademark, Ashland or its subsidiaries, registered
in various countries
863183
Version: 1.0
Signal Word Danger
Hazard Statements Flammable liquid and vapor.
May form combustible dust concentrations in air.
Causes skin irritation.
Causes serious eye Irritation.
May cause respiratory irritation.
Causes damage to organs (Auditory system) through prolonged
or repeated exposure if inhaled.
Precautionary Statements Prevention:
Keep away from heat/sparks/open flames/hot surfaces. - No
smoking.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion -proof electrical/ ventilating/ lighting/ equipment.
Use only non -sparking tools.
Take precautionary measures against at discharge.
Do not breathe dust/ fume/ gas/ mist/ vapors/ spray.
Wash skin thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well -ventilated area.
Wear protective gloves/ eye protection/ face protection.
Response:
IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Call a POISON CENTER or doctor/ physician if
you feel unwell.
IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing.
Get medical advice/ attention if you feel unwell.
If skin irritation occurs: Get medical advice/ attention.
If eye irritation persists: Get medical advice/attention.
Take off contaminated clothing and wash before reuse.
In case of fire: Use dry sand, dry chemical or alcohol -resistant
foam to extinguish.
Storage:
Store in a well -ventilated place. Keep container tightly closed.
Store in a well -ventilated place. Keep cool.
Store locked up.
Disposal:
Dispose of contents/ container to an approved waste disposal
plant.
Other hazards
Static Accumulating liquid
SECTION 3. COMPOSITIONIINFORMATION ON INGREDIENTS
ASH LANo
Page: 3
SAFETY DATA SHEET
Revision Date: 05/23/2015
Print Date: 1/6/2016
SDS Number: 000000258834
AropolTm L 67307 T-50 B RESIN
TM Trademark, Ashland or its subsidiaries, registered
in various countries
863183
Version: 1.0
Substance / Mixture : Mixture
Chemical nature : Defatter
Chemical nature : Static Accumulator
Hazardous components
Gltemioal Name''' . ,: .. ;
CAS No x:
Class160atigp '%.
,Concentration
STYRENE
100-42-5
Flam. Liq. 3; H226
33.35
Acute Tox. 4; H332
Skin Irrit. 2; H315
Eye Irrit. 2A; H319
STOT SE 3; H335
STOT RE 1; H372
Asp. Tox. 1; H304
COBALT COMPOUNDS
0.12
SECTION 4. FIRST AID MEASURES
General advice Move out of dangerous area.
Call a POISON CENTRE or doctor/physician if exposed or
you feel unwell.
Show this safety data sheet to the doctor in attendance.
Symptoms of poisoning may appear several hours later.
Do not leave the victim unattended.
If inhaled Move to fresh air.
IF INHALED: Call a POISON CENTER or doctor/ physician if
you feel unwell.
Keep patient warm and at rest.
If unconscious place in recovery position and seek medical
advice.
In case of skin contact Remove contaminated clothing. If irritation develops, get
medical attention.
If on skin, rinse well with water.
Wash contaminated clothing before re -use.
If on clothes, remove clothes.
ASH LANX
Page: 4
SAFETY DATA SHEET
Revision Date: 05/23/2015
Print Date: 1/6/2016
SDS Number: 000000258834
AropolTm L 673D7 T-50 B RESIN
TM Trademark, Ashland or its subsidiaries, registered
in various countries
863183
Version: 1.0
In case of eye contact
Immediately flush eye(s) with plenty of water.
Remove contact lenses.
Protect unharmed eye.
If swallowed
Obtain medical attention.
Do NOT induce vomiting.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
Most important symptoms
Overexposure to this product (or a component) may cause
and effects, both acute and
methemoglobinemia, which in sufficient concentration causes
delayed
cyanosis. Severe cyanosis may require intravenous injection
of methylene blue. Methylene blue is contraindicated if the
patient has confirmed or suspected glucose-6-phosphate
dehydrogenase deficiency.
Signs and symptoms of exposure to this material through
breathing, swallowing, and/or passage of the material through
the skin may include:
stomach or Intestinal upset (nausea, vomiting, diarrhea)
irritation (nose, throat, airways)
confusion
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Causes damage to organs through prolonged or repeated
exposure if inhaled.
Notes to physician
No hazards which require special first aid measures.
SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Water spray
Foam
Alcohol -resistant foam
Carbon dioxide (CO2)
Dry chemical
Unsuitable extinguishing High volume water jet
media
Specific hazards during Never use welding or cutting torch on or near drum (even
firefighting empty) because product (even just residue) can ignite
explosively.
Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.
Do not allow run-off from fire fighting to enter drains or water
courses.
Page: 5
SAFETY DATA SHEET
Revision Date: 05/23/2015
Print Date: 1/6/2016
SIDS Number: 000000258834
Aropol'm L 67307 T-60 B RESIN
Tp4 Trademark, Ashland or its subsidiaries, registered
in various countries
863183
Version: 1.0
Hazardous combustion Hydrocarbons
products carbon dioxide and carbon monoxide
Specific extinguishing
methods
Product is compatible with standard fire -fighting agents.
Further information Do not use a solid water stream as it may scatter and spread
fire.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
Use a water spray to cool fully closed containers.
Special protective equipment In the event of fire, wear self-contained breathing apparatus.
for firefighters
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions,
Evacuate personnel to safe areas.
protective equipment and
Remove all sources of ignition.
emergency procedures
Use personal protective equipment.
Ensure adequate ventilation.
Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.
Persons not wearing protective equipment should be excluded
from area of spill until clean-up has been completed.
Environmental precautions
Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Methods and materials for
Contain spillage, and then collect with non-combustible
containment and cleaning up
absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in container for disposal according to
local / national regulations (see section 13).
Other information
Comply with all applicable federal, state, and local regulations.
Suppress (knock down) gases/vapours/mists with a water
spray jet.
SECTION 7. HANDLING AND STORAGE
Advice on safe handling Open drum carefully as content may be under pressure.
Avoid formation of aerosol.
Provide sufficient air exchange and/or exhaust in work rooms.
Do not breathe vapours/dust.
Do not smoke.
Page: 6
SAFETY DATA SHEET
Revision Date: 05/23/2015
Print Date: 116/2016
Tm Trademark, Ashland or its subsidiaries, registered
in various countries
863183
Dispose of rinsewater inaccordance with local and national
Container hazardous when empty.
Take precautionary measures against static discharges.
Avoid exposure ^ obtain special instructions before use.
Avoid contact with skin and eyes.
Smoking, eating and drinking should beprohibited inthe
application area.
For personal protection see section H.
Conditions for safe storage Keep container tightly closed inudry and well -ventilated
Containers which are opened must bocarefully resealed and
kept upright tuprevent leakage.
Observe label precautions.
No smoking.
Electrical installations / working materials must comply with
the technological safety standards.
SECTION8. EXPOSURE CQNTROLSIPERSONALPROTECTION
Components with workplace control parameters
Biological occupational exposure limits
13
blood
g time:
End of
Remarks:
Semi -quantitative
acid plus
in n
g time:
phenylglyox
I
End of
ylic acid
shift.
Page:7
SAFETY DATA SHEET
Revision Date: 05/23/2015
Print Date: 1/6/2016
SDS Number: 000000258834
AropolTM' L 67307 T-50 B RESIN
TM Trademark, Ashland or its subsidiaries, registered
in various countries
863183
Version: 1.0
Remarks: I Nonspecific
Engineering measures Provide sufficient mechanical (general and/or local exhaust)
ventilation to maintain exposure below exposure guidelines (if
applicable) or below levels that cause known, suspected or
apparent adverse effects.
Personal protective equipment
Respiratory protection In the case of vapour formation use a respirator with an
approved filter.
A NIOSH-approved air -purifying respirator with an appropriate
cartridge and/or filter may be permissible under certain
circumstances where airborne concentrations are expected to
exceed exposure limits (if applicable) or if overexposure has
otherwise been determined. Protection provided by air -
purifying respirators is limited. Use a positive pressure, air -
supplied respirator if there is any potential for uncontrolled
release, exposure levels are not known or any other
circumstances where an air -purifying respirator may not
provide adequate protection.
Hand protection
Remarks
The suitability for a specific workplace should be discussed
with the producers of the protective gloves.
Eye protection
Safety glasses
Skin and body protection
Wear resistant gloves (consult your safety equipment
supplier).
Wear as appropriate:
impervious clothing
Safety shoes
Flame -resistant clothing
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.
Discard gloves that show tears, pinholes, or signs of wear.
Hygiene measures
Wash hands before breaks and at the end of workday.
When using do not eat or drink.
When using do not smoke.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state
Odour
Odour Threshold
pH
liquid
No data available
No data available
No data available
ANSHL N"o
Page:8
SAFETY DATA SHEET
Revision Date: 05/23/2015
Print Date: 1/6/2016
'
SIDS Number: 000000258834
AropolTM L 67307 T-50 B RESIN
TM Trademark, Ashland or its subsidiaries, registered
in various countries
863183
Version: 1.0
Boiling point/boiling range
Flash point
Evaporation rate
Flammability (liquids)
Upper explosion limit
Lower explosion limit
Vapour pressure
Relative vapour density
t
Relative density
Density
Solubility(ies)
Water solubility
Solubility in other solvents
Partition coefficient: n-
octanol/water
Thermal decomposition
Viscosity
Viscosity, dynamic
Viscosity, kinematic
Oxidizing properties
: No data available
: 293 OF / 145 °C
Calculated Phase Transition Liquid/Gas
: 84.9 OF / 29.4 °C
Method: Seta closed cup
: No data available
: Static Accumulating liquid
Upper flammability limit
6.1 %(V)
Method: Calculated Explosive Limit
lower flammability limit
1.1 %(V)
Method: Calculated Explosive Limit
8.53 hPa (25 °C)
Calculated Vapor Pressure
No data available
No data available
1.078 g/cm3 (25 °C)
insoluble
No data available
No data available
No data available
No data available
> 20.5 mm2/s (40 °C)
: No data available
( SECTION 10. STABILITY AND REACTIVITY
Reactivity No decomposition if stored and applied as directed.
JASH LAAN0
Page:9
SAFETY DATA SHEET
Revision Date: 05/23/2015
Print Date: 1/6/2016
SDS Number: 000000258834
AropolTm L 67307 T-50 B RESIN
TM Trademark, Ashland or its subsidiaries, registered
in various countries
863183
Version: 1.0
Chemical stability : Stable under recommended storage conditions.
Possibility of hazardous : Hazardous polymerisation may occur.
reactions Vapours may form explosive mixture with air.
Conditions to avoid : Exposure to air.
Exposure to sunlight.
Heat, flames and sparks.
Incompatible materials
Acids
aluminum
aluminum chloride
Bases
Copper
Copper alloys
halogens
iron chloride
metal salts
Strong oxidizing agents
Peroxides
Hazardous decomposition
products
carbon dioxide and carbon monoxide
Hydrocarbons
SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of :
Inhalation
exposure
Skin contact
Eye Contact
Ingestion
Acute toxicity
Not classified based on available
information.
Components:
STYRENE:
Acute oral toxicity
LD50 Oral (Rat): > 2,000 mg/kg
Acute inhalation toxicity
LC 50 (Rat): 11.8 mg/I, 2770 ppm
Exposure time: 4 h
Test atmosphere: vapour
No observed adverse effect level (Humans): 100 ppm
Exposure time: 7 h
Test atmosphere: vapour
Acute dermal toxicity
LD 50 (Rat): > 2,000 mg/kg
Method: OECD Test Guideline 402
Assessment: No adverse effect has been observed in acute
Page:10
SAFETY DATA SHEET
Revision Date: 05123/2015
Print Date: 1/6/2016
SDS Number: 000000268834
AropolT'^ L 67307 T-50 B RESIN
T Trademark, Ashland or its subsidiaries, registered
in various countries
863183
Version: 1.0
dermal toxicity tests.
Skin corrosion/irritation
Causes skin irritation.
Product:
Remarks: May cause skin irritation and/or dermatitis.
Components:
STYRENE:
Species: Rabbit
Result: Irritating to skin
Serious eye damage/eye irritation
Causes serious eye irritation.
Product:
Remarks: Vapours may cause irritation to the eyes, respiratory system and the skin., Causes
serious eye irritation.
Components:
STYRENE:
Result: Irritating to eyes
Remarks: Vapour during processing may be irritating to the respiratory tract and to the eyes.
Respiratory or skin sensitisation
Skin sensitisation: Not classified based on available information.
Respiratory sensitisation: Not classified based on available information.
Components -
STYRENE:
Exposure routes: Skin contact
Species: Guinea pig
Assessment Does not cause skin sensitisation.
Result: negative
Exposure routes: inhalation (vapour)
Species: Humans
Assessment: Does not cause respiratory sensitisation.
Result: negative
Germ cell mutagenicity
Not classified based on available information.
Carcinogenicity
Not classified based on available information.
Product:
Carcinogenicity- Styrene has been tested for carcinogenicity in rats and mice.
Assessment Styrene caused lung tumors in mice only. These tumors are
not considered to be relevant to humans.
Reproductive toxicity
Not classified based on available information.
STOT -single exposure
May cause respiratory irritation.
Components:
STYRENE:
Page: 11
SAFETY DATA SHEET
Revision Date: 05/23/2015
Print Date: 1/6/2016
SDS Number: 000000258834
AropolT L 67307 T-50 B RESIN
TM Trademark, Ashland or its subsidiaries, registered
in various countries
863183
Version: 1.0
Assessment: May cause respiratory irritation.
STOT - repeated exposure
Causes damage to organs (Auditory system) through prolonged or repeated exposure if inhaled.
Components:
STYRENE:
Exposure routes: inhalation (vapour)
Target Organs: Auditory system
Assessment: Causes damage to organs through prolonged or repeated exposure.
Repeated dose toxicity
Components:
STYRENE:
Species: Human
85 mg/m3
Application Route: inhalation (vapour)
Species: Human
615 mg/kg
Application Route: Skin contact
Aspiration toxicity
Not classified based on available information.
Components -
STYRENE:
May be fatal if swallowed and enters airways.
Further information
Product:
Remarks: Solvents may degrease the skin.
Carcinogenicity:
IARC Group 213: Possibly carcinogenic to humans
STYRENE 100-42-5
OSHA No component of this product present at levels greater than or
equal to 0.1 % is identified as a carcinogen or potential
carcinogen by OSHA.
NTP Reasonably anticipated to be a human carcinogen
STYRENE 100-42-5
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Components,
STYRENE:
JASH U o
Page: 12
SAFETY DATA SHEET
Revision Date: 05/23/2015
Print Date: 1/6/2016
SDS Number: 000000258834
AropolTM L 67307 T-50 B RESIN
T Trademark, Ashland or its subsidiaries, registered
in various countries
863183
Version: 1.0
Toxicity to fish
LC 50 (Pimephales promelas (fathead minnow)): 4.02 mg/I
Exposure time: 96 h
Toxicity to daphnia and other
EC 50 (Water flea (Daphnia magna)): 4.7 mg/I
aquatic invertebrates
Exposure time: 48 h
Toxicity to algae
ErC50 (Pseudokirchneriella subcapitata (green algae)): 4.9
mg/I
Exposure time: 72 h
Toxicity to daphnia and other
NOEC (Water flea (Daphnia magna)): 1.01 mg/I
aquatic invertebrates
Exposure time: 21 d
(Chronic toxicity)
Toxicity to bacteria
: EC 50 (activated sludge): ca. 500 mg/I
Exposure time: 0.5 h
Toxicity to soil dwelling
: NOEC (Eisenia fetida (earthworms)): 34 mg/kg
organisms
Exposure time: 14 d
Method: OECD Test Guideline 207
Persistence and degradability
Components:
STYRENE:
Biodegradability Result: Readily biodegradable
Biodegradation: > 60 %
Exposure time: 10 d
Bioaccumulative potential
Components:
STYRENE:
Bioaccumulation Bioconcentration factor (BCF): < 100
Partition coefficient: n- : log Pow: 2.96 (25 °C)
octanol/water
Mobility in soil
Components:
STYRENE:
Distribution among
environmental compartments
Other adverse effects
Product:
Additional ecological
information
Koo: 352
An environmental hazard cannot be excluded in the event of
unprofessional handling or disposal., Toxic to aquatic life.
o
Page:13
-ASHL
SAFETY DATA SHEET
Revision Date: 05/23/2016
Print Date: 1/6/2016
SIDS Number: 000000258834
AropolTm L 67307 T-50 B RESIN
TA9 Trademark, Ashland or its subsidiaries, registered
in various countries
863183
Version: 1.0
Components:
STYRENE:
Results of PBT and vPvB
assessment
This substance is not considered to be persistent,
bioaccumulating and toxic (PBT). This substance is not
considered to be very persistent and very bioaccumulating
(vPvB).
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
General advice The product should, not be allowed to enter drains, water
courses or the soil.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Send to a licensed waste management company.
Dispose of in accordance with all applicable local, state and
federal regulations.
Contaminated packaging Empty remaining contents.
Dispose of as unused product.
Empty containers should be taken to an approved waste
handling site for recycling or disposal.
Do not re -use empty containers.
Do not burn, or use a cutting torch on, the empty drum.
SECTION 14. TRANSPORT INFORMATION
International transport regulations
REGULATION
ID NUMBER
PROPER SHIPPING NAME
*HAZARD
SUBSIDIARY
PACKING
MARINE
CLASS
HAZARDS
GROUP
POLLUTANT/
LTD. OTY.
MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND
WASTES
UN 1866 Resin solution 3 III
NTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER
UN 1866 Resin solution 3 III
INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO
UN 1866 Resin solution 3 III
INTERNATIONAL MARITIME DANGEROUS GOODS
13118.:_,
Page:14
SAFETY DATA SHEET
Revision Date: 05/23/2015
Print Date: 1/6/2016
SDS Number: 000000258834
Aropo1TM L 67307 T-50 B RESIN
TM Trademark, Ashland or its subsidiaries, registered
in various countries
863183
Version: 1.0
TRANSPORT CANADA - INLAND WATERWAYS
UN 1866 RESIN SOLUTION 3 III
TRANSPORT CANADA - RAII
UN 1866 RESIN SOLUTION 3 III
POLLUTANT:(
ALIPHATIC
PETROLEUM
DISTILLATES,
ALIPHATIC
PETROLEUM
U.S. DOT - INLAND WATERWAYS
UN 1866 Resin solution 3 III
J.S. DOT - RAIL
UN 1866 Resin solution 3 III
U.S. DOT - ROAD
UN 1866 RESINA SOLUCIONES DE 3 III
*ORM = ORM-D, CBL = COMBUSTIBLE LIQUID
Marine pollutant yes
Dangerous goods descriptions (if indicated above) may not reflect quantity, end -use or region -specific
exceptions that can be applied. Consult shipping documents for descriptions that are specific to the
shipment.
SECTION 16. REGULATORY INFORMATION
EPCRA- Emergency Planning and Community Right -to -Know Act
CERCLA Reportable Quantity
Components
CAS -No
Comoon, entRQ
Ca(culated;productF?Q';
Ibs
Ibs
Page: 15
SAFETY DATA SHEET
Revision Date: 05/2312015
Print Date: 1/6/2016
SDS Number: 000000258834
AropolT" L 67307 T-50 B RESIN
T Trademark, Ashland or its subsidiaries, registered
in various countries
863183
Version: 1.0
STYRENE 1 100-42-5 1 1000 I 2998.141152 1
SARA 311/312 Hazards
Reactivity Hazard
Fire Hazard
Acute Health Hazard
Chronic Health Hazard
SARA 313 Component(s)
STYRENE 100-42-5 33.35
COBALT 2- 136-52-7 0.07 %
ETHYLHEXANOATE
COBALT 27253-31-2 0.03 %
NEODECANOATE
COBALT HYDROXIDE 21041-93-0 0.01 %
California Prop 65
WARNING! This product contains a chemical known to the
State of California to cause cancer.
BENZENE 71-43-2
FORMALDEHYDE 50-00-0
1,4-DIOXANE 123-91-1
ACETALDEHYDE 75-07-0
ETHYLENE OXIDE 75-21-8
1,3, BUTADIENE 106-99-0
WARNING: This product contains a chemical known to the
State of California to cause birth defects or other reproductive
harm.
BENZENE 71-43-2
TOLUENE 108-88-3
ETHYLENE OXIDE 75-21-8
1,3, BUTADIENE 106-99-0
The components of this product are reported in the following inventories:
TSCA
On TSCA Inventory
DSL
This product contains the following components listed on the
Canadian NDSL. All other components are on the Canadian
DSL.
AUSTR
Not in compliance with the inventory
Page: 16
SAFETY DATA SHEET
Revision Date: 05/23/2015
Print Date: 1/6/2016
SDS Number: 000000258834
AropoITm L 67307 T-50 B RESIN
TM Trademark, Ashland or its subsidiaries, registered
in various countries
863183
Version: 1.0
ENCS : Not in compliance with the inventory
KECL : Not in compliance with the inventory
PICCS : Not in compliance with the inventory
IECSC : On the inventory, or in compliance with the inventory
Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL
(Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA)
SECTION 16. OTHER INFORMATION
Further information
Revision Date: 05/23/2015
NFPA:
HMIS III:
Flammability
HEALTH
2*
§ '
"MAMMABILITY3
PHYSICAL HAZARb', $t
2
0 = not significant, 1 =Slight,
Special hazard.
2 = Moderate, 3 = High
4 = Extreme, `= Chronic
NFPA Flammable and Combustible Liquids Classification
Flammable Liquid Class IC
Full text of H-Statements referred to under sections 2 and 3.
H226
Flammable liquid and vapor.
H304
May be fatal if swallowed and enters airways.
H315
Causes skin irritation.
H319
Causes serious eye irritation.
H332
Harmful if inhaled.
H335
May cause respiratory irritation.
H372
Causes damage to organs through prolonged or repeated exposure if
inhaled.
ASHLo
Page: 17
SAFETY DATA SHEET
Revision Date: 05/23/2015
Print Date: 1/6/2016
SDS Number: 000000258834
AropolT L 67307 T-50 B RESIN
TM Trademark, Ashland or its subsidiaries, registered
in various countries
863183
Version: 1.0
Sources of key data used to compile the Safety Data Sheet
Ashland internal data including own and sponsored test reports
The UNECE administers regional agreements implementing harmonised classification for labelling
(GHS) and transport.
The information accumulated herein Is believed to be accurate but is not warranted to be whether
originating with the company or not. Recipients are advised to confirm in advance of need that the
information is current, applicable, and suitable to their circumstances. This SDS has been prepared by
Ashland's Environmental Health and Safety Department (1-800-325-3751).
List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data
sheet:
ACGIH : American Conference of Industrial Hygienists
BE[: Biological Exposure Index
CAS : Chemical Abstracts Service (Division of the American Chemical Society).
CMR : Carcinogenic, Mutagenic or Toxic for Reproduction
FG : Food grade
GHS : Globally Harmonized System of Classification and Labeling of Chemicals.
H-statement: Hazard Statement
IATA : International Air Transport Association.
IATA-DGR : Dangerous Goods Regulation by the "International Air Transport Association" (IATA).
ICAO : International Civil Aviation Organization
ICAO-TI (ICAO) : Technical Instructions by the "International Civil Aviation Organization"
IMDG : International Maritime Code for Dangerous Goods
ISO: International Organization for Standardization
log Pow: octanol-water partition coefficient
LCxx : Lethal Concentration, for xx percent of test population
LDxx : Lethal Dose, for xx percent of test population.
ICxx : Inhibitory Concentration for xx of a substance
Ecxx : Effective Concentration of xx
N.O.S.: Not Otherwise Specified
OECD: Organization for Economic Co-operation and Development
DEL: Occupational Exposure Limit
P-Statement : Precautionary Statement
PBT : Persistent, Bioaccumulative and Toxic
PPE : Personal Protective Equipment
STEL : Short-term exposure limit
STOT : Specific Target Organ Toxicity
TLV : Threshold Limit Value
TWA: Time -weighted average
vPvB : Very Persistent and Very Bioaccumulative
WEL : Workplace Exposure Level
CERCLA : Comprehensive Environmental Response, Compensation, and Liability Act
DOT: Department of Transportation
FIFRA: Federal Insecticide, Fungicide, and Rodenticide Act
HMIRC : Hazardous Materials Information Review Commission
HMIS : Hazardous Materials Identification System
NFPA : National Fire Protection Association
NIOSH : National Institute for Occupational Safety and Health
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Page:18
SAFETY DATA SHEET
Revision Date: 05/23/2015
Print Date: 1/6/2016
SDS Number. 000000258834
AropolTm L 67307 T-50 B RRESIN
TM Trademark, Ashland or its subsidiaries, registered
in various countries
863183
Version: 1.0
OSHA: Occupational Safety and Health Administration
PMRA : Health Canada Pest Management Regulatory Agency
RTK : Right to Know
WHMIS : Workplace Hazardous Materials Information System
SCANNED
BY
St. Lucie County
OVERVIEW OF NFPA REQUIREMENTS FOR HAZARDOUS MATERIALS
Most polyester resin users deal primarily with three chemicals which will be reviewed here:
Styrene, MEKP (Methyl Ethyl Ketone Peroxide) and Acetone.
According to the NFPA Flammable and Combustible Liquids Code which is referred to by
OSHA, Styrene is classified as a IC material, Acetone is IB, and MEKP is IIC, also falling
under the classification of an Organic Peroxide.
IB and IC material must be stored in DOT metal spec. containers. Fiber drums, one way
totes, etc. are not allowed for storage of flammable liquids -- even though the DOT allows
the material to be transported in those containers!
MEKP should always be stored in a cool dark, place in its original plastic container to avoid
contamination.
For more detailed information on storage requirements, it is recommended that you
purchase NFPA 30, Flammable and Combustible Liquids Code, 2000 Edition and NFPA
432, Code for The Storage of Organic Peroxide Formulations, 1997 Edition. These can be
ordered on-line at www.nfpa.org/catalog.
Storage Cabinets: Not more than 60 gallons of Class I or Class II liquids are allowed in a
cabinet. The cabinets must be UL-approved or meet specific construction requirements.
They must be labeled Flammable -- Keep Fire Away. No more than three storage cabinets
are allowed per process area.
Inside Storage Rooms: Self -closing fire doors must be provided. The room must have fl-
inch raised sills or ramps of non-combustible material by openings.
If there is no fire protection and the walls have a 2-hour fire resistant rating, the maximum
size of the room allowed is 500 ft. with only 2,000 gallons of material being allowed.
The storage room would be considered a Class I, Division 2 hazard location when selecting
wiring and electrical equipment according to the National Electrical Code.
Outside Storage: A maximum of 1,100 gallons of flammable or combustible liquid is
allowed to be adjacent to the building. If quantities exceed that, they must be stored 10 ft.
away from the building, but 50 ft. away from the property line.
There must be a spill containment curb of at least 6 inches and provisions for drainage with
termination of drains at a safe location. Otherwise, the area must be graded so that spills
are diverted from the building or other exposures.
There must be security provided to prevent tampering or trespassing
0 Composites One LLC 2005
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Fire Control: Small hoses or portable fire extinguishers must be available at inside storage
locations. Organic peroxide storage areas should have water or carbon dioxide
extinguishers, not ABC.
At least one portable extinguisher having at least a 12-B rating must be located not less
than 10 ft. nor more than 25 ft. from Class I or II liquid storage areas outside the room.
Class I, II or III liquids outside of storage areas: Only material in process is allowed, not
to exceed 120 gallons. One portable tank instead is permitted.
Transferring liquids must be separated from other operations in the building by an adequate
distance. Containers should be grounded and bonded while transferring flammable liquids.
Drainage or other methods of spill control must be provided. Natural or mechanical
ventilation must be provided.
Handling liquids at point of final use:
• flammable liquids must be kept in covered containers when not in actual use
• clean up leakage or spills promptly and safely
• Class I liquids may only be used when no sources of ignition are within the path of
vapor
• Class I liquids must be properly grounded when being dispensed
The area where organic peroxides and polyester resins are used should be separated from
the remainder of the building by a 2-hour rated fire-resistant wall.
Fire Protection: All resin spray application areas must be protected by an automatic
sprinkler system that is designed for at least Ordinary Hazard, Group 2 occupancies. For
more detailed information on requirements of "Styrene Cross -linked Composites
Manufacturing", it is recommended that you refer to Chapter 15 of NFPA 33, Standard for
Spray Application Using Flammable or Combustible Materials, 2000 Edition.
Electrical Classifications and Requirements:
• Division 1, Class 1 areas are considered to be up to 5 ft. in all directions where vapor
is released
■ Division I, Class 2 areas are within 25 ft. horizontally, 3 ft. vertically and up to 3 ft.
above the floor beyond Class I, Division 1 areas
• Electrical wiring and utilization equipment located in resin application areas that do
not collect combustible residues may be installed according to the requirements for
ordinary hazard locations if the vapors do not exceed 25 % of the lower flammable
limit (LFL for Styrene is equivalent to approximately 11,000 ppm)
■ All metal parts of the area, such as exhaust ducts, ventilation fans, spray application
equipment, etc, that receive the spray stream or convey flammable liquids must be
0 Composites One LLC 2005
electrically grounded.
Housekeeping:
• control leakage
■ clean up spills immediately
■ in areas where chopper guns are used, paper or polyethylene film, etc. must be
provided to cover the exposed surface of the walls and floor to allow overspray to be
readily removed
■ a single day's accumulation of overspray or 2 inches, whichever is greater, must be
disposed of after a minimum curing time of 4 hours
■ place waste and residue in covered receptacles and dispose of daily
• grounds around building must be free of weeds, trash and unnecessary
combustibles
For more in-depth information on proper handling and storage of hazardous
materials, please call Composites One's Department of Health, Safety & Environment
at 8001621-8003.
0 Composites One LLC 2002
STORAGE TANK PLANS
Regulations governing Underground Storage Tanks (USTs) were promulgated by the EPA
on September 23, 1988. Most polyester resin users do not have USTs to be concerned
about, but Aboveground Storage Tanks (ASTs) are used quite a lot in this industry. ASTs
are not governed by the EPA with specific regulations as of yet -- only indirectly, such as
eliminating stormwater run-off contamination and containment provisions, in general, to
protect human health and the environment.
On the other hand, the National Fire Protection Association (NFPA), which OSHA
incorporates by reference, has specific recommendations for bulk storage tanks.
Whenever installing a tank, it is imperative to contact the local fire department, State fire
marshal and local building codes since each municipality has its own provisions. Your
insurance carrier should also be contacted.
Chapter 2 of the 2000 edition of the NFPA 30, Flammable and Combustible Liquids Code
provides some insight as to what most municipalities and insurance carriers will require.
Outdoor Aboveground Storage Tanks: A tank installation that only has a canopy or roof
over it that does not limit the dispersion of flammable vapors can be treated as an outdoor
aboveground storage tank. Usually, those tanks must be set back from the property line by
at least 25 ft. and must be provided with a diked area that has the volumetric capacity to
contain all of the liquid that can be released from the largest tank. Certain construction and
venting requirements for the tanks must be met.
Storage Tank Buildings: Storage tanks must be separated from the process area by at
least a 2-hour fire -resistive wall. Distance from the property line is dependent on how large
the tank is and what the fire -resistance rating of the surrounding walls are.
Access aisles of at least 3 ft. must be maintained in the building and a clearance of at least
3 ft. from the ceiling must be provided. Exit doors must be provided.
All electrical equipment and wiring must be installed according to the National Electrical
Code. Usually, all equipment located below grade level must be suited for Class I, Division
1. Any area within 5 ft. of a tank opening must also be considered Class I, Division 1.
Areas between 5 ft. and 8 ft. of any tank opening or areas up to 3 ft. above the floor within 5
ft. to 25 ft. horizontally from the tank opening must be considered Class I, Division 2 areas.
Fire prevention and control systems have many variables based on size, design and
location of the building. The local authorities will have to be consulted. All tanks must be
bonded or connected to a ground.
For more detailed information, please contact Composites One's Department of Health, Safety &
Environment at 800/621-8003.
®Composites One LLC 2002